• Title/Summary/Keyword: 시멘트계

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시멘트를 이용한 지반개량 및 시멘트계 건설폐기물의 재활용에 의한 환경오염

  • Min, Soo-Hong;Moon, Se-Heum
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.267-267
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    • 2008
  • 시멘트를 이용한 지반개량 및 시멘트계 건설폐기물을 (예, 폐콘크리트, 및 시멘트 개량토 등) 성토재로 재활용하는 경우 지반 환경에 미칠 수 있는 영향으로는 (1) 시멘트에 함유된 6가 크롬($Cr^{6+}$) 및 (2) 강알칼리 물질의 용출이 있을 수 있다. 특히 $Cr^{6+}$의 경우 인체에 치명적인 발암성물질로 알려져 있어 이에 따른 주의가 필요하다. 최근 일본에서는 시멘트의 $Cr^{6+}$에 의한 지반오염이 우려됨에 따라 2000년 시멘트계 고화재를 지반에 사용하는 경우와 개량된 토양을 재이용하는 경우에는 토양환경기준을 만족하도록 규제하고 있다. $Cr^{6+}$외의 시멘트계 물질에 의한 환경오염으로는 강알칼리 물질의 유출이 있을 수 있다. 시멘트 개량토나 폐콘크리트 등의 건설폐기물을 성토재로 재활용하는 경우, 강우의 유입에 따라 구성물질인 수산화칼슘이 용해되어 높은 pH의 유출수가 발생한다. 강알칼리 유출수가 주변 하천 등으로 유입되는 경우 심각한 환경문제를 유발할 수 있으므로 이에 대한 기술적 검토가 필요하다. 본 발표에서는 시멘트계 물질에 의한 일본의 지반환경오염 사례 및 대책을 소개하였다.

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Effect of the Polycarboxylates on the Physical Properties of Cement Materials (폴리카르본산계 고분자가 시멘트계 재료의 물성에 미치는 영향)

  • 조헌영;서정목;전기석;이기환;김진만
    • Journal of the Korea Concrete Institute
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    • v.13 no.4
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    • pp.354-361
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    • 2001
  • In this paper, three kinds of poly(acrylate-co-methylacrylate) with different number average molecular weight(Mn) were synthesized and studied for the effects on the mechanical properties and the fluidities of the cement mortar admixtured with them. The physical properties of the cement mortar are more favorably enhanced by the poly(acrylate-co-methylacrylate) of Mn,, 5,000 than that of Mn, 2,000∼3,000. And the optimum dosage was decided to ca. 0.6 % of cement weight in cement mortar. However, the dispersion abilities of the polymers in cement mortar was not kept long time. This last result could not be explained by the theory that the fluidity of the cement mortar added with the slow releasing polycarboxylates is kept by the releasing of the carboxylic group of the copolymer in alkaline solution of cement paste.

Literature Review on Rheological Properties and Required Performances of 3D Printable Cementitious Materials (3D 프린팅 시멘트계 재료의 유변학적 물성과 요구 성능에 관한 문헌 조사)

  • Oh, Sangwoo;Hong, Geuntae;Choi, Seongcheol
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.41-49
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    • 2021
  • 3D printing techniques have been recently adopted in the construction industry. It mainly utilizes additive manufacturing which is the fabrication process depositing successive layers of materials without any formworks. Conventional cementitious materials may not be directly applicable to 3D printing because 3D printable cementitious materials is required to satisfy such characteristics as pumpability, extrudability, and buildability in a fresh state. This study aimed to investigate rheological properties and required performances of 3D printable cementitious materials, by reviewing existing studies. Test methods and equipments, evaluation results and characteristics of mixture additives were compared. Based on reviews of existing studies, this study indicates that the viscosity is mainly relevant to the pumpability of 3D printable materials whereas the yield stress and thixotropy are important in securing buildability of the materials.

Evaluation on the Deterioration and Resistance of Cement Matric due to Seawater Attack (시멘트 경화체의 해수침식에 의한 성능저하 및 저항성 평가)

  • 문한영;이승태;김홍삼
    • Journal of the Korea Concrete Institute
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    • v.13 no.2
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    • pp.175-183
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    • 2001
  • Immersion tests with artificial seawater were carried out to investigate the resistance to seawater attack of 5 types of cement matrices. From the results of compressive strength and length change, it was found that blended cement mortars due to mineral admixtures, were superior to portland cement mortars with respect to the resistance to seawater attack. Moreover, XRD analysis indicated that the peak intensity ratio of low heat portland cement(LHC) paste, in portland cement pastes, had better results, and so did that of blended cement Paste. Pore volume of pastes by mercury intrusion porosimetry method demonstrated that total pore volume of ordinary portland cement(OPC) paste had a remarkable increase comparing with that of other pastes. In case of immersion of artificial seawater, the use of ground granulated blast-furnace slag and fly ash, however, showed the beneficial effects of 56% and 32% in reduction of total pore volume, respectively.

Effects of Concrete Superplastizers on the Cement Wettability and the Strength Properties of Cocreate Mortar (콘크리트 유동화제가 시멘트 입자의 표면 젖음성 및 콘크리트 몰타르 경화물성에 미치는 영향)

  • Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.21 no.4
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    • pp.457-462
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    • 2010
  • In this research, the effects of the concrete superplastizers on the wettability of cement particle and concrete strength were studied. The wettability of the cement particles strongly depended on the type of the superplastizer. When the superplastizer had a higher wettability with the cement particles, it revealed a good fluidity of the concrete mortar and a higher concrete strength. Non-ionic superplastizers (polycarboxylic type) had a relatively good performance on the mortar fluidity and concrete strength properties compared to anionic superplastizers (lignosulfate, sulfonated naphthalene formaldehyde, sulfonated melamin formaldehyde). It was observed that the blending of the polycarboxylic and the lignosulfate type concrete superplastizers resulted in synergistic effects on the concrete mortar fluidity and concrete strength properties.

A Study on the Flexural Fatigue Behavior of R/C Beams Repaired with Concrete-Polymer Composites (유기 및 유기재료로 보수된 R/C 보의 휨 피로거동에 관한 연구)

  • 심종성;황의승;배인환;이은호
    • Magazine of the Korea Concrete Institute
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    • v.7 no.6
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    • pp.233-241
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    • 1995
  • In this thesis, the fatigue tests were performed on a series of R /C beams repaired with co& crete-lmlyrner composites to investigate the fatigue bahavior. The three point loading system is used in the fatigue tests. In these tests, relations between the repeated loading cycles and mid-span deflections, number of repeated loading cycles when repaired beams were fractured, the bonding performance of repair materials were observed. On this basis, the mid-span deflections, the crack growth and failure mode of repaired R /C beams were studied. A S-N curve was drawn to present the fatigue strength of repaired beams. From the test results, it was shown that behavior of R /C beams repaired with polymer-cement series were very sirnillar to control beam about bonding performance, mid-span deflections and fatigue strength according to S-N curve drawn by the regression anlysis on the fatigue test results.