• Title/Summary/Keyword: 시차적 교환

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Characteristics of the Library Services Market (도서관 서비스 시장의 특성)

  • Kim, Giyeong
    • Journal of the Korean Society for information Management
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    • v.32 no.3
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    • pp.183-197
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    • 2015
  • The purpose of this conceptual paper is to identify the library services market and its characteristics versus the common commodity market so that marketing and management in library services can be more fruitful in terms of research and development. Based on the developed hypothetical market, a library services market is identified; the market is then characterized in comparison to the common commodity market using three theoretical characteristics of the library services market: indirect exchange, limited competition, and time-lagging exchange. Based on these characteristics, two possible research directions are suggested: development of goals for library management and consideration of applications in library marketing.

Studies on the Sorption and Fixation of Cesium by Vermiculite (II)

  • Lee, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.6 no.2
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    • pp.97-111
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    • 1974
  • The adsorption mechanism of Cs-137 in low level radioactive solution by vermiculite treated with Na ion is studied in order to investigate its effective utilization for the radioactive effluent treatment. The beneficial role of Na-vermiculite is that Na ion can induce the wider c-axis spacing in which Cs ion can be sorbed in vermiculite. Cation exchange capacity and distribution coefficient of cesium seems to be influenced by the variation of c-axis spacing of vermiculite. Comparative identification and detection with the characteristic analyses of X-ray diffraction and electron diffraction patterns, diffrential thermal analysis and electron microscopy of Na-, K- and Cs-vermiculite are studied for the phemomena of Cs adsorption by vermiculite. This importance of the utilization in terms of adsorption and fixation of cesium involving vermiculite is discussed. It is found that the Na-vermiculite is valuable outside charging material for high level radioactive liquid waste storage tank of underground to protect the pollution of the underground water.

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Assessment of Physicochemical Properties of Domestic Bentonite and Zeolite as Candidate Materials for a Engineered Barrier in a Radwaste Repository (방사성폐기물 처분장 공학방벽 재료로서의 국산 벤토나이트 및 제올라이트에 대한 물리화학적 특성 평가)

  • 정찬호
    • The Journal of Engineering Geology
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    • v.9 no.2
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    • pp.89-100
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    • 1999
  • This study was carried out to assess the physicochemical properties of domestic bentonites and zeolites from Tertiary Formation as the candidate material for a engineered barrier of a radioactive waste repository. Natural bentonite and zeolite samples were collected from nine bentonite mines and six zeolite mines in Yeonil-Gampo area. The commercial products of bentonite and zeolite were obtained from local companies. The collected samples were investigated to study the following physicochemical properties: X-ray diffraction patterns, swelling, cation exchange capacity(CEC), specific surface area, montmorillonite content, pH, organic carbon content, thermal property, microstruciure and chemical composition. Based on the physicochemical properties of bentonite and zeolite, the bentonites from U-41 and G-46 mines and the zeolites from Daedo and Y-1 mines are regarded as the most desirable candidate materials.

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Differential Thermal Analysis and Quantum Chemical Consideration for Catalytic Stability of Ion Exchanged Faujasite Type Zeolite 1. Ni2+-Faujasite계 (이온교환된 Faujasite형 제올라이트의 촉매적 안정성에 대한 시차열분석 및 양자화학적 고찰; 1. Ni2+-Faujasite계)

  • Kim, Myung-Chul;Kim, Jong-Taik
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.75-81
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    • 1993
  • The thermochemical stability of $Ni^{2+}-faujasite$ was studied by differential thermal analysis(DTA), thermal gravitational analysis(TGA), X-ray diffraction analysis(XRD) and quantum chemical calculations. Dehydration of $Ni^{2+}-faujasite$ was observed at 373-773K. A CNDO/2 calculations have been applied on cluster models for the representative T sites in faujasite to get total energy and wiberg bond orders. It has proved that the decrease of zeolitic crystallinity is directly related to the weakening of Al-O bonds in framework.

