• Title/Summary/Keyword: 시멘트 대체재료

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A Study on the Engineering Characteristics of Soil - Fly Ash - Bentonite Liner (플라이애시-벤토나이트 혼합 점토차수재의 공학적 특성에 관한 연구)

  • Lee, Changhwan;Kim, Myeongkyun
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.6
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    • pp.21-29
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    • 2008
  • As household and industrial wastes continue to rapidly increase every year, the demands for landfill sites are also increasing. However, the construction of landfill sites causes many problems due to the high costs of liners, while the leachate from the landfills generates secondary contamination of surrounding lands and groundwater. The purpose of this study is to determine the proper mixing ratio to meet the liner conditions (must be less than $1{\times}10^{-7}cm/sec$), using the local soil as the main material and using fly ash, bentonite, and cement as the mixing materials. The possibility of using this mixture as the liner for landfill sites was examined. To determine the proper mixing ratio, this study conducted basic physical properties tests, compaction tests, consolidation tests, and uniaxial compression tests. It was found that the higher the ratio of bentonite, the lower the coefficient of permeability, and the higher the ratio of fly ash, the higher the coefficient of permeability. The reason for this is that, while bentonite expands and fills pores, fly ash cannot fill the pores because the particles have a round shape and do not have adhesion. In conclusion, the optimum coefficient of permeability that meets the landfill liner condition was obtained when the ratio of bentonite was 15% or higher. If fly ash was mixed, the landfill liner condition was met when the ratio of bentonite was 15% or higher and the ratio of fly ash was 20% or lower.

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A Study on the Reinforcement Effect Analysis of Aging Agricultural Reservoir using Surface Stabilizer (표층안정재를 사용한 노후 농업용 저수지의 보강효과 분석에 관한 연구)

  • Kim, Jae-Hong;Kim, You-Seong;Cho, Dae-sung
    • Journal of the Korean Geosynthetics Society
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    • v.19 no.2
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    • pp.13-21
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    • 2020
  • In Korea, small reservoirs have been constructed for the supply of agricultural water, but most of them have been over 50 years from the year of construction. Aging agricultural reservoirs are being investigated for serious defects such as leaks and movements in slope, which are very vulnerable to safety. Accordingly, grouting methods are used to reinforce aging agricultural reservoirs in Korea. However, cement used as a grouting injection material consumes natural resources and generates a large amount of greenhouse gases during production. In addition, there is a problem that sufficient reinforcement is not made due to various factors such as the injection amount, the compounding ratio, the injection pressure, and etc. Therefore, due to these problems, the development of new materials and methods that can replace the grouting method and cement is required. In order to solve these problems, this study conducted an laboratory test on the surface stabilizer used to secure the stability of road and rail slopes. In addition, the program was analyzed and the reinforcing effect was examined when the surface stabilizer was used as reinforcement material for aging agricultural reservoir. As a result of the laboratory test, when the surface stabilizer is mixed, the increase of cohesion is possible up to 9% and there is no change in the friction angle. The results of the program analysis showed that the 1.0m reinforcement of slopes increased the factor of safety by 1.4 times, making it possible to reinforce the aging agricultural reservoir using surface stabilizers. And as a reinforcement method, it was analyzed that it is most appropriate to reinforce the slope and the bottom of slope simultaneously.

Effect of Blast Furnace Slag and Desulfurized Gypsum on Hardening of CFBC Boiler Coal Ash (CFBC 보일러 석탄회의 경화에 대한 고로슬래그, 탈황석고의 영향)

  • Lee, Woong-Geol;Kim, Jin-Ho;Kim, Kyung-Nam;Song, Myong-Shin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.443-450
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    • 2021
  • The effects of blast furnace slag(BFS) and desulfurized gypsum(FDG) on the compressive strength of CFBA, and self-hydration of CFBA were studied. CFBA has self-hydrating and hardening properties, and it can be seen that the compressive strength of CFBA can be improved by using appropriate amounts of BFS and FDG. In addition, the self-hardening properties of CFBA are similar to the hydration reaction of 4CaO·Al2O3·Fe2O3 (C4AF), a cement clinker mineral, and when free-CaO, CaSO4 and CaCO3 coexist, Compressive strength of CFBA is expressed by the formation of calcium carbo compounds and hydrates of ettringite, calcium silicate, and calcium aluminate.

NOx Reduction Performance in Cement Mortar with TiO2 Treatment and Mineral Admixture (무기계 혼화재료를 혼입한 모르타르 시편의 광촉매 처리를 고려한 NOx 저감 성능)

