• 제목/요약/키워드: 실리케이트

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Treeing Phenomena to High Temperature for Epoxy Based Nanocomposites (에폭시기반 나노콤포지트의 고온부에서 트리잉현상)

  • Park, Jae-Jun;Cho, Dae-Ryung;Um, Ji-Yong;Yun, Yo-Wook;Baek, Kwan-Hyun
    • Proceedings of the KIEE Conference
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    • 2008.10a
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    • pp.155-156
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    • 2008
  • 물리적 분산기법으로 초음파와 균질기를 동시에 적용한 분산기법을 이용하여 에폭시 기반 층상나노실리케이트를 충진한 에폭시-나노콤포지트 제조하였다. 유리천이온도 특성으로 무충진 에폭시수지와 층상실리케이트가 충진된 나노콤포지트의 비교에서 $9.2^{\circ}C$가 상승되는 결과를 얻었다. 고온부인 $130^{\circ}C$ 환경온도에서 장시간 트리잉 절연파괴측정에서 무충진에폭시 수지에 비하여 나노콤포지트가 절연파괴시간이 13.39배 늦은 시간에 파괴되었고, 트리진전속도의 경우 나노콤포지트가 13.9배 늦은 지연속도를 나타내었다.

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Morphology, Thermal, Electrical Properties for Epoxy-Layered Silicate Nanocomposites using Homogenizer +Ultrasonic Dispersion Method (Homogenizer+Ultrasonic을 이용한 Epoxy-Layered Silicate Nanocomposites의 구조적, 열적, 전기적 특성연구)

  • Park, Jae-Jun;Um, Ji-Yong;Lee, Chang-Hun;Kim, Min-Kyu;Baek, Kwan-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.287-288
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    • 2008
  • 에폭시-층상실리케이트 나노콤포지트의 균질분산과 층상실리케이트내로 침투되는 박리정도를 향상시키기 위해 친환경적 분산기법인 물리적방법으로 Homogenizer와 Power Ultrasonic를 적용한 기법을 실시하였다. Homogenizer의 최적속도를 얻기 위해 분산시킨 나노콤포지트의 박리정도, 유리천이온도를 구할 수 있었고, Homogenizer와 Ultrasonic을 동시에 적용하여 최적시간을 구하기 위해 적용된 나노콤포지트를 절연파괴 강도의 Weibull Plots을 통하여 판단할 수 있는 좋은 결과를 얻을 수 있었다.

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Effect of Dispersion Agents for Epoxy-Organoclay Nanocomposites (Epoxy-Organoclay Nanocomposites의 Dispersion Agent 영향)

  • Park, Jae-Jun;Cho, Dae-Ryung;Lee, Hyun-Dong;Bang, Byung-Yun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.296-297
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    • 2008
  • 층상실리케이트 나노입자가 충진된 에폭시수지를 분산정도 향상을 위해 즉, 층상실리케이트 층간간경의 삽입과 박를 향상시키기 위해 분산제를 첨가하였고, 초음파 적용으로 분산시켰다. 그 결과 분산제 종류에따라 분산정도인 X-RD 특성이 서로다른 결과를 얻었다. 절연성능을 평가하기위해 단시간 절연파괴강도와 장시간 절연파괴특성인 트리시스템을 이용하여 절연파괴시간 및 측정하였다. 이와같은 결과에대한 통계적인 분석으로 Weibull plots를 이용하였고 그 결과 분산제가 첨가된 나노콤포지트의 기울기 파라미터인 $\beta$값의 결과로부터 나노콤포지트 우수성을 확인 할수있었다.

