• Title/Summary/Keyword: 시멘트계

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Explosion Characteristics of Bituminous Coal Dusts in Cement Manufacturing Process (시멘트 제조공정에서 유연탄 분진의 폭발특성)

  • Kim, Won-Hwai;Lee, Seung-Chul;Seung, Sam-Sun;Kim, Jin-Nam
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.2
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    • pp.257-263
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    • 2008
  • We have examined explosion characteristics of bituminous coal dusts in cement manufacturing process. In order to find the thermal properties, we investigated weight loss and ignition temperature of coal materials using TGA and DSC. Also specific surface area of dust was investigated. Dust explosion experiments with Hartman's dust explosion apparatus have been conducted by varying concentration and size of coal dust for explosion probability and lower limit explosion concentration. According to the results for thermal properties, there is a little change by dust size. However, the specific surface area of dust is increased by decreasing dust size. The explosion test results show that small size and increasing concentration of dusts make dust explosion easier. And we find that the lower limit explosion concentration of bituminous coal is $0.3mg/cm^3$ and the probability is 100% on $0.9mg/cm^3$ in 170/200 mesh used in cement manufacturing process.

Surface Properties of Exposed-Aggregate Concrete Depending on Retarder and Water Jet Washing Timing (지연제 살포량과 물씻기 시간이 골재노출 콘크리트의 표면성상에 미치는 영향)

  • Park, Jun Hui;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.2
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    • pp.169-175
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    • 2015
  • Recently, a stone is preferred as a cladding materials because of its outstanding durability and luxurious character. However, because of running out of natural resources and restriction of production, it is expected that difficulty of stable supply, and thus alternative cladding materials for concrete wall is needed. Therefore, in this research, as an alternative cladding materials, exposed-aggregate concrete is studied using saccharin based retarder. For evaluating factors, changing water-to-cement ratio, dosages of saccharin-based retarder, and timing of water jet washing were tested on the surface properties of exposed-aggregate concrete. As a result, the most favorable surface performance was obtained at 0.75 day after the placing in 25% of water-to-cement ratio, and at one day after the placing in 35 and 55% of water-to-cement ratio, 1.5 day after the placing in 65% of water-to-cement ratio with $24m{\ell}/m^2$ of retarder application.

Development of High-Toughness Concrete Using the Mixed Materials for CO2 Reduction (CO2 저감용 혼합재를 사용한 고인성 콘크리트의 개발)

  • Yi, Seong Tae;Heo, Hyung Seok;Noh, Jae Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.3
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    • pp.89-96
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    • 2013
  • Now-a-days, a manhole adopted since the late 1990s and produced using the polymer concrete has widely used due to the various benefits. While entering the High oil prices times, however, and with the price increase of the petrochemical materials, the cost of manufacture of polymer concrete was elevated and the resulting polymer concrete's weakness is being put on. Accordingly, the development of economic cement concrete manholes, which can replace the outstanding bending strength of manhole made of high-price polymer concrete, has been required. In this study, based on the cement technology of fast hardening armorphous calcium aluminate (ACA), by minimizing the amount of cement using the industrial byproducts, to develop the eco-friendly high-toughness concrete manhole, which can reduce $CO_2$ reduction, was intended. As the results, the cement concrete manhole, which economic, eco-friend, and meeting the performance requirements, was developed.

Early Hydration of Portland Cement-Blast furnace Slag System by Impedance Techniques (임피던스 측정법을 이용한 포틀랜드 시멘트 -고로 슬래그계의 초기수화)

  • 송종택;김훈상;황인수
    • Journal of the Korean Ceramic Society
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    • v.39 no.1
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    • pp.99-107
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    • 2002
  • Impedance Spectroscopy (IS) has been used to study microstructure and hydration mechanism of cement pastes. In this work, the early hydration behaviour of portland cement paste with different blame values and contents of blast-furnace slag was investigated by IS. As slag was added to portland cement, the values of $R_{t(s+1)}$ (the solid-liquid phase resistance) and $R_{t(int)}$ were decreased in the early hydration period. It showed that hydration of cement paste containing slag was slower than it of the reference cement paste. As the content of slag was increased, the values of $R_{t(s+1)}$ was decreased. Furthermore, the diameter of semicircle, $R_{t(int)}$ observed at 72 hours was decreased with the increment of slag content. However, the values of $R_{t(s+1)}$ and $R_{t(int)}$ were increased with blame value of slag from the early hydration period.

