• Title/Summary/Keyword: 아레니우스 공식

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The Recovery of Silver from Thiourea Leaching Solution by Cementation Technique (침전법을 이용한 Thiourea 용출용액으로부터 Silver 회수)

  • Kim, Bong-Ju;Cho, Kang-Hee;Choi, Nag-Choul;Park, Cheon-Young
    • Economic and Environmental Geology
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    • v.46 no.1
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    • pp.29-37
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    • 2013
  • In order to apply the silver cementation method using Fe powder from pregnant thiourea leaching solution. Parameters such as the amount of Fe powder addition, agitation speed, and temperature were investigated. The silver cementation rate was increased by the increasing of Fe powder addition, agitation speed, and temperature. The highest silver cementation rate was found when the addition of Fe powder was 50 g/L at the agitation speed of 500 rpm. The silver cementation rate increase with increasing temperature according to the Arrhenius equation and obeys $1^{st}$ order kinetics. The activation energy from the kinetics data was found to be between 13.73 KJ/mol and 17.02 KJ/mol. In the XRD analysis, goethite was detected in the precipitate of the thiourea leach solution. This indicates that an oxidation-reduction reaction had occurred in the thiourea solution due to the addition of the Fe powder.

Effect of Energy Barrier Distribution on Current-Induced Magnetization Switching with Short Current Pulses (짧은 전류 펄스를 이용한 전류 유도 자화 반전에서 에너지 장벽 분포의 효과)

  • Kim, Woo-Yeong;Lee, Kyung-Jin
    • Journal of the Korean Magnetics Society
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    • v.21 no.2
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    • pp.48-51
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    • 2011
  • We performed macro-spin simulation studies of the current-induced magnetization reversal of nanomagnetic elements with short current pulses. A special attention was paid to the effect of the energy barrier on the switching current distribution. The switching current and its distribution increase with decreasing the current pulse-width. The relationship between the energy barrier and switching current distribution is described by the Arrhenius-N$\'{e}$el law at a long pulse-width regime. At a regime of short pulse-width, however, the relationship is left unaddressed. The difficulty to address this issue arises because the magnetization switching with a short current pulse is governed not by the thermal activation but by the precession motion. Therefore, an exact formulation for the short pulse regime by solving the Fokker-Plank equation is needed to understand the result.