• Korean Journal of Soil Science and Fertilizer
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• v.39 no.1
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• pp.21-28
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• 2006

We investigated the mobilization of Cd, Pb, and Cr in two different soils in response to sorption capacities and competition for available sorption site while they moved under saturated water conditions. Two soil samples that were clay and sandy clay loam were collected within 20 cm from the upland surface. To do this, we used three different systems of heavy metal combinations such as single, binary, and ternary as solution phase. And then we observed the breakthrough curve (BTC) and elution as a function of pore volume by applying heavy metal solution and displacing K solution until these curves reached to maximum and minimum. The results showed that BTC and elution curves were not symmetric and it required more pore volumes with increasing species of heavy metals in solution phase, as well as longer tailings. Compared the areas over and under BTC and elution curve, relatively small amount of heavy metal was displaced by K even though there were differences in electronegativity among heavy metals. Conclusively, we assumed that heavy metals transport in soil could be influenced by soil physical nonequilibrium and chemical equilibrium in solution as far as there were more than two species of heavy metals existed.

• Korean Journal of Soil Science and Fertilizer
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• v.38 no.4
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• pp.202-210
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• 2005

Since understanding on spatial variability of a field is essential to pursue precision agricultural technology, a field study for field variability and variable rate fertilization of nitrogen in a direct seeding paddy was attempted. Variable rate application of nitrogen was designed with soil test, and field application was tested in a direct seeding paddy in the Kimje, Jeonbuk, Korea. The grid samples of soil was collected from the field of which unit size was 35 m by 112 m on February before irrigating of the field. Soil organic matter, available phosphate and silicate, and extractable potassium were analyzed. Variable rate fertilizer recommendation maps of nitrogen for high yielding, HY, and low input sustainable agriculture, LISA, were derived based on the soil analysis. Direct seeding of rice was performed for variable rate treatment, VRT, for the experimental plot in 2001 and 2002, and so did for three volunteer farmers' field in 2003. Yield mapping was performed by harvesting. Economic feasibility of direct seeding of rice by variable rate fertilization was evaluated. Though increased yield of variable rate application and benefit of reducing fertilizer use and environmental impact, the cost for soil test exceeded the total reduced fertilizer cost.

• Journal of Food Hygiene and Safety
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• v.34 no.5
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• pp.431-437
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• 2019

This study was conducted to develop a simultaneous analysis method for ferulic acid, caffeic acid, catechin and taxifolin from Health Functional Food (HFF) Pinus Pinaster bark extract. The simultaneous analytical method for ferulic acid, caffeic acid, catechin and taxifolin is carried out using UPLC-MS/MS. The method validation was performed to determine selectivity, linearity, accuracy, limit of detection (LOD), limit of quantification (LOQ) and precision for ferulic acid, caffeic acid, catechin and taxifolin. LC-MS/MS method was established using an Acquity UPLC BEH $C_{18}$ Column and was applied for these 4 compounds. Product-ion traces, at m/z $194.2{\rightarrow}133$, $180.2{\rightarrow}135$, $290.3{\rightarrow}245$, $304.3{\rightarrow}248$, were used for quantitative analysis of ferulic acid, caffeic acid, catechin and taxifolin, respectively. Excellent linearity ($r^2=0.999$) was observed for ferulic acid, caffeic acid, catechin and taxifolin in the concentration range (50-2500 mg/L). The observed recoveries of these 4 compounds were found to be between 84.9 and 104.9%, while precision was between 1.20 and 4.43% relative standard deviation (% RSD).

