• Journal of the Korean Applied Science and Technology
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• v.31 no.3
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• pp.500-508
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• 2014

For this research, synthesis acrylic resin by ethyl acrylate monomer(EAM) and prepared samples which set by difference amount of monoammonium phosphate solution in waterborne acrylic resin. Use these resins, analyzed mechanical properties and thermal stability by films and leather surface coated. The test of DSC experiment sample WAC-APS3 was $410^{\circ}C$ Tm values which means the highest content of monoammonium phosphate had highest thermal stability in acrylic resin. According to measure data for solvent resistance, all samples showed good property. As known in the results, increase of ammonium phosphate constant did not influence to big change of resin properties. In abrasion test WAC-APS3 was good abrasion properties(68.729 mg.loss). Test of tensile strength, as increase as monoammonium phosphate resin analyzed low properties $1.505kgf/mm^2$ to $1.275kgf/mm^2$. In elongation case, same as strength test result 425 % to 384 % by increase to monoammonium phosphate amount in acrylic resin.

• Analytical Science and Technology
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• v.33 no.6
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• pp.274-284
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• 2020

This study described the analytical method for simultaneous determination of 89Sr and 90Sr in liquid sample using automated separation system. Radiostrontium in 0.5 kg of liquid sample was concentrated as SrCO3 to reduce the volume of sample, and purified from the sample using Sr-resin 2 mL (BV, Bed volume). The behavior of Sr and interferences such as Ba, Ca and Y were estimated with various flow rate ranging from 1 to 4 mL min-1. The detailed procedure for the purification of Sr on Sr-resin was presented. The purified radiostronitum was measured in Cerenkov mode and then measured in Scintillation mode by mixing scintillation cocktail. The measured value in both modes were used to calculate the activity of 89Sr and 90Sr. The performance tests were carried out the lab-control-sample having various activity ratio of between 89Sr and 90Sr. The recovery of Sr was ranged from 68 to 94 %. The relative bias of 89Sr activity was ranged from -5 to 20 %, and it was ranged from -10 to 10 % for 90Sr.

• Analytical Science and Technology
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• v.33 no.6
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• pp.262-273
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• 2020

A fluorine content analysis method for krill oils, which is a representative oil formulation in foods, was developed in compliance with the Korea Food and Drug Ministry's "Guidelines for Validation of Testing Methods Related to Food". Using this method for krill oils, the presence of impurities was evaluated via combustion-ion chromatography (C-IC). A review of published technical data on fluorine in krill oils showed that while the traditional wet potentiometric method was typically used, it was not reliable. Moreover, there was no food testing/analysis laboratory in Korea to perform a fluorine test analysis on such an oil matrix. Therefore, we identified halogen (fluorine) tests, developed to national and international standards, and developed a test method suitable for krill oils by selecting a C-IC method that is sufficiently applicable to the oil matrix. Based on the characteristics of the oil matrix, the optimal test method was established through various experiments by reviewing the concerns related to loss and interference in the preparation and introduction of samples. The fluorine content test was carried out on 11 krill oil products that were purchased online. Most products (with the exception of only one) were found to contain less than the reporting limit obtained by the test method. Furthermore, after additional testing, a high fluorine content of approximately 2,000 ~ 3,000 mg/kg was detected on the krill surface, although the concentration varied depending on the area of the krill. A comparison with samples from two ISO/IEC 17025 testing laboratories confirmed that there was no significant difference in the statistical analysis results obtained by ANOVA among the three laboratories. A testing guide for fluorine content analysis was completed.

• Analytical Science and Technology
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• v.22 no.5
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• pp.395-406
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• 2009

The determination of iodine in the spent nuclear fuel and the volatile behavior during its acid dissolution have been studied by NAA(neutron activation analysis) and electron probe microanalysis (EPMA). Simulated spent fuels (SIMFUELs) were dissolved in $HNO_3$(1+1) at $90^{\circ}C$ for 8 hours. The iodine remained in a dissolver solution after dissolution, and that condensed in dissolution apparatus and trapped in the adsorbent by volatilization during the dissolution were determined, respectively. The condensed iodine was recovered by the redistillation with $HNO_3$(1+1) after transfer of the dissolver solution. The iodines in the dissolver and redistilled solution were separated by solvent extraction followed by ion exchange or precipitation method and determined by RNAA (radiochemical neutron activation analysis). The ion exchange column and filtration kit used for the isolation of iodine, which were prepared with a polyethylene tube, were used as an insert in the pneumatic tube for neutron irradiation. The iodine volatilized during the dissolution of SIMFUELs was collected in a trapping tube containing Ag-silica gel (Ag-impregnated silica gel) adsorbent, and the distribution of iodine trapped in the adsorbents were determined by EPMA. The adsorbing characteristics shown with the SIMFUELs were compared with those shown with a real spent fuel from the nuclear power plant.

