• Title/Summary/Keyword: 시멘트 수화반응

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Properties and Prediction Model for Ultra High Performance Fiber Reinforced Concrete (UHPFRC): (I) Evaluation of Setting and Shrinkage Characteristics and Tensile Behavior (초고성능 섬유보강 콘크리트(UHPFRC)의 재료 특성 및 예측모델: (I) 응결 및 수축 특성과 인장거동 평가)

  • Yoo, Doo-Yeol;Park, Jung-Jun;Kim, Sung-Wook;Yoon, Young-Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.5A
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    • pp.307-315
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    • 2012
  • Recently, ultra high performance fiber reinforced concrete (UHPFRC) having over 180 MPa compressive strength and 10 MPa tensile strength has been developed in Korea. However, UHPFRC represents different material properties with normal concrete (NC) and conventional high performance concrete (HPC) such as a high early age autogenous shrinkage and a rapid dry on the surface, because it has a low water-binder ratio and high fineness admixtures without coarse aggregate. In this study, therefore, to propose suitable experimental methods and regulations, and to evaluate mechanical properties at a very early age for UHPFRC, setting, shrinkage and tensile tests were performed. From the setting test results, paraffin oil was an appropriate material to prevent drying effect on the surface, because if paraffin oil is applied on the surface, it can efficiently prevent the drying effect and does not disturb or catalyze the hydration of cement. From the ring-test results, it was defined that the shrinkage stress is generated at the time when the graph tendency of temperature and strain of inner steel ring is changed. By comparing with setting test result, the shrinkage stress was firstly occurred as the penetration resistance of 1.5 MPa was obtained, and it was about 0.6 and 2.1 hour faster than those of initial and final sets. So, the starting time of autogenous shrinkage measurement (time-zero) of UHPFRC was determined when the penetration resistance of 1.5 MPa was obtained. Finally, the tensile strength and elastic modulus of UHPFRC were measured from near initial setting time by using a very early age tensile test apparatus, and the prediction models for tensile strength and elastic modulus were proposed.

Reduction of pH of Recycled Fine Aggregate due to Natural and Artificial Treatment Method (자연 및 인위적 처리방법 변화에 따른 순환잔골재의 pH저감)

  • Han, Cheon-Goo;Han, Min-Cheol;Han, Sang-Yoon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.103-110
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    • 2011
  • This study is to comparatively analyze the characteristics of pH decrease in recycled fine aggregates for embankment and landfill produced from waste concrete by using natural process and artificial process. The result was as follows In case of recycled fine aggregates left outdoor, it was found that pH level was decreased if the thickness of embankment becomes thinner, or the materials left outdoors owing to high concentration of $CO_2$ in atmosphere caused by respirations of people. When the air was permeated, pH level was decreased more effectively. It was analyzed that this phenomenon was caused by efficient supply of $CO_2$ in the recycled fine aggregates owing to high-pressure ventilators. In case of water spraying treatment, sprayed water facilitated hydration of unhydrated cement to dissolve calcium hydroxides which neutralized $CO_2$ in the atmosphere during desiccation process and decrease pH level by a considerable margin. In case of Immersed treatment, decrease of pH was not sufficient. When facilitating the supply of $CO_2$, pH level of the recycled fine aggregates was decreased by the largest margin. It was analyzed that this phenomenon was caused by efficient supply of $CO_2$. From the above results, it was analyzed that the most effective method of reducing pH level of the recycled fine aggregates from the aspects of pH reduction performance, economic efficiency and workability was repeated wet-dry cycles of spraying water to the aggregates in the proportion of 1:0.5 by weight and then treating by forcefully blowing $CO_2$ gas into the aggregates.

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A Study on Properties of Retarder via Tabletting Method (정제화 방법을 이용한 응결 지연제의 특성에 관한 연구)

  • Ryou, Jae-Suk;Yang, Neung-Won;Lee, Yong-Soo
    • Journal of the Korea Concrete Institute
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    • v.25 no.2
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    • pp.201-207
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    • 2013
  • When hot weather concrete is utilized, the cooling methods of cooling pipe, liquid nitrogen, ice, etc., are used to prevent the poor consistency and cold joint due to high temperature. These methods, however, spike the production cost and energy consumption, and make quality control difficult. Among these methods is one that involves the use of a retarder. Although economical, retarder is caused difficulty of retarded hardening and setting time control due to inaccurate weighing and poor working condition. Therefore, how to make a tablet for hot weather concrete, as with the existing pharmacy and foods, is discussed in this study, including the following items: mortar setting time, flow test by elapsed time, physical and mechanical properties of concrete. As a result, gluconic acid is superior to lignosulfonic acid and the possibility of using them for such purpose without quality degradation was confirmed in this study, when retarder is tabletting.

