• Journal of Welding and Joining
• /
• 제20권3호
• /
• pp.116-121
• /
• 2002

For the accumulation of a fundamental knowledge about the behavior of glass solder during the joining of ceramics, the wettability of solder on silicon nitride have been measured by sessile drop method. $SiO_2-MgO-Al_2O_3$ g1ass solder and oxynitride glass solders were selected as examples while silicon nitride which were used as substrates. Contact angle of solder on silicon nitride didn't decrease with time at high nitrogen content in the solder, but low nitrogen content in solders have the time-dependent property. Reason which contact angle of low nitrogen content in solders decrease on silicon nitride was that diffusion of nitrogen take place between solder and silicon nitride.

• 한국전기전자재료학회논문지
• /
• 제21권2호
• /
• pp.188-193
• /
• 2008

Epoxy/Organically Modified Layered Silicate Nanocomposites were prepared by dispersing synthetic layered silicate modified with alkyl ammonium ions. In the dispersing process, the organically modified layered silicate were mixed in epoxy resin with shearing, and aggregation of the silicate were removed by centrifugal separation after mixing epoxy resin and silicates. Micrographs taken by transmission electron microscopy(TEM) indicate that the nanocomposites have a mixed morphology including both parallel silicate layers and exfoliated silicate layers area, As the thermal properties, the glass transition temperature of the nanocomposites was shifted to a higher temperature($+6^{\circ}C$)than pure epoxy. Furthermore, dispersion of OMLS will prevented relative permittivity from increasing at a high temperature above the glass transition temperature.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2007년도 추계 학술논문 발표대회
• /
• pp.91-94
• /
• 2007

It is essential every concrete structure should continue to perform its intended functions, that is maintain its required strength and durability, during the service life. However, deterioration occurs more progressively from the outside of concrete exposed to severe conditions. Deterioration in the concrete structure is due to carbonation and chloride ion attack. Therefore, concrete structure is needed to surface protection for increase durability using impregnant. Impregnant classify into two large groups in polymeric and silicate materials. Silicate impregnant is included silane and alkali silicate(sodium and lithium silicate). Thus, this study is concerned with carbonation and chloride ion resistance of self cleaning hydrophilic impregnant of concrete structure using lithium and potassium silicate. From the experimental test result, lithium and potassium silicate have a good properties as a carbonation and chloride ion resistance. Lithium and potassium silicate make good use of hydrophilic impregnant.

• 한국기계가공학회지
• /
• 제13권6호
• /
• pp.145-151
• /
• 2014

The glass used for mobile display windows is required to have high strength. Chemical strengthening by means of ion exchange is widely used glass. The depth of the layer and the compressed stress are affected by tempering temperature and time. The purpose of this study is to investigate the range of DOL and CS, which to less breakage during reliability tests such as the ball drop test, hole drop test, 3-point bending test, drop test, and tumble test with Soda-lime Glass.

• E2M - 전기 전자와 첨단 소재
• /
• 제10권2호
• /
• pp.166-171
• /
• 1997

The photomachinable glass-ceramics of Ag and CeO$_{2}$ added to Li$_{2}$O-Al$_{2}$O$_{3}$-SiO$_{2}$-K$_{2}$O glass system was investigated as a function of UV irradiation time. The temperature of optimum nucleation and crystal growth temperature were confirmed at 525.deg. C, 630.deg. C respectively using DTA and TMA. The phases of Li$_{2}$O.SiO$_{2}$ habit were lath-like and/or dendrite type and [002] direction of Li$_{2}$O.SiO$_{2}$ / Li$_{2}$O.2SiO$_{2}$ phases were changed according to the UV irradiation time by 400 W, 362 nm UV light source. Under that condition, the optimum UV irradiation time was 5 min.

