• Title/Summary/Keyword: 아레니우스 관계

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Accelerated Life Prediction of Ethylene-Propylene Diene Monomer Rubber Subjected to Combined Degradation (복합노화를 받는 EPDM 고무의 가속수명예측)

  • Han, Seung Wook;Kwak, Seung Bum;Choi, Nak Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.5
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    • pp.505-511
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    • 2014
  • The EPDM(ethylene-propylene diene monomer) rubbers used for manufacturing engine radiator hoses can be degraded by locally generated electrical stress in addition to thermal and mechanical stresses. This study presents an accelerated life prediction of the EPDM rubber under electrochemical stresses using the Arrhenius formula under various aging temperatures($60^{\circ}C$, $80^{\circ}C$, and $100^{\circ}C$). The modified life prediction formula considers the relationship between the gradient($E_a/R$) and the Arrhenius constant(C). The effects of tensile strain(5%, 10%) on the life of these rubbers were investigated. The aging temperature influences EPDM rubber life, and tensile strain was predicted. It was confirmed that the modified life prediction was within the data deviation level of the test.

A three-dimensional patent evaluation model that considers the factors for calculating the internal and external value of a patent: Arrhenius chemical reaction kinetics-based patent lifespan prediction (특허의 내적.외적 가치산정요인을 고려한 입체적 특허평가모델: 아레니우스 화학반응속도론 기반의 특허수명예측)

  • Choi, Yong Muk;LEE, JAEWON;Cho, Daemyeong
    • Journal of Digital Convergence
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    • v.19 no.6
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    • pp.113-132
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    • 2021
  • This study is a new evaluation using the Arrhenius equation, which is known as the chemical reaction rate estimation equation, to evaluate the intrinsic and extrinsic value elements of patents as a model. The performance of the evaluation model was superior to the SVM, Logistic reg. and ANN models that were used as patent evaluation models in prior studies. In addition, there was a strong correlation between the predicted lifespan of the patent and the actual lifespan of the patent. These evaluation models may be used for evaluation purposes only, or if an evaluation is required, including a commercialization entity or technical characteristics.

Prediction of Useful Life by Heat Aging of Motor Fan Isolating Rubber (모터팬 방진고무부품의 노화수명 예측)

  • Kim, W.S.;Woo, C.S.;Cho, S.J.;Kim, W.D.
    • Elastomers and Composites
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    • v.37 no.2
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    • pp.107-114
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    • 2002
  • This paper discusses the accelerated heat aging tests were carried out to predict the useful life of EPDM isolating rubber components of ventilation fan motor for clean room. 20% compression set results changes as the threshold are used for assessment of the useful life and the time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. The useful life at variable temperatures and activation energy are obtained from the Arrhenius relationship. An accelerated test program to assess useful life can be represented an appreciable investment in time was designed. We also considered the effect of antioxidant agents.

Accelerated Life Test for 1.25Gbps Transceiver (광통신용 1.25Gbps Transceiver 가속수명시험)

  • Yun, Gwang-Su;Yu, Chong-Hee;Heo, Young-Soon
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1391-1393
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    • 2008
  • In this paper, the long-term reliability for 1.25G transceiver in use of high speed optical access network is investigated. High temperature storage tests and accelerated life tests are used to long-term reliability. Accelerated aging test have been during 3,000 hour of the three accelerated aging conditions by caused high temperature stress. Mean life is assumed to follow the Arrhenius relationship and analysis from the failure data obtained in the accelerated aging conditions.

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A Study for Aging Factor of Bulletproof Helmet : High Temperature Treatment (방탄헬멧의 노화인자에 관한 연구 : 고온 환경 처리를 중심으로)

  • Park, Ho Yun;Gu, Seung Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.6
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    • pp.332-339
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    • 2020
  • This study was a prior study to establish the shelf life of bulletproof helmets, considered the aging factor of bulletproof helmets. To estimate the aging factor of bulletproof helmets, we established a hypothesis that the 'temperature' factor would have the greatest impact on the shelf life of the bulletproof helmet, considering the environmental treatment of the American army's bulletproof helmet's materials. To verify the hypothesis, high temperature acceleration environmental treatment of bulletproof helmets was performed, and the Arrhenius formula was applied to calculate the shelf life. The study result confirmed the negative correlation between bulletproof performance and high temperature, and the influence of temperature as an aging factor was not significant by deriving life by using the Arrhenius model. The limitation of this study is that we couldn't obtain enough samples due to the specificity (miliary supplies) of the test subjects. However, given that the life-related research on bulletproof helmets has not been carried out, this research has great implications and could be used as a reference for improving the Korean Army's bulletproof helmet specifications.

Effects of Thermal Aging on Properties and Life-time Prediction of NBR and EPDM Vulcanizates (열 노화에 따른 NBR과 EPDM 가황물의 물성변화 및 노화수명 예측)

  • Woo, C.S.;Choi, S.S.
    • Elastomers and Composites
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    • v.40 no.2
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    • pp.119-127
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    • 2005
  • Material characteristics and lifetime evaluation are very important in design procedure to assure the safety and reliability of the rubber components. In this paper, the material test and accelerated heat aging test were carried out to predict the useful life of NBR and EPDM rubber mount for a compression motor which is used in a refrigerator. In order to investigate the effects of heat-aging on the material properties, crosslink density, modulus at 100% strain, stress-strain curves were obtained from uniaxial and equi-biaxial tensile tests. The change of compression set were used for assessment of the useful life and the time to threshold value were plotted against the reciprocal of absolute temperature to give the Arrhenius plot. The useful life at variable temperatures are obtained in the Arrhenius relationship.