Autogenous Shrinkage of Very-Early Strength Latex-Modified Concrete with Latex Contents (라텍스함량 변화에 따른 VES-LMC의 자기수축)

  • Park, Won-Il;Choi, Pan-Gil;Yun, Kyong-Ku;Lee, Bong-Hak
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.3
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    • pp.1059-1065
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    • 2010
  • Very-early strength latex-modified concrete (VES-LMC) was developed for the purpose of fast-track overlay of a concrete bridge deck under heavy traffic, concentrated on the workability, durability, and strength gain so that it can be opened to the traffic only three hours after its placement. The mixture of VES-LMC might accompany very high heat of hydration at early-age because of its inherent rapid hardening property and could have susceptibility to autogenous shrinkage because of its relatively low water-cement ratio. This study evaluated the effect of the latex-cement ratio(L/C) both of the constant and variable slumps on the autogenous shrinkage of VES-LMC by carrying out simple temperature rise test and early-age shrinkage experiment. Test results are as follows: The latex contributes on the enhancement of the concrete durability but has little effect on its hydration and the accompanied heat of hydration in VES-LMC. Autogenous shrinkage increased with the increase in latex-cement ratio at variable slumps and its pattern followed regularly a logarithmic increase. However, the influence of water-cement ratio and latex-cement ratios for the test specimens at constant slump on early-age autogenous shrinkage property was found to be minor due to the simultaneous effect of the two experimental variables.

The Properties of OPC-Slag Cement Mixed with Nano-Silica Solution by Mixing Water Weight Replacement Method (나노실리카 졸을 배합수 중량치환 방법으로 혼합한 OPC-slag cement의 특성)

  • Seo, Ki-Young;Kim, Taewan;Kim, Seong-Do
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.1
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    • pp.24-34
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    • 2020
  • This research is a study on the characteristics of OPC-slag cement using nano-silica solution (NSS) with water-weight substitution method. The new replacement method is a fundamental step to study the behavior of cement with higher NSS replacement rates than previous studies. NSS was replaced by 10%, 20%, 30%, 40%, and 50% of the mixing water weight. As a result, the mechanical and microstructural characteristics were improved. This can be summarized in two ways. First, when the NSS is replaced with mixing water, the homogeneous dispersion action of the nano-silica particles is improved. This promotes initial hydration. Second, substitution of NSS with higher density than mixing water reduces w / b. This forms a dense hydration reaction material. The new substitution method did not show any degradation of mechanical and microstructural properties as compared with the results using the powdered nano-silica particles revealed in the previous study. Therefore, it is considered that the method of weight substitution of NSS used in this study can be applied to the formulation of OPC-slag cement.

An Experimental Study on the Mechanical Healing Properties of Self-Healing Mortar with Solid Capsules Using Crystal Growth Type Inorganic Materials (결정성장형 무기재료 활용 고상 캡슐을 혼합한 자기치유 모르타르의 역학적 치유 특성에 관한 실험적 연구)

  • Choi, Yun-Wang;Nam, Eun-Joon;Oh, Sung-Rok;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.581-589
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    • 2020
  • In this paper, a solid capsule was prepared using a crystal growth type inorganic material capable of hydration reaction, the quality and mechanical healing properties of self-healing mortar with solid capsules were evaluated. Solid capsules were mixed 5% by mass of cement. Reloading test results of compressive load, it was found to improve about 20% on average for the natural healing effect of Plain, in the case of the elastic range, the healing rate was about 79% at the 7 days of healing age and 98% at the 28 days of healing age. Reload test results of flexural load, in the case of the elastic range, the healing rate was about 79% at the 7 days of healing age and 98% at the 28 days of healing age. Through these results, it is judged that the healing performance of solid capsules has also an effect on mechanical healing properties such as strength in addition to the durability properties obtained by the permeability test. Since the strength tends to decrease as the solid capsules are mixed, it is considered necessary to compensate.

A Experimental Study on the Ready-mixed Shotcrete Using Granulated Blast Furnace Slag (고로슬래그 미분말을 혼입한 레디믹스트 숏크리트의 현장적용성에 관한 실험적 연구)

  • Choi, Hee-Sup;Kim, Dong-Min;Jang, Pil-Sung;Seo, Sin-Seuk
    • Journal of the Korean Geotechnical Society
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    • v.25 no.6
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    • pp.31-45
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    • 2009
  • The aim of this study is to evaluate the applicability of Granulated Blast Furnace Slag to the development of the Powdered Ready-mixed Shotcrete. First of all, after accomplishing SEM analysis and Leaching Test, the laboratory and field experiments for evaluating the utility of Granulated Blast Furnace Slag were performed. As a result of SEM and Leaching test, the environmental stability was confirmed. That is, non-detection of harmful lists and dense shotcrete structure result from mixing Granulated Blast Furnace Slag. As a result of lab. and field test, Blast Furnace Slag is superior to Plain Batch in improving strength and durability. And it will be able to improve to some extent the problem caused by the delayed reaction of existing Granulated Blast Furnace Slag with alkali activated material. Also the proper amount of Granulated Blast Furnace Slag is estimated to be under 30%. Finally, it is possible that Granulated Blast Furnace Slag can apply to economical recycling and development of the Ready-mixed Shotcrete for its price is only about 5% of Silica-finne's price.