  • Yoon, Yong-Sik;Kim, Hyeok-Jung;Park, Jang-Hyun;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.506-513
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    • 2020
  • In this study, the mechanical properties, absorption, and reduction performance of NOx in the mortar containing mineral admixture like zeolite and active hwangtoh were evaluated. Zeolite and active hwangtoh were used as binder, and zeolite and active hwangtoh were substituted for cement. The substitution ratio of two types of mineral admixtures was considered as 20 and 30% respectively. As a result of evaluating the compressive strength and flexural strength of each mortar specimen, the highest strength in the plain mixture was evaluated. As the substitution ratio of zeolite and active hwangtoh increased, the compressive and flexural strength decreased. In addition, the difference of compressive and flexural strength between active hwangtoh and zeolite mixing was evaluated to be insignificant. To evaluate the absorption rate, the mixture was designed to lower the W/B ratio of the existing mixture and set the substitution ratio of active hwangtoh and zeolite at 25%. The highest absorption ratio in the mortar with zeolite was evaluated, and the difference in absorption ratio between the remaining two mortar mixtures was small. The assessment of reduction performance of NOx considering the application of photocatalyst showed a clearly decreasing reduction behavior, even if they were the same mortar mixture. Zeolite and active hwangtoh also showed a higher NOx reduction than the Plain mixture, because of their porosity properties. In the case of active hwangtoh, the absorption ratio was lower than that of zeolite mixture, but the reduction of NOx performance was better than the result of zeolite mixture.

Mechanical Properties Evaluation of 3D Printing Recycled Concrete utilizing Wasted Shell Aggregate (패각 잔골재를 활용한 3D 프린팅 자원순환 콘크리트의 역학적 성능 평가)

  • Jeewoo Suh;Ju-Hyeon Park;Tong-Seok Han
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.37 no.1
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    • pp.33-40
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    • 2024
  • The volume of shells, a prominent form of marine waste, is steadily increasing each year. However, a significant portion of these shells is either discarded or left near coastlines, posing environmental and social concerns. Utilizing shells as a substitute for traditional aggregates presents a potential solution, especially considering the diminishing availability of natural aggregates. This approach could effectively reduce transportation logistics costs, thereby promoting resource recycling. In this study, we explore the feasibility of employing wasted shell aggregates in 3D concrete printing technology for marine structures. Despite the advantages, it is observed that 3D printing concrete with wasted shells as aggregates results in lower strength compared to ordinary concrete, attributed to pores at the interface of shells and cement paste. Microstructure characterization becomes essential for evaluating mechanical properties. We conduct an analysis of the mechanical properties and microstructure of 3D printing concrete specimens incorporating wasted shells. Additionally, a mix design is proposed, taking into account flowability, extrudability, and buildability. To assess mechanical properties, compression and bonding strength specimens are fabricated using a 3D printer, and subsequent strength tests are conducted. Microstructure characteristics are analyzed through scanning electron microscope tests, providing high-resolution images. A histogram-based segmentation method is applied to segment pores, and porosity is compared based on the type of wasted shell. Pore characteristics are quantified using a probability function, establishing a correlation between the mechanical properties and microstructure characteristics of the specimens according to the type of wasted shell.

A Feasibility Study on the Deep Soil Mixing Barrier to Control Contaminated Groundwater (오염지하수의 확산방지를 위한 대체 혼합차수재의 적용에 관한 연구)

  • 김윤희;임동희;이재영
    • Journal of Soil and Groundwater Environment
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    • v.6 no.3
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    • pp.53-59
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    • 2001
  • There is a lot of method to manage the insanitary landfill but vertical cutoff walls have been widespreadly used and were installed into the subsurface to act as a barrier to horizontal groundwater flow, The stabilized material such as specialized cement or mixed soil with additives has been generally applied for the materials of the deep soil mixing barrier in korea. The amount of the stabilized material is dependent on the field conditions, because the mixing ratio of the material and the field soil should achieve a requirement in the coefficient of permeability, lower than 1.0$\times$$10^{7}$cm/sec. This study determined the quantity and optimized function ratio of the stabilized material in the formation process of the mixed barrier that was added with stabilized material on the field soil classified into SW-SC under USCS (Unified Soil Classification System). After that the fly ash and lime were selected as an additives an that could improve the function of the stabilized material and then the method to improve the functional progress in the usage of putting into the stabilized material as an appropriate ratio was studied and reviewed. The author used the flexible-wall permeameter for measuring the permeability and unconfined compressive strength tester for compressive strength, and in the view of environmental engineering the absorption test of heavy metals and leaching test regulated by Korean Waste Management Act were performed. As the results, the suitable mixing ratio of the stabilized material in the deep soil mixing barrier was determined as 13 percent. To make workability easy, the ratio of stabilized material and water was proven to be 1 : 1.5. With the results, the range of the portion of the additives(fly ash : lime= 70 : 30) was proven to be 20-40% for improving the function of the stabilized material, lowering of permeability. In heavy metal absorption assessment of the mixing barrier system with the additives, the result of heavy metal absorption was proved to be almost same with the case of the original stabilized material; high removal efficiency of heavy metals. In addition, the leaching concentration of heavy metals from the leaching test for the environmental hazard assessment showed lower than the regulated criteria.