The Hydration Characteristics of High-Durable Portland Cement Treated with Asphalt and Carbon Black (ASPHALT와 CARBON BLACK으로 처리(處理)된 고내구성(高耐久性) 포틀랜드시멘트의 수화특성(水化特性))

  • Cho, Heon-Young;Kim, Hee-Rack;Hong, Won-Pyo
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.148-155
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    • 1992
  • For the enhancement of the concrete durability, we developed high - durable portland cement (ACTPC) by physical treatment of ordinary portland cement with asphalt and carbon black. In this research, the hydration reaction characteristics of ACTPC were studied by using SEM, X-Ray, Conduction Micro Calolimeter etc. When the ACTPC is mixed with water, it is believed the asphalt films on cement particles suppress the early stage of hydration reactions of cements, because the films hinder the contact with water and the elusion of soluble ions from particles. But the carbon blacks on the cement particles accelerated the hydration reactions of cement after a while, because the micro particles can be used as seed crystals in $CaO-SiO_2-H_2O$ gel formation.

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Recovery of C-14 in the Cement Waste Form (농축폐액 시멘트 고화체로부터 C-14 회수 특성)

  • Ahn Hong-Joo;;Lee Jeong-Jin;Pyo Hyung-Yeal;Han Sun-Ho;Jee Kwang-Young
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.284-289
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    • 2005
  • According to the nuclear safety regulation policy including the administration of radionuclides in low level radwastes, the evaporator bottoms were mixed with cement to form a stable solidification for identifying the recovery possibility of the C-14. The chemical oxidation method was applied for the extraction of C-14 from the cement waste form. The emitting beta ray of the C-14 extracted from the radwastes was measured with the liquid scintillation counter and calculated by using the quenching correction curves. Only the beta emitting radioactive nuclides of the C-14 in the radwastes was showed the radioactivities with the range of $2.7E+00\;{\sim}\;3.07E+02$ Bq/g.

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Experimental Study on the Development and Application of High-Performance Composite Utilizing Industrial Wasts Products for Construction Works -Carbon Fiber Reinforced Fly Ash.Cement Composites- (산업폐기물을 이용한 건재용 고성능복합체의 개발 및 응용에 관한 실험적 연구 -탄소섬유 보강 플라이애쉬.시멘트 복합체-)

  • 박승범;이보성;윤의식
    • Magazine of the Korea Concrete Institute
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    • v.3 no.3
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    • pp.101-110
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    • 1991
  • Results of an experimental study on the manufacture, the mechanical properties and watertightness of pitch - based carbon fiber reinforced fly ash. cement composites are presented in this paper. The carbon fiber reinforced fly ash. cement composites using early strength cement silica powder and a small amount of stylene butadiene rubber latex are prepared with carbon fiber, foaming agents and mixing conditions. As a result, the mechanical and physical properties such as compressive , tensile and flexural strengths, watertightness and drying shrinkage of lightweight carbon fiber reinforced fly ash cement composites are Improved by using a samll amount of stylene butadiene rubber latex. Also, the manufacturing pnx:ess technology of carbon fiber reinforced fly ash . cement composItes is developed. The development and applications of precast products of lightweight carbon fiber remforced cement composites are expected in the near future.