Properties of Chemically Activated MSWI(Municipal Solid Waste Incinerator) Mortar (도시 폐기물 소각재를 이용한 화학적 활성화 모르타르의 특성)

  • Jo, Byung-Wan;Kim, Kwang-Il;Park, Jong-Chil;Park, Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.18 no.5 s.95
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    • pp.589-594
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    • 2006
  • The recycling of industrial wastes in the concrete manufacturing is of increasing interest worldwide, due to the high environmental impact of the cement and concrete industries and to the rising demand of infrastructures, both in industrialized and developing countries. The production of municipal wastes in the South Korea is estimated at about 49,902 ton per day and only 14.5% of these are incinerated and principally disposed of in landfill. These quantities will increase considerably with the growth of municipal waste production, the progressive closing of landfill, so the disposal of municipal solid waste incinerator(MSWI) ashes has become a continuous and significant issue facing society, both environmentally and economically. MSWI ash is the residue from waste combustion processes at temperature between $850^{\circ}C\;and\;1,000^{\circ}C$. And the main components of MSWI ash are $SiO_2,\;CaO\;and\;Al_2O_3$. The aim of this study is to find a way to useful application of MSWI ash(after treatment) as a structural material and to investigates the hydraulic activity, compressive strength development composition variation of such alkali-activated MSWI ashes concrete. And it was found that early cement hydration, followed by the breakdown and dissolving of the MSWI-ashes, enhanced the formation of calcium silicate hydrates(C-S-H). The XRD and SEM-EDS results indicate that, both the hydration degree and strength development are closely connected with a curing condition and a alkali-activator. Compressive strengths with values in the 40.5 MPa were obtained after curing the activated MSWI ashes with NaOH+water glass at $90^{\circ}C$.

Field Applicability of Scale Prevention Technologies for Drainage Holes (배수공 내 스케일 생성 방지 기술의 현장 적용성 평가)

  • Chu, Ickchan;Lee, Jonghwi;Kim, Hyungi;Kim, Kyungmin;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.9
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    • pp.45-51
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    • 2012
  • The calcium hydroxide$(Ca(OH)_2)$ which is the cement hydrate flowed into the tunnel by groundwater is reacted with microorganism in the soil, carbon dioxide$(CO_2)$ and the vehicle's exhaust gas$(SO_3)$. So its by-products are precipitated at the drainage pipe and these cause the drainage clogging. By this phenomenon, Degradation of water flow at the drainage system of the tunnel occurred and also pore water pressure is increased. Hence the acceleration of seepage and degradation of lining is occurred. The purpose of this study is to evaluate the field applicability of the Quantum Stick and Magnetic treatment in prevention of scale deposits at the Namsan ${\bigcirc}{\bigcirc}$ tunnel and the Zone ${\bigcirc}{\bigcirc}{\bigcirc}$ of subway. These technologies were installed into drainpipes with their performance monitored through occasional site visits. SEM and XRD were also performed on scale collected from these drainpipes. As a result, in case which factor technology is applied, scale creation is remarkably decreased and especially Quantum Stick treatment performing better than Magnetic treatment. Therefore, additional application of Quantum Stick or Magnetic treatment to the existing drainage is expected to decrease the drainage clogging of the drainage.

The Density and Strength Properties of Lightweight Foamed Concrete Using Stone-Powder Sludge in Hydrothermal Reaction Condition (수열반응 조건에서 석분 슬러지를 사용한 경량 기포 콘크리트의 밀도와 강도 특성)

  • Kim, Jin-Man;Jeong, Ji-Yong;Choi, Se-Jin;Kim, Bong-Joo
    • Journal of the Korea Concrete Institute
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    • v.18 no.5 s.95
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    • pp.687-693
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    • 2006
  • The Stone Powder Sludge(below SPS) is the by-product from the process that translates stone power of 8mm under as crushed fine aggregate. It is the sludge as like cake that has average particle size of $7{\mu}m$, absorbing water content of 20 to 60%, and $SiO_2$ content of 60% over. Because of high water content of SPS, it is not only difficult to handle, transport, and recycle, but also makes worse the economical efficiency due to high energy consuming to drying. This study is aim to recycle SPS as it is without drying. Target product is the lightweight foamed concrete that is made from the slurry mixed with pulverized mineral compounds and foams through hydro-thermal reaction of CaO and $SiO_2$. Although in the commercial lightweight foamed concrete CaO source is the cement and $SiO_2$ source is high purity silica powder with $SiO_2$ of 90%, we tried to use the SPS as $SiO_2$ source. From the experiments with factors such as foam addition rate and replacement proportion of SPS, we find that the lightweight foamed concrete with SPS shows the same trends as the density and strength of lightweight foamed concrete increases according to decrease of foam addition rate. But in the same condition, the lightweight foamed concrete with SPS is superior strength and density to that with high purity silica. This trends is distinguished according to increase of replacement proportion of SPS, also the analysis of XRF shows that the hydro thermal reaction translates SPS to tobermorite. Although SPS has low $SiO_2$ contents, the lightweight foamed concrete with SPS has superior strength and density, because it reacts well with CaO due to extremely fine particles. We conclude that it is possible to replace the high purity silica as SPS in the lightweight foamed concrete experimentally.