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A Study on the Method for Quantifying CO2 Contents in Decarbonated Slag Materials by Differential Thermal Gravimetric Analysis (DTG 분석법을 활용한 슬래그류 비탄산염 재료의 CO2 정량 측정방법 연구)

  • Jae-Won Choi;Byoung-Know You;Yong-Sik Chu;Min-Cheol Han
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.8-16
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    • 2024
  • Limestone (CaCO3, calcium carbonate), which is used as a raw material in the portland cement and steel industry, emits CO2 through decarbonation by high temperatures in the manufacturing process. To reduce CO2 emissions by the use of raw materials like limestone, it has been proposed to replace limestone with various industrial by-products that contain CaO but less or none of the carbonated minerals, that cause CO2 emissions. Loss of Ignition (LOI), Thermogravimetric analysis (TG), and Infrared Spectroscopy (IR) are used to quantitative the amount of CO2 emission by using these industrial by-products, but CO2 emissions can be either over or underestimated depending on the characteristics of by-product materials. In this study, we estimated CO2 contents by LOI, TG, IR and DTG(Differential Thermogravimetric analysis) of calcite(CaCO3) and samples that contain CO2 in the form of carbonate and whose weight increases by oxidation at high temperatures. The test results showed for CaCO3 samples, all test methods have a sufficient level of reliability. On the other hand, for the CO2 content of the sample whose weight increases at high temperature, LOI and TG did not properly estimate the CO2 content of the sample, and IR tended to overestimate compared to the predicted value, but the estimated result by DTG was close to the predicted valu e. From these resu lts, in the case of samples that contain less than a few percent of CO2 and whose weight increases during the temperature that carbonate minerals decompose, estimating the CO2 content using DTG is a more reasonable way than LOI, TG, and IR.

Study on Characteristics of Controlled Low Strength Material Using Time Domain Reflectometry (시간영역반사법을 이용한 유동성 채움재의 특성 연구)

  • Han, Woojin;Lee, Jong-Sub;Byun, Yong-Hoon;Cho, Samdeok;Kim, Juhyong
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.4
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    • pp.33-37
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    • 2016
  • The hydration process of Controlled Low Strength Material (CLSM) used for backfill is the primary factor to determine the construction period. The objective of this study is to monitor the hydration process of CLSM using the Time Domain Reflectometry (TDR) and to establish the relationship between dielectric constant and compressive strength. The CLSM specimen is composed of cement, flyash, silt, sand, accelerator, and water. The material characteristics of the CLSM including flow, unit weight, compressive strength are investigated. To measure the dielectric constant of the CLSM during the curing time, TDR probe incorporated with a mold and a reflectometer are used. Experimental results show that the dielectric constant remains constant at early stage, and then decreases as the curing time increases. In addition, the dielectric constant is related to the compressive strength in inverse power function. This paper suggests that the TDR technique may be used as a non-destructive testing method in order to estimate the compressive strength of the CLSM mixture under construction.

An Experimental Study on the Resistance to Penetration of Harmful Ions in Surface Coatings Material Containing Organic Corrosion inhibitor (유기계 방청제를 혼입한 표면피복재의 유해이온 침투저항에 관한 실험적 연구)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.2
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    • pp.157-166
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    • 2017
  • In general, carbonation and chlorine ions are the most harmful causes of deterioration of concrete structures. Recently, a method has been developed to control the corrosion of rebar in concrete containing chloride by impregnating a Surface coating material with a inhibitor. In this study, accelerated carbonation and differential thermogravimetric analysis (TG-DTA) and CASS tests were carried out to evaluate the characteristics of Surface coatings containing Organic Corrosion inhibitors which are excellent in corrosion inhibition and fix degradation causes $CO_2$ and $Cl^-$. As a result of the experiment, TG-DTA analysis and accelerated carbonation showed that $CO_2$ was directly reacted with amine derivative in concrete by the incorporation of Organic Corrosion inhibitor. In other words, $CO_2$ was immobilized and carbonation inhibition effect was confirmed. In addition, in the CASS test, the specimen coated with the Surface coating material containing the Organic Corrosion inhibitor with $Cl^-$ fixing property showed no corrosion until the 28th day and had excellent performance in preventing corrosion of a rebar by the chloride ion.

Material Characteristic of POFA Concrete and Its Application to Corrosion Resistance Evaluation (POFA 콘크리트의 재료특성 및 부식 저항성 평가로의 적용)

  • Lee, Chang-Hong;Song, Ha-Won;Ann, Ki-Yong;Ismail, Mohamed Abdel
    • Journal of the Korea Concrete Institute
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    • v.21 no.5
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    • pp.565-572
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    • 2009
  • In this study, corrosion resistance of palm oil fuel ash (POFA) concrete as a blended concrete is evaluated by using electrochemical technique. The POFA is an industrial byproduct obtained from fuel ash after extracting palm oil from palm-tree. In order to obtain basic material characteristics of the POFA concrete, tests on compressive strength, slump, weight loss, bleeding and expansion ratio were carried out the early-aged POFA concrete. On the other hand, durability characteristics, both chloride penetration and carbonation depth test, were also conducted. Finally, corrosion resistance were evaluated by applying electro-chemical artificial crack healing technique, and the tests on the impressed voltage characteristic, galvanic current and linear polarization resistance. From the experimental results, it was found that long-term strength, bleeding, lower slump ratio, expansion ratio, chloride penetration, carbonation and corrosion resistance were improved by using the POFA due to activated pozzolanic reaction. It can be also mentioned that POFA concrete has a potential to be used as a cementitious binder for green-recycling resources.