• Title/Summary/Keyword: 시멘트 클링커

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Utilization of Scheelite Mine Tailing as Raw Material of Ordinary Portland Cement (보통포틀랜드시멘트 원료로서 회중석 광미의 활용)

  • 김형석;정수복;김완태;안지환;채영배
    • Resources Recycling
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    • v.13 no.3
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    • pp.19-26
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    • 2004
  • In order to use the mine tailing which was generated in the flotation process of scheelite ore into the raw material of ordinary portland cement, the characteristics of the prepared cement clinker was investigated. Scheelite mine tailing is composed of 68.8% of $SiO_2$, 8.6% of $Al_2$$O_3$, 10.8% of $Fe_2$$O_3$, 5.0% of CaO, respectively. It exists as $\alpha$-quartz, muscovite, clinochlore and has 8.0% of 88 $\mu\textrm{m}$ residue. When LSF, SM, and IM of the raw materials (such as limestone, convertor slag, fly ash, and mine tailing) are 91.0, 2.60, and 1.60, respectively, the burnability index of the raw materials is 50.7, the crystal size of $C_3$S and $\beta$-C$_2$S in the prepared clinker is 15∼35$\mu\textrm{m}$, and about 3.8% of scheelite mine tailing can be used as raw material.

Study on Burnability and Reactivity of High Al2O3 Content OPC Clinker for the Use of Industrial Waste (산업부산물 활용을 위한 고Al2O3 함량 OPC 클링커의 소성성 및 반응성에 관한 연구)

  • Kang, Bong-Hee;Choi, Jaewon;Ki, Tae-Kyoung;Kwon, Sang-Jin;Kim, Gyu-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.294-301
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    • 2020
  • This study evaluated the burnability and hydration reaction of clinker burned with high Al2O3 content OPC to apply large amounts of industrial by-products in the cement manufacturing process. Specifically, after preparing a clinker with a high C3A content by burning the OPC raw material with a high content of Al2O3 in a laboratory electric furnace, the burnability of the clinker was evaluated through XRD Rietveld analysis and polarization microscopy, and clinker hydration reactivity was reviewed through the Isothermal conduction calorimetry analysis and the cement compressive strength. As a result, the kiln burning temperature for the production of high Al2O3 content clinker lower, and the compressive strength was equal to or higher than OPC. Therefore it was confirmed the possibility to manufacturing energy-saving high Al2O3 content clinker using a large amount of industrial by-products.

CaO Optimal Classification Conditions for the Use of Waste Concrete Fine Powder as a Substitute for Limestone in Clinker Raw Materials (폐콘크리트 미분말을 클링커 원료의 석회석 대체재로 사용하기 위한 CaO 최적 분급 조건)

  • Ha-Seog Kim;Sang-Chul Shin
    • Land and Housing Review
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    • v.15 no.1
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    • pp.147-156
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    • 2024
  • This study aims to reduce CO2 generated during the manufacturing process by using limestone (CaCO3), a carbonate mineral used in the production of cement clinker, as a decarbonated raw material that does not contain CO2. Among various industrial by-products, we attempted to use cement paste attached to waste concrete. In general, limestone for cement must have a CaCO3 content of at least 80% (CaO, 44% or more) to ensure the quality of cement clinker. However, the CaO content of waste concrete fine powder is about 20% on average, so in order to use it as a cement clinker raw material, the CaO content must be increased to more than 35%. Therefore, by using the difference in hardness of the mineral composition of waste concrete fine powder to selectively crush CaO type minerals with relatively low hardness, classify and sieve, the CaO content can be increased by more than 35%. Accordingly, in this study, we experimentally and statistically reviewed and analyzed the optimal conditions for efficiently separating CaO and SiO2 and other components by selectively pulverizing minerals containing relatively low CaO through a grinding process. As a result of the optimal grinding conditions experiment, it was found that the optimal conditions were a grinding time of less than 5 minutes, a type of material to be crushed of 30 mm, and an amount of material to be crushed of 1.0 or more. However, it is judged that it is necessary to review pulverized materials of mixed particle sizes rather than pulverized products of single particle size.

Analysis of Cement Clinker Minerals According to Burning Conditions (광학현미경을 이용한 소성 조건별 시멘트 클링커 광물의 특성 변화)

  • Chu, Yong-Sik;Kim, In-Seob;Lee, Jong-Kyu
    • Journal of the Korean Ceramic Society
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    • v.41 no.11
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    • pp.819-825
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    • 2004
  • The characteristic analysis of cement clinker using light microscope can evaluate not only the quality of cement but also making process. Thus this study analyzed clinkers having different burning conditions by reflective light microscope. As heating and cooling rates is decreased, alite and belite minerals grew and especially cooling rate had an effect on the growth of belite. Futhermore as the retention time in max. temperature got longer by twenty minutes, alite and belite minerals grew more about 5 $\mu\textrm{m}$. In the case of temperature 1400$^{\circ}C$ in max, the size of belite was suitable but alite was not suitable with the size of 10~15 $\mu\textrm{m}$.

Evaluation of Self-Healing Performance Using Hydration Model of Portland Cement and Clinker (포틀랜드시멘트와 클링커의 수화모델을 이용한 자기치유 성능평가)

  • Choi, Sang-Hyeon;Park, Byoung-Sun;Cha, Soo-Won
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.81-87
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    • 2020
  • Crack control is essential to increase the durability of concrete significantly. Healing of crack can be controlled by rehydration of unreacted clinkers at the crack surface. In this paper, by comparing the results of isothermal calorimetry test and regression analysis, the Parrot & Killoh's cement hydration model was verified and clink er hydration model was proposed. The composition and quantification of hydration products were simulated by combining kinematic hydration model and thermodynamic model. Hydration simulation was conducted using the verified and proposed hydration model, and the simulation was performed by the substitution rate of clink er. The type and quantity of the final hydration product and healing product were predicted and, in addition, the optimal cementitious material of self-healing concrete was selected using the proposed hydration model.