Life-time Prediction of a FKM O-ring using Intermittent Compression Stress Relaxation (CSR) and Time-temperature Superposition (TTS) Principle (간헐 압축응력 완화와 시간-온도 중첩 원리를 이용한 FKM 오링의 수명 예측 연구)

  • Lee, Jin-Hyok;Bae, Jong-Woo;Kim, Jung-Su;Hwang, Tae-Jun;Park, Sung-Doo;Park, Sung-Han;Min, Yeo-Tae;Kim, Won-Ho;Jo, Nam-Ju
    • Elastomers and Composites
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    • v.45 no.4
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    • pp.263-271
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    • 2010
  • Intermittent CSR testing was used to investigate the degradation of an FKM O-ring, also the prediction of its life-time. An intermittent CSR jig was designed taking into consideration the O-ring's environment under use. The testing allowed observation of the effects of friction, heat loss, and stress relaxation by the Mullins effect. Degradation of O-rings by thermal aging was observed between 60 and $160^{\circ}C$. In the high temperature of range ($100-160^{\circ}C$) O-rings showed linear degradation behavior and satisfied the Arrhenius relationship. The activation energy was about 60.2 kJ/mol. From Arrhenius plots, predicted life-times were 43.3 years and 69.9 years for 50% and 40% failure conditions, respectively. Based on TTS (time-temperature superposition) principle, degradation was observed at $60^{\circ}C$, and could save testing time. Between 60 and $100^{\circ}C$ the activation energy decreased to 48.3 kJ/mol. WLF(William-Landel-Ferry) plot confirmed that O-rings show non-linear degradation behavior under $80^{\circ}C$. The life-time of O-rings predicted by TTS principle was 19.1 years and 25.2 years for each failure condition. The life-time predicted by TTS principle is more conservative than that from the Arrhenius relationship.

Kinetics and Mechanism of Corrosion of ρ-alumina Bonded Alumina Castable by Molten Slag (ρ-알루미나결합 알루미나 캐스터블의 용융슬래그에 의한 침식기구)

  • 천승호;전병세
    • Journal of the Korean Ceramic Society
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    • v.40 no.10
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    • pp.1015-1020
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    • 2003
  • The Corrosion behavior of the matrix of the $\rho$-alumina bonded alumina vibrated castable was, on the basis of Jabsen's theory, elucidated by use of the Kingery's reaction mechanism. Corrosion of the matrix during induction period was controlled by the molecular diffusion. The temperature dependence of activation process is well established by the Arrhenius plots. The difference of Ca concentration between slag and interface is 23.2%, which causes a driving force of the materials transfer. The extent of the corrosion of the matrix is more deeper than that of the sintered mullite, but the corrosion mechanism can be well employed as the reaction mechanism proposed by the Kingery. The life time of the castable may be well estimated by the corrosion mechanism of Kingery.

Measurement of Mass Transfer Coefficients in a Benzene Adsorption Process (벤젠 흡착공정에서의 물질전달계수에 관한 연구)

  • Kwon, Jun-Ho;Choi, Moon-Kyu;Suh, Sung-Sup
    • Clean Technology
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    • v.14 no.1
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    • pp.47-52
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    • 2008
  • Among various mass transfer models to express adsorption rates for any adsorption processes, the linear driving force (LDF) model is used most. The present investigation aims at finding whether this model may be applied to real adsorption process for separation and removal of benzene. Comparison of numerical simulation results calculated by the LDF model with experimental data allowed us to find the mass transfer coefficients that are most appropriate for a specific adsorption process. Various breakthrough curves were obtained from experiments performed at many different temperatures and pressures, which in turn produced suitable mass transfer coefficients. These dependencies of mass transfer coefficient on temperature and pressure were represented by an Arrhenius type- and a power law type empirical equation, respectively.

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Effect of Energy Barrier Distribution on Current-Induced Magnetization Switching with Short Current Pulses (짧은 전류 펄스를 이용한 전류 유도 자화 반전에서 에너지 장벽 분포의 효과)

  • Kim, Woo-Yeong;Lee, Kyung-Jin
    • Journal of the Korean Magnetics Society
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    • v.21 no.2
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    • pp.48-51
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    • 2011
  • We performed macro-spin simulation studies of the current-induced magnetization reversal of nanomagnetic elements with short current pulses. A special attention was paid to the effect of the energy barrier on the switching current distribution. The switching current and its distribution increase with decreasing the current pulse-width. The relationship between the energy barrier and switching current distribution is described by the Arrhenius-N$\'{e}$el law at a long pulse-width regime. At a regime of short pulse-width, however, the relationship is left unaddressed. The difficulty to address this issue arises because the magnetization switching with a short current pulse is governed not by the thermal activation but by the precession motion. Therefore, an exact formulation for the short pulse regime by solving the Fokker-Plank equation is needed to understand the result.