• Resources Recycling
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• v.13 no.3
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• pp.19-26
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• 2004

In order to use the mine tailing which was generated in the flotation process of scheelite ore into the raw material of ordinary portland cement, the characteristics of the prepared cement clinker was investigated. Scheelite mine tailing is composed of 68.8% of $SiO_2$, 8.6% of $Al_2$$O_3$, 10.8% of $Fe_2$$O_3$, 5.0% of CaO, respectively. It exists as $\alpha$-quartz, muscovite, clinochlore and has 8.0% of 88 $\mu\textrm{m}$ residue. When LSF, SM, and IM of the raw materials (such as limestone, convertor slag, fly ash, and mine tailing) are 91.0, 2.60, and 1.60, respectively, the burnability index of the raw materials is 50.7, the crystal size of $C_3$S and $\beta$-C$_2$S in the prepared clinker is 15∼35$\mu\textrm{m}$, and about 3.8% of scheelite mine tailing can be used as raw material.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.364-372
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• 2023

By applying coarse-grained limestone and unprocessed coal ash as sintering raw materials for cement clinker, the microstructure and distribution of chemical components of cement clinker were compared and examined. Samples using coarse limestone as a raw material for cement clinker showed a decrease in sinterability compared to samples using reagent-grade raw materials. Samples using coal ash showed a tendency for some increase in sinterability. In samples using coarse limestone and coal ash, the formation of Belite was high at 1350 ℃. The conversion rate from Belite to Alite was high in the range of 1350~1450 ℃. Samples using coal ash showed stable formation of interstitial phase in the range of 1350 to 1450 ℃. The microstructure and chemical composition distribution of cement clinker sintered at 1350~1450 ℃ showed that all samples showed a form and composition distribution in which the calcium silicate phase and interstitial phase were clearly distinguished.

• Cement Symposium
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• no.30
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• pp.49-62
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• 2003

• Cement Symposium
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• no.32
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• pp.41-48
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• 2005

• Cement Symposium
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• no.32
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• pp.155-161
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• 2005

• Cement
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• s.112
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• pp.21-29
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• 1988

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.4
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• pp.514-519
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• 2020

In this study, cement clinkers were sintered at each temperature by replacing some of the clay components of cement clinkers with coal materials. The mineral phase change of sintered cement clinker was quantitatively analyzed by XRD-Rietveld method. As the sintering temperature of cement clinker increased, the amount of belite decreased, the amount of alite increased, and the amount of free-CaO decreased. The form of alite and belite could be distinguished at sintering temperature of 1450℃ or higher. The crystal size was greatly increased at 1500℃ sintering. It was confirmed that the excessive sintering was progressed. Free-CaO decreased with the increase of sintering temperature. At 1450 ℃ or higher, it was less than 0.5%. In 1450℃ or greater, it is determined that enough sintering is included. Therefore, the application of fly ash as a raw material of cement clinker was judged to be usable as a source of chemical components of alumina and iron raw materials.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.211-218
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• 2022

Coal ash is being considered as a source of silica and alumina for cement clinker. The purpose of this study was to investigate the effect on cement clinker sintering by confirming the high-temperature microstructural change according to the firing temperature in the cement clinker sintering process of coal ash. In the coal ash used as a raw material for cement clinker, the shape change of the particle surface was confirmed from the sintering tem perature of 950 ℃. The shape of the coal ash disappeared from the sintering temperature higher than 1250 ℃. It was confirmed that the Al and Fe components of the coal ash were converted to the cement interstitial phase at a temperature higher than 1350 ℃. In addition, the clinker using a large amount of coal ash as a raw material showed a low content of Lime and a high content of Belite in the sintering tem perature range of 1150~1200 ℃. From this, it was confirmed that the formation of calcium silicate mineral proceeds more easily at the initial sintering temperature by the application of coal ash.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.33 no.6
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• pp.210-215
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• 2023

Raw mix burnability is an especially crucial factor in cement manufacturing technology, and it depends on the physical, chemical and mineralogical properties of each raw material. In this article, we compared the difference of burnability between the domestic and Japanese fly ash as cement raw materials by using Lafarge and Polysius evaluation method. Regardless of the type or amount of fly ash used, it was found to be more combustible when using fly ash. In both case, burnability improves as the amount of fly ash increases, especially the improvement in bunarbility is remarkable up to 3%. In conclusion, as the amount of fly ash increases within the range allowed by cement quality, burnability of raw materials improves, and thus the fuel cost required for the firing of clinker can also be expected to be reduced.

• Proceedings of the KAIS Fall Conference
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• 2001.05a
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• pp.300-302
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• 2001

폴리카본산계 기능성 고분자를 합성해서 고성능 감수제 원료로 활용하여 고유동화 혼화제를 개발하고자 한다. 폴리카본산계 기능성 고분자를 합성한 후, 이를 고유동, 고강도 혼화제 원료로의 제반 물성을 확인하고, 이를 현장에 적용하여 현재의 제품을 획기적으로 개선하고, 혼화제 품질의 우위성을 확보하기 위해 1) 시멘트 및 골재 표면에서의 적절한 계면활성을 갖는 분자설계를 하였으며, 2)분자량의 조절 기술의 개발을 개발하였다. 합성에 있어서 첫째, 시멘트 및 골재 표면에서의 적절한 계면활성을 갖는 분자설계와 둘째, Mw 5,000정도의 분자량을 갖는 감수제의 합성기술을 개발하였다. 이렇게 제조된 고성능 유동화제의 화학구조 해석을 해석하고 분자량 및 분자량 분포를 측정한 다음, 시멘트 페이스트의 유동성, 점도, 슬럼프로스 등을 측정하여 고성능 유동화제의 성능인 시멘트 페이스트의 유동성을 시험하였다. 그 결과 고유동성을 갖는 것과 장시간 안정한 유동성을 나타내었으며, 경과 시간에 따른 겉보기 점도변화를 측정한 결과 점도의 상승이 초기에 일어나다가 시간의 경과에 따라 점도가 감소하는 경향을 나타내었다. 따라서 경과시간에 따른 유동성 손실을 억제할 것으로 기대한다.