• Journal of the Korean Society of Urban Environment
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• v.18 no.4
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• pp.455-463
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• 2018

This study was carried out to assess the distribution and pollution level of organic matters and nutrients in surface sediments of the Yeongsan River Basin. The surface sediments were collected from the mainstream (12) and tributaries sites (4) for two years from 2015 to 2016, and the particle sizes, organic matters (Ignition Loss, COD, TOC) and nutrients (TN, TP, SRP) were analyzed. The distribution of particle sizes was dominated by sand in the upstream sites (MS1-MS7) and by silt loam in the downstream sites (MS8-MS12), but MS3 and MS6, located slightly upstream of the two weirs, were found to be mostly loamy sand and silt loam, respectively. As a results of the correlation assessment, the organic matters (IL, COD, TOC) were strongly correlated with particle sizes, while the nutrients (TP, SRP) were weak except for TN. The concentrations of organic matter and nutrient were higher at the downstream and the sites nearby the two weirs (MS3, MS6). In particular, the TP concentration at the MS3 site sampled in the second half period of the years was higher than that in the first half periods. Comparing of sediments criteria, the organic matters and nutrients were evaluated to have almost no toxic effects at all sites.

• Journal of the Korean Geotechnical Society
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• v.37 no.6
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• pp.29-37
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• 2021

Since many geotechnical structures are constructed on a weathered granite layer, it is important to evaluate their characteristics. As a seismic design is the more important nowadays, the demands to estimate a shear wave velocity (V_S) based on acceptable methods are increasing. In this study, an empirical equation predicting V_S of the weathered granite layer is suggested based on the nonlinear multiple variable regression analysis whose independent variables are both SPT (Standard penetration test)-N₆₀ and chemical weathering index. It is concluded that the accuracy of the empirical equation estimating V_S of the weathered granite layer increases when it considers the chemical weathering index as an additional independent variable compared to the result of simple regression analysis using only N₆₀.

• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.208-216
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• 2022

Surface morphology and adsorption characteristics of black and white charcoals prepared from Korean traditional kiln were quantitatively analyzed. TGA and elemental analysis of charcoals were different from produced kiln, and thermal degradation temperature and carbon content of white charcoals were apparently higher than those of black charcoals. Surface morphology shows the activation progressed through the longitudinal direction of woods and new micropores were developed to radial direction on the surface of macropores as the furthermore activation resulting in the pore connection. BET adsorption isotherms show that there are low-pressure hysteresis due to the no desorption of adsorbates, which resulted in unique Type of charcoals overlapping Type I and Type IV. Such a low-pressure hysteresis is occurred from expansion of adsorbates, which were embedded in the micropore entrances and did not get out during the desorption run. The characteristics of charcoals such as specific surface area and pore size distribution did not show correct values depending on not only produced company but also sampling sites of one piece of charcoal. Therefore, it is not easy to suggest the quantitative characteristics of charcoals prepared from Korean traditional kiln. On the other hand, preparation the quality standard of charcoal is necessary for their special uses such as adsorbent.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.5
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• pp.112-118
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• 2022

In this study, the diffusion characteristics were evaluated using the concrete mix design of nuclear safety-related structures. Among the concrete structures related to nuclear power safety, we selected the composition of intake and drainage structures that are immersed in seawater or located on the tidal platform and evaluated the chloride ion permeation resistance by compressive strength and electrical conductivity and the diffusion characteristics by immersion in salt water. analyzed. Compressive strength was measured on the 1st, 7th, 14th, 28th, 56th, and 91st days until the 91st day, which is the design standard strength of the nuclear power plant concrete structure, and chloride ion permeation resistance was evaluated on the 28th and 91st. After immersing the 28-day concrete specimens in salt water for 28 days, the diffusion coefficient was derived by collecting samples at different depths and analyzing the amount of chloride. As a result, it was found that after 28 days, the long-term strength enhancement effect of the nuclear power plant concrete mix with 20% fly ash replacement was higher than that of concrete using 100% ordinary Portland cement. It was also found that the nuclear power plant concrete mix has higher chloride ion permeation resistance, lower diffusion coefficient, and higher resistance to salt damage than the concrete mix using 100% ordinary Portland cement.