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Miscibility and Transesterification Reaction of blends of Polyarylate and Thermotropic Liquid Crystalline Polymer (Polyarylate와 열방성 액정고분자 블렌드의 상용성 및 에스터 교환반응에 대한연구)

  • 진선우
    • The Korean Journal of Rheology
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    • v.10 no.1
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    • pp.50-56
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    • 1998
  • 폴리아릴레이트(PAr)와 열방성 액정고분자(LCP)블렌드의 상용성과 두 고분자 사이 의 에스터 교환반응을 시차 주사 열분석기 (DSC)와 Fourier transform 적외선 분광분석기 (FT-IR spectroscopy)로 연구하였다. DSC를 이용하여 PAr-LCP 블렌드의 유리전이온도 (Tg)를 관찰한 결과, 두 개의 Tg가 관찰되었다. 측정된 Tg 결과로부터 블렌드 각 상에 녹아 있는 두성분의 상거동을 조사했으며 그결과 LCP가 PAR-rich 상에 녹아 들어간 양이 PAr 이 LCP-rich 상에 녹아 들어간 양보다 더 많음을 알수 있었다. 이러한 결과는 두 고분자 사 이에 부분적으로 상용성이 있음을 의미한다. 액정고분자의 이방성을 고려하여 PAr-LCP 블 렌드의 고분자-고분자 상호작용계수($\chi$12)는 0.069~0.076의 값으로 계산되었다. 두 고분자사 이의 에스터 교환반응를 조사하기 위하여 DSC내에서 열처리한 결과, 열처리 후에 PAr과 LCp의 Tg는 열처리하기 전에 비해 더 큰폭으로 두 Tg의중간값으로 이동하였다. 열처리한 PAr-LCP 블렌드를 FT-IR spectroscopy로 분석한 결과, 순수한 PAr과 LCP에 없는 새로운 에스터기의 특성피이크가 발견되었다. 이와 같은 열분석과 FT-IR spectroscopy 연구 결과 로부터 주어진 열처리 조건에서 PAr과 LCP 사이에 에스터 교환반응이 일어났음을 확인할 수 있었다.

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Thermal and Physical Properties of Poly(butylene succinate)/Poly(${\varepsilon}$-caprolactone) Copolyesters Prepared by Transesterification (에스테르 교환반응으로 제조된 Poly(butylene succinate)/Poly(${\varepsilon}$-caprolactone) Copolyesters의 물리적 및 열적 성질에 관한 연구)

  • Yoo, Young-Tai;Yang, Su-Bong;Im, Seung-Soon
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.486-495
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    • 2001
  • Degradable poly(butylene succinate) (PBS)/poly(TEX>${\varepsilon}$-caprolactone) (PCL) copolyesters were prepared by using transesterification between poly(butylene succinate) and poly(TEX>${\varepsilon}$-caprolactone). The thermal and mechanical properties of copolyesters were investigated using differential scanning calorimetry and tensile testing. Interchange reaction between PBS and PCL molecules could be identified from proton NMR spectra. The reduced viscosity of the PBS/PCL copolyesters increased with reaction time except for a series of PBS/PCL (50/50 wt%) copolyesters. For all the compositions, the melting point and crystallization temperature of high-$T_m$ component (PBS) decreased as reaction time increased. From the results of tensile testing, it was found that stress and strain at break of the PBS/PCL copolymers containing less than 40 wt% PCL improved as compared to those of pure PBS, but at 50 wt% PCL stress at break of PBS/PCL copolymers was lowered due to decrease of crystallinity. On the other hand, Young's moduli of all the copolyesters decreased with both reaction time and PCL content.

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Some Mineralogical and Physico-Chemical Properties of Fuller's Earths from Tertiary Sediments in South Korea (삼기층중(三紀層中)에서 산출(産出)되는 산성백토(酸性白土)에 관(關)한 광물학적(鑛物學的) 조성(組成) 및 물리화학적(物理化學的) 성질(性質)에 관(關)하여)

  • Moon, Hee Soo;Morgan, D.J.
    • Economic and Environmental Geology
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    • v.16 no.3
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    • pp.149-161
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    • 1983
  • Fuller's earth deposits from Miocene sedimentary sequences in Gyeong Sang-do contain up to 95% Ca-montmorillonite accompanied by cristobalite, clinoptilolite, mordenite, quartz, feldspar and X-ray amorphous material. Differential thermal analysis, infrared and electron microscopic data are given for the montmorillonite component. The ease with which the exchangeable calcium of the montmorillonite could be replaced by sodium (to give a product with properties similar to that of a bentonite) was monitored by the Atterberg liquid limit test. Some samples tested as possible binders for foundry moulding sands gave results that compared favourably with material currently being used for this application. Many of the samples also met the OCMA specifications for clays used in drilling muds.

