• Title/Summary/Keyword: 실리콘 차단제

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Preparation and Characterization of Fire-Resistant Silicone Polymer Composites Containing Inorganic Flame Retardants (무기계 난연제를 첨가한 실리콘 고분자 내화재료의 제조 및 특성분석)

  • Yoon, Chang-Rok;Lee, Jong-Hyeok;Bang, Dae-Suk;Won, Jong-Pil;Jang, Il-Young;Park, Woo-Young
    • Elastomers and Composites
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    • v.45 no.2
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    • pp.87-93
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    • 2010
  • The fire resistive materials are used to resist from fire accidents in the building. In this study silicone rubber/inorganic flame retardant composites were prepared by mechanical stirring method, using aluminium trihydroxide(ATH, $Al(OH)_3$) and magnesium dihydroxide(MDH, $Mg(OH)_2$) as synergistic fire-resistant additives. The thermal properties of the fire resistant composites were characterized by thermogravimetric analysis(TGA). In addition, rheological properties were observed by rheometer and fire-resistant properties were tested by gas torch. Through this study, we realized that the silicone rubber containing ATH, MDH increased the performance of fire-resistance.

유도 결합 산소 플라즈마에서 고조화파 분석법을 이용한 음이온 공간 분포 측정

  • Hwang, Hye-Ju;Kim, Yu-Sin;Kim, Yeong-Cheol;Park, Il-Seo;Jeong, Jin-Uk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.562-562
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    • 2013
  • 산소 플라즈마는 음이온을 발생시키는 음전성 플라즈마로서 감광제 세정이나 금속, 폴리실리콘 등의 식각을 위해 할로겐 가스와 혼합하여 반도체나 디스플레이 공정에 광범위하게 사용되고 있다. 산소 플라즈마는 아르곤 플라즈마와 그 특성이 상이하고, 다량의 음이온이 국부적으로 만들어지므로 음이온의 공간분포 진단이 중요하다. 본 연구에서는 평판형 부유형 탐침에 고조화파 분석법을 적용하여 양이온의 밀도를 구하고, 직류 차단 커패시터를 제거하여 접지전위에서 전자 전류 측정을 통하여 위치에 따른 전자의 상대적인 공간 분포를 얻었다. 이러한 방법으로 측정된 양이온과 전자의 공간 분포로부터 음이온의 공간 분포를 구할 수 있었다. 가스 압력, 산소 첨가량, 인가 전력 등 여러 조건에서 측정된 음이온의 분포는 이론적인 경향성과 유사함을 확인할 수 있었다.

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A Study on the Emulsifying Stability of W/O Type Sunscreen Cream by the Hansen Solubility Parameter (Hansen Solubility Parameter 를 통한 W/O 형 자외선차단 제형의 유화 안정성에 관한 연구)

  • Kim, Dong Hee;Lee, Jin Jae
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.47 no.4
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    • pp.273-280
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    • 2021
  • The water resistance is important factor for sunscreen formulations. Generally a sunscreen cream was formulated by a water-in-oil (W/O) emulsion. In the W/O emulsion system, silicone oils are added to improve the texture of formulations. Silicone oils have low compatibility with organic sunscreen agent, causing problems with the stability in emulsion. In this study, the compatibility between various oils in the W/O emulsion was derived numerically using Hansen solubility parameter (HSP) at first. HSP is represented a dispersion degree, a polarity, and a hydrgen bond in a composition. In this study, various emulsions were prepared according to the types of oils with different HSP values and then monitored by a viscosity and morphology according to the time and temperature. The HSP values of components and the experimental results have similar activities for the stability of emulsions. HSP made it easy to select oil with high compatibility. When the compatibility of the oil phase in the W/O emulsion was high, the viscosity change over time was small. The stability was improved under the freeze-thaw cycle (-15 ℃ ~ 45 ℃). In the future, if the composition of the ingredients is optimized through HSP, it is expected that it will be helpful in the development of W/O type sunscreen formulations that are excellent in use and stability.

A STUDY ON THE EFFECT OF UV LIGHT ABSORBER ON THE COLOR CHANCE OF MAXILLOFACIAL SILICONE (자외선 차단제가 악안면 실리콘의 색변화에 미치는 영향에 관한 연구)

  • Song, Yun-Seok;Lim, Ju-Hwan;Cho, In-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.37 no.3
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    • pp.343-357
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    • 1999
  • The color change of maxillofacial silicone has been attributed to certain environmental factors such as exposure to the UV component of natural sunlight, wetting and drying of the elastomer and surface abrasion resulting from the application and removal of cosmetics. The purpose of this study was to evaluate the color change of maxillofacial silicone (Silastic MDX4-4210) according to type of pigment (cadmium yellow, titanium white, cosmetic red), and UV absorber application method after 200, 400, and 600 hours of 350nm UV light irradiation. The results were as follows. 1. According to type of pigments, after 200 hours cosmetic red showed significantly larger color change than cadmium yellow and titanium white, and after 400 and 600 hours color change significantly decreased in the order of cosmetic red, cadmium yellow, and titanium white (p<0.05). 2. In the cadmium yellow group, after 200 hours, the non-treatment group showed significantly larger color change, but after 400 and 600 hours, color change significantly decreased in the order of non-treatment, surface application and mixed group (p<0.05). 3. In the titanium white group, there was no significant color change difference between the three groups after 200 and 400 hours, but after 600 hours, the mixed group showed significantly smalt or color change than the non-treatment and surface application groups (p<0.05). 4. In the cosmetic red group, there was significant decrease in color change in the order of non-treatment, surface application and mixed group (p<0.05). From the results above, the effect of UV light absorber differed according to the type of pigment, but mixing UV light absorber with maxillofacial silicone is thought to give superior resistance against UV light irradiation in the long run.

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Synergistic Interaction in W/O and W/S Emulsions Stabilized by a Mixture of Powders and Surfactant (분체와 유화제의 상호 관계성에 기인한 저점도 W/O 및 W/S 에멀젼의 안정성 연구)

  • In, So Hyun;Cho, Hwanil;Kang, Nae Gyu;Han, Jong Sup;Park, Sun Gyoo;Lee, Cheon Koo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.42 no.1
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    • pp.15-28
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    • 2016
  • Water-in-oil emulsions including water-in-ester oil and water-in-silicone oil (W/O+S) have various advantages such as blocking moisture evaporation and forming air permeable membrane. However, their applications have been limited due to the poor stability under low viscosity condition. In this study, we investigated the effect of synergistic interaction between nonionic surfactant, micro-size particles and cationic surfactant on the stability of W/O+S formulation. The stability of W/O+S emulsions was changed as a function of cationic surfactant concentration where it increased at lower concentration and then started to decrease above a critical point. Finally, emulsion phase inversion occurred at a high concentration. The results suggest that W/O+S emulsions of low viscosity ranging from 2000 to 5000 cps can be stabilized under the conditions where a nonionic surfactant, micro-size particles and a cationic surfactant are used in the range of 1.0 ~ 4.0 wt%, 2.5 wt% and 0.1 ~ 0.5 wt%, respectively.