• Journal of the Korean GEO-environmental Society
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• v.23 no.3
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• pp.15-22
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• 2022

This study aims to observe the swelling representative rocks in Korea and to suggest improvements in the use of test methods and prior analysis in relation to the weathering of rocks. The swelling test and analysis were performed on the drilling cores obtained for the ground investigation at the domestic highway construction site. For the method of determining the absorption expansion index of rocks, the method proposed in "Standard Methods for Sample Collection and Specimen Preparation" of ISRM and Korean Rock Engineers Standard Rock Test Method was used. The specimen for the measurement of the expansion displacement was cylindrical with a height of 10 cm and a diameter of 5 cm. The existing swelling analysis method evaluates the sensitivity to weathering by using the maximum expansion displacement, but since the classification by bedrock grade is unclear, it is reasonable to use the rate of change of the expansion displacement according to the immersion time. It is necessary to conduct an experiment to distinguish between weathering and fault deterioration. In addition, long-term weathering prediction technology for each cancer type is needed through the expansion displacement analysis of the chemical weathering stage.

• Journal of the Korean Institute of Gas
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• v.27 no.4
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• pp.62-69
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• 2023

The use of low-grade coal is continuously increasing with the development of combustion technology and cost reduction for coal used in thermal power plants . During combustion, the latent heat of evaporation due to moisture is large, and there is a risk of spontaneous combustion and dust explosion during the process of storing and pulverizing coal. This study compared and evaluated the minimum explosive concentration and explosive strength of four types of coal dust-fine, coal dust-coarse, wood pallet+organic dust, and wood chip with coal powder collected from domestic power plant D. The minimum explosive concentration of coal dust was measured according to JIS Z 8818:2002, and the explosion strength was tested according to ASTM E1226 using a Siwek 20 L Chamber Apparatus. As a result of the minimum explosive concentration test, it was found that coal dust-fine has a risk of dust explosion, and since an explosion occurs at a dust concentration of 130 g/m³ of wood chips, it was found that there is a risk of explosion at the lowest dust concentration. According to the dust explosion class standard, Kst is less than 200 bar m/s, and all samples fall under the explosion class St 1, and the dust has a low risk of explosion.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.5
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• pp.616-623
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• 2010

Plant samples from 49 sites for Chinese cabbage, 28 sites for radish, 16 sites for cabbage, 8 sites for head lettuce, 20 sites for onion from farmers' and experimental fields in highland of Korea were collected and analyzed to find out the uptake patterns of nitrogen (N), phosphorus (P) and potassium (K) by altitude. Dry weight and uptake of N, P and K were increased at higher altitude in most vegetable crops. Nutrition uptake by Chinese cabbage was 163 ~ 283 kg $ha^{-1}$ for N, 42 ~ 69 kg $ha^{-1}$ for $P_2O_5$ and 146 ~ 270 kg $ha^{-1}$ for $K_2O$ according to altitude. Nutrient uptake by radish according to altitude was 153~159 kg $ha^{-1}$ for N, 38 ~ 46 kg $ha^{-1}$ for $P_2O_5$, and 151 ~ 185 kg $ha^{-1}$ for $K_2O$. In case of cabbage, the plant uptakes of N, P, and K were increased at altitudes of 600 ~ 1,000 m. Nutrient uptake of cabbage was 280 ~ 348 kg $ha^{-1}$ for N, 34 ~ 87 kg $ha^{-1}$ for $P_2O_5$, and 209 ~ 290 kg $ha^{-1}$ for $K_2O$ according to altitude. Uptakes of N-$P_2O_5-K_2O$ by head lettuce at an altitude of 800 ~ 850 m were 93-26-126 kg $ha^{-1}$, respectively. Uptakes of N-$P_2O_5-K_2O$ by onions at an altitude of 600 ~ 800 m were 313-140-234 kg $ha^{-1}$, respectively, but there was no tendency in nutrition uptake patterns by altitude. Small cultivation areas used for leaf vegetable crops do not have fertilizer recommendation standards in alpine regions. It might be preferable to use a correction factor equivalent to the index of available nutrient uptake for the determination of N, P and K fertilizer application rates.