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A Study of Physicochemical Characteristics and Adsorption properties of Cs and Sr of Natural Zeolite from Kuryongpo in Korea (한국 구룡포산 천연 제올라이트의 이화학적 특성 및 Cs과 Sr 흡착 특성 연구)

  • Bayarsaikhan Battsetseg;Hu Sik Kim;Hyeon Uk Choo;Jong Sam Park;Woo Taik Lim
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.2
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    • pp.117-124
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    • 2023
  • X-ray diffraction analysis, X-ray fluorescence analysis, thermal differential and thermos gravimetric analysis, cation exchange capacity analysis, and Cesium (Cs), Strontium (Sr) adsorption experiments were performed to investigate the physical and chemical properties of natural zeolite from Guryongpo in Korea. As a result of X-ray diffraction analysis, minerals such as mordenite, heulandite, clinoptilolite, and illite are contained, and as a result of X-ray fluorescence analysis, elements such as SiO2, Al2O3, CaO, K2O, MgO, Fe2O3 and Na2O are contained, and the cation exchange capacity was 148.6 meq/100 g. As a result of thermal differential and thermos gravimetric analysis, it was confirmed that the thermal stability was excellent up to 600 ℃. As a result of the adsorption equilibrium experiment over time, the equilibrium was reached within 30 min. for Cesium (Cs) and within 8 hr. for Strontium (Sr), and the adsorption rates of Cesium (Cs) and Strontium (Sr) were 80% and 18%, respectively. As a result of the single-component isothermal adsorption experiment, in conformed to the Langmuir model, and the maximum Cesium (Cs) adsorption amount was 131.5 mg/g, which was high, while the Strontium (Sr) maximum adsorption amount was 29.5 mg/g, which was low. In the case of the natural zeolite used in this study, the content of minerals including 8-rings such as clinoptilolite, heulandite, and mordenite is high, showing high selectivity for Cesium (Cs).

The Effect of the Membrane Fluidity of Bellflower(Platycodon grandiflorum A.) Fractions on Liposomal Phospholipid Membranes (도라지 분획성분이 인지질막 Liposome의 유동성에 미치는 영향)

  • 배송자;강보영
    • Journal of Life Science
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    • v.12 no.2
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    • pp.121-128
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    • 2002
  • The object of this study was to investigate the effect of membrane fluidity of bellflower(Platycodon grandiflorum A. DC, ; PG) fractions in phosphatidylcholine(PC) liposomes, measured with high-sensitivity differential scanning calorimetry(DSC). We used dipalmitoylphosphatidylcholine(DPPC) bilayers which slake most stable liposomes among the other phosphatidylcholine. The sample PG was extracted and fractionated to five different types : butanol(PGMB), ethylacetate(PGMEA), ethylether(PGMEE), hexane (PGMH) and methanol(PGMM). Among five different solvent fractions, the PGMEE, PGMEA, PGMH and PGMM fractions markedly affected the thermotropic properties of DPPC liposomes, broadened and shifted the thermograms, and reduced the cooperative unit. It might be said that the incorporation of PGMEE, PGMEA and PGMH in DPPC liposomes were located in the hydrophobic core of DPPC bilayers and, PGMM and PGMB in the hydrophilic core of DPPC bilayers. These results suggest that certain substances in the PGMEE, PGMEA and PGMH fractions might have biologically significant effect on the membrane fluidity.

The Effect of Daucus carota L. Extracts on the Fluidity of Phospholid Liposomes (당근추출물이 인지질막 Liposome의 유동성에 미치는 영향)

  • 신미옥;배송자
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.4
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    • pp.646-650
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    • 2001
  • In this study, we investigated the thermotropic behavior of Daucus carota L. (DCS) extracts in phosphatidylcholine(PC) liposomes using high-sensitivity differential scanning calorimetry (nano-DSC). We used dipalmitoylphosphatidylcholine (DPPC) bilayers which made most stable liposomes among the other phosphatidylcholine. The sample DCS was extracted and fractionated to four different types, hexane(DCSMH), ethylacetate (DCSMEA), butanol (DCSMB) and aqueous(DCSMA) fractions. Compared to the other fractions of Daucus carota L., the DCSMH and DCSMEA fractions markedly affected the thermotropic properties of DPPC liposomes, broadened and shifted the thermograms of transition to lower temperatures. The incorporation of DCSMH and DCSMEA in DPPC liposomes were preferentially located in the hydrophobic core of DPPC bilayers, where it reduced the lipid packing orderness (cooperative unit) in the gel state compared to it in the liquid-crystalline state. These results suggest that the activities of the Daucus carota L. extracts to enhance the fluidity of the liposomal membrane have implication in their biological activities.

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