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Detergency Performance Evaluation of Organic Adherent Pollutant by Modified Silicate-Based Antifouling Coating Material (변성 실리케이트계 방오성 코팅재의 유기성 피착 오염물질 세정성능 평가)

  • Chae, Woo-Byung;Seong, Dong-Yun;Kim, Cheun-Soo;Seo, Sang-Kyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.275-278
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    • 2012
  • This study try to finding the self-detergency performance of adherent pollutant on the mortar surface by using the developed silicate based antifouling coating material. Developed coating material coated on the surface of mortar test piece and after 30 minutes, over layed already coated mortar surface. After 7 days, the surface is polluted with crayons and oily magic marker. After 24 hours, contaminated area was wiped out the water. From the result of self-detergency performance test, it is concluded the developed material could be used as a detergent the contaminated concrete surface.

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Observation of Growth Behavior of Induced Hillock for Nano/Micro Patterning on Surface of Borosilicate with Etching Time and Load (보로실리케이트 표면의 나노/마이크로 패터닝을 위한 식각 시간, 하중에 따른 유기 힐록의 성장거동 관찰)

  • Cho S. H.;Youn S. W.;Kang C. G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.10a
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    • pp.182-185
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    • 2005
  • Indentation pattern and line pattern were machined on borosilicate(Pyrex 7740 glass) surface using the combination of mechanical machining by $Nanoi-indenter\circledR$ XP and HF wet etching, and a etch-mask effect of the affected layer of the nano-scratched and indented Pyrex 7740 glass surface was investigated. In this study, effects of indentation and scratch process with etching time on the morphologies of the indented and scratched surfaces after isotropic etching were investigated from an angle of deformation energies.

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A Study on Wettability of Silicate Glasses on the Different Impurities in Alumina Substrates (알루미나의 순도에 따른 알루미나와 실리케이트계 유리와의 젖음성에 관한 연구)

  • 안병국
    • Journal of Welding and Joining
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    • v.16 no.2
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    • pp.122-128
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    • 1998
  • This investigation was performed to collect fundamental informations concerning the behavior of glass solders on ceramic joining process. The wettability of glasses on two types of alumina was evaluated by sessile drop method. SiO$_2$-CaO-Al$_2$O$_3$system glasses were selected as solder glasses, and alumina that have different purities were used for substrate materials. It is indicated that contact angles of glasses on 99% purity of alumina substrate do not change as increasing time at elevated temperature, however the contact angles on the 92% purity of alumina substrate exhibit the strong time dependency. The time-dependent property on 92% alumina was due to the interlayer reactions occurred between the glass solder and impurities on the substrate.

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Surface Layer Change of Concrete with Concrete Impregnant (침투성 함침제에 따른 콘크리트 표층부의 개질특성)

  • Song, Hun;Shin, Hyeong-UK;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.200-201
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    • 2013
  • This study is interested in manufacturing the concrete surface impregnants including tetra ethyl ortho silicate, alkali silicate for the repair of the exposed concrete and the color concrete requiring the advanced function in view of the concrete appearance. The surface layer change and porosity properties was tested for the review of application. The result of this study show that the effective silicate are tetra ethyl ortho silicate and alkali silicate t. The adhesion in tension is slightly increased but the reinforcement of concrete substrate is slight. So, the concrete impregnant of this study is more desirable for the improvement of durability rather than the reinforcement.

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Effects of Ca/Si Molar Ratio on the Interatomic Distance of Synthetic Calcium Silicate Hydrate (C-S-H) at Elevated Temperature (고온 가열시 Ca/Si 몰비율에 따른 합성 칼슘 실리케이트 수화물(C-S-H)의 구성 원자간 거리 변화)

  • Im, Su-Min;Bae, Sung Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.144-145
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    • 2021
  • Calcium silicate hydrate(C-S-H) is the principal binding phase that controls the strength and thermal stability of concrete. However, the effects of high temperature on the lattice structure and interatomic structure of C-S-H remains poorly understood due to its nanocrystallinity. This study aims to elucidate the change in interatomic distance of synthetic C-S-H with different Ca/Si molar ratios after exposure to high temperature via high energy X-ray scattering experiment which is a powerful analytical tool for amorphous materials.

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