• Transactions of the Korean hydrogen and new energy society
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• v.16 no.1
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• pp.25-30
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• 2005

수소 분위기에서 10wt.%MnO와 기계적인 분쇄(반응성 기계적 분쇄)에 의해 Mg의 수소 저장 성질을 향상시켰다. 회전 속도는 250 rpm, 밀링시간은 2 h, 그리고 시료 대 볼 중량비는 1/45이었다. 준비한 Mg-10wt.%MnO 시료는 활성화를 위한 수소화물 형성 분해 싸이클링이 필요없었으며, 첫 번째 싸이클 593k 12 bar $H_2$에서, 10분 동안에 3.12wt.%, 60분 동안에 3.95wt.%의 수소를 흡수하였다. 또한 Mg-10wt.%MnO는 593k 0.8 bar $H_2$에서 60분 동안에 2.12wt.%의 수소를 방출하였다. MnO와 Mg의 방응성 분쇄는, 핵생성을 용이케하고 (Mg 입자의 표면에 결함 형성과 첨가물에 의해), Mg 입자의 표면에 crack을 만들어 Mg의 입자 크기를 줄여 그 결과 수소 원자의 확산 거리를 작게 함으로써 수소 흡수 방출 속도를 증가시킨다. 수소화물 형성 분해 싸이클링은 Mg 입자의 표면에 crack을 만들고 Mg의 입자 크기를 줄여 수소 흡수 방출 속도를 증가시킨다.

• Membrane Journal
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• v.28 no.1
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• pp.37-44
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• 2018

Polysulfone composites including graphene were prepared, and their thermal characteristics in membrane states were analyzed by using a custome-made residual stress analyzer and a thermal diffusivity analyzer based on laser flash method. The residual stress analysis was carried out on the polysulfone composite films deposited on Si (100) substrates for 1 cycle of heating and cooling runs. The flat membrane of graphene-embedded polysulfone composites were prepared by the phase transfer method in distilled water and the thermal conductivity was separately measured in the out-of-plane and the in-plane directions. The residual stress of the graphene-embedded polysulfone film was gradually decreased with increasing graphene loading and the out-of-plane thermal conductivity was distinguished from the in-plane thermal conductivity in the flat membranes. These thermal characteristics are caused by the structural uniqueness of graphene and the micro-void structures formed during membrane fabrication.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2007.04a
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• pp.257-263
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• 2007

본 논문은 내구성(durability) 및 내오염성(soiling resistance)이 매우 중요한 성질로 인식되는 유통지의 평가방법을 제안하는데 목적이 있다. 즉, 종이의 내구성 및 내오염성의 측정 및 평가에 있어서, 재현성 및 반복성이 우수하고 합리적인 측정방법 및 평가방법을 구축하는데 목적이 있다. 연구목적에 적합한 시료의 준비, 오염물의 조성, 실험장치 및 실험후의 타당한 평가방법 등에 대하여 선행 연구결과를 고찰하였다. 기존 방법의 수정과 새로운 장치의 제작 및 평가방법의 설정을 통해 재현성이 높은 평가방법을 정립하고자 하였다. 유통지의 내구성을 평가하는 방법으로는 습식, 내오염성, 건식 내오염성, 구김기공도, 내세탁성, 잉크 내마모도 등의 항목을 측정하여 개별항목으로 내구성을 가늠하거나, 몇가지항목에 각기 다른 가중치를 부여하여 구한 내구성 지수(durability index)의 개념으로 내구성을 평가하기도 한다. 본 논문에서는 내구성에 영향하는 요소로 강도적 성질요소(strength property value)와 내오염성 요소(artificial soiling value)로 구분하였다. 강도적 성질요소에서는 전통적으로 내구성과 관련이 깊은 것으로 인식되어 온 내절도(folding endurance), 인열강