Pore and Efflorescence Characteristics of Alkali Activated Slag-Red Mud Cement Mortar depending on Red Mud Content (레드머드 대체율에 따른 알칼리활성화 슬래그-레드머드 시멘트 모르타르의 기공 및 백화특성)

  • Kang, Suk-Pyo;Kang, Hye-Ju
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.3
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    • pp.261-268
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    • 2017
  • Red mud is an inorganic by-product obtained from the mineral processing of alumina from Bauxite ores. A highly alkali inorganic waste product with a pH level over 11, red mud in its original state negatively impacts the ecosystem, so appropriate treatment is necessary. The development of alkali activated slag-red mud cement can be a representative study aimed at recycling the strong alkali of the red mud as a construction material. However, Alkali-activated binders that use sodium activators have been reported to be more vulnerable to efflorescence. Therefore, in this study, the compressive strength, pore characteristics, water absorption, elution characteristics, and efflorescence properties of alkali-activated slag cement mortar were assessed according to their red mud substitution ratio.

An Experimental Study on Indoor Pollutant Reduction of Cementitious Composite Using Charcoal and Phytoncide (숯과 피톤치드를 사용한 시멘트계 복합재의 실내 오염물질 저감에 관한 실험적 연구)

  • Jeong, Hyeon-Woo;Jeong, We-Young;Jung, Yoong-Hoon;Han, Song-Yi;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.13-19
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    • 2021
  • In modern society, indoor activities time is increasing due to industrial development. Interest in indoor air quality is increasing as indoor activity time increases. The main causes of indoor air pollution are formaldehyde which a chemical cause, and fungi which a biological cause. Phytoncide effectively reduces Formaldehyde and Fungi. Charcoal which possess porous-structure has a good absorbance of pollutants. In this study, the authors manufactured functional cement matrix using by phytoncide and charcoal to remove formaldehyde and fungi. In this study, Functional cement matrix reduced formaldehyde and Fungi and effectively improve indoor air quality.

Relationship between Compressive Strength and Dynamic Modulus of Elasticity in the Cement Based Solid Product for Consolidating Disposal of Medium-Low Level Radioactive Waste (중·저준위 방사성 폐기물 처리용 시멘트 고화체의 압축강도와 동탄성계수의 관계)

  • Kim, Jin-Man;Jeong, Ji-Yong;Choi, Ji-Ho;Shin, Sang-Chul
    • Journal of the Korea Concrete Institute
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    • v.25 no.3
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    • pp.321-329
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    • 2013
  • Recently, the medium-low level radioactive waste from nuclear power plant must be transported from temporary storage to the final repository. Medium-low level radioactive waste, which is composed mainly of the liquid ion exchange resin, has been consolidated with cementitious material in the plastic or iron container. Since cementitious material is brittle, it would generate cracks by impact load during transportation, signifying leakage of radioactive ray. In order to design the safety transporting equipment, there is a need to check the compressive strength of the current waste. However, because it is impossible to measure strength by direct method due to leakage of radioactive ray, we will estimate the strength indirectly by the dynamic modulus of elasticity. Therefore, it must be identified the relationship between of strength and dynamic modulus of elasticity. According to the waste acceptance criteria, the compressive strength of cement based solid is defined as more than 3.44 MPa (500 psi). Compressive strength of the present solid is likely to be significantly higher than this baseline because of continuous hydration of cement during long period. On this background, we have tried to produce the specimens of the 28 day's compressive strength of 3 to 30 MPa having the same material composition as the solid product for the medium-low level radioactive waste, and analyze the relationship between the strength and the dynamic modulus of elasticity. By controling the addition rates of AE agent, we made the mixture containing the ion exchange resin and showing the target compressive strength (3~30 MPa). The dynamic modulus of elasticity of this mixtures is 4.1~10.2 GPa, about 20 GPa lower in the equivalent compressive strength level than that of ordinary concrete, and increasing the discrepancy according to increase strength. The compressive strength and the dynamic modulus of elasticity show the liner relationship.