• 한국자원리싸이클링학회:학술대회논문집
• /
• 한국자원리싸이클링학회 2005년도 춘계임시총회 및 제25회 학술발표대회
• /
• pp.131-135
• /
• 2005

• 소성∙가공
• /
• 제12권7호
• /
• pp.623-630
• /
• 2003

Nanomachining process, static nanoplowing, is one of the most promising lithographic technologies in terms of the low cost of operation and variety of workable materials. In nanomachining process, chemical effects are more dominant factor compared with those by physical deformation or fracture. For example, during the nanoscratch on a silicon surface in the atmosphere, micro protuberances are formed due to the mechanochemical reaction between diamond tip and the surfaces. On the contrary, in case of chemically stable materials, such as ceramic or glass, surface protuberances are not formed. The purpose of this study is to understand effects of the mechanochemical reaction between tip and surfaces on deformation behaviors of hard-brittle materials. Nanometerscale elasoplastic deformation behavior of single crystal silicon (100) was characterized with micro protuberance phenomena, and compared with that of borosilicate (Pyrex glass 7740). In addition, effects of the silicon protuberances on nanoscratch test results were discussed.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
• /
• pp.1231-1234
• /
• 2003

A sample procedure has been described to room temperature synthesis, mesoporous aluminosilicate materials with strong surface acidity by using a cationic surfactnat cetyltrimethylammonium bromide(CTABr) as the template agent. All samples were charecterized by X-ray diffraction(XRD) and nitrogen adsorption. The crystallinity and surface area of MCM-41 type aluminosilicats decrease with decreasing of Si/Al ratio. The influence of the aluminum contents of MCM-41 on the coordination of Al and on the acidity is studied by $^{27}Al$ MAS NMR and temperature programmed desorption of ammonia(TPD). It was shown that the incorporation of Al atoms into the framework causes increasing of acid site surface. And then Al atoms in the framework were incorporated tetrahedrally in structure, which gave a rise to cationic sites in the framework.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2020년도 가을 학술논문 발표대회
• /
• pp.151-152
• /
• 2020

When concrete is exposed to fire, the thermal decomposition of hydrates of Portland cement paste results in critical damage to the concrete structure of a building. Recently, nanosilica arose as the effective nano-additive which can enhance the thermal resistance of the cementitious materials. However, the mechanism of the enhancement was not elucidated specifically. In this study, we investigated the properties of calcium silicate hydrates(C-S-H)of the nanosilica incorporated cement paste after heating to different heating temperatures (200℃, 500℃, and 800℃) by 29Si nuclear magnetic resonance. The results showed that the polymerization of C-S-H of nanosilica incorporated samples was larger than ordinary cement paste after heating to 200℃, and C-S-H formed during heating process to 500℃ due to the pozzolanic reaction during heating process.

• Korean Chemical Engineering Research
• /
• 제51권2호
• /
• pp.214-220
• /
• 2013

본 연구에서는 실리케이트계 황색 형광체($Sr_2SiO_4:Eu^{2+}$)의 신뢰성 향상을 위하여 대기압 유전체장벽방전 플라즈마를 이용하여 hexamethyldisiloxane (HMDSO, $C_6H_{18}OSi_2$)을 형광체 분말에 코팅하였다. 플라즈마 코팅 후의 형광체 분말특성은 주사전자현미경(scanning electron microscope), 투과전자현미경(transmission electron microscope), 형광분광광도계(fluorescence spectrophotometer) 및 접촉각측정기(contact angle analyzer)를 이용하여 조사되었다. 형광체 분말의 플라즈마 코팅 후 접촉각이 $133.0^{\circ}$(물)와 $140.5^{\circ}$(글리세롤)로 증가하여 표면이 소수성으로 변화되었음을 확인하였으며, 광발광(photoluminescence)은 최대 7.8%의 향상을 나타냄을 알 수 있었다. 플라즈마 코팅 후 형광체 표면의 주사전자현미경 및 투과전자현미경 사진을 통해 낟알형상의 표면조직이 박막 코팅 층으로 덮여 있고, 코팅 층은 31~46 nm 가량의 두께로 형성되어 있음을 확인하였다. 발광다이오드(3528 1 칩 LED)에 형광체를 실장한 후 $85^{\circ}C$와 85% 상대습도에서 1,000시간 동안 신뢰성 테스트(85-85 Test)를 수행한 결과 코팅이 되지 않은 경우와 비교하여 코팅후의 형광체가 광도 저하율에서도 개선 효과를 보이는 것으로 나타났다. 본 연구의 유전체장벽방전 플라즈마 코팅 방법은 불규칙한 입자 형태의 형광체 분말 표면을 입체적으로 코팅하여 제품의 신뢰성을 향상시킬 수 있는 방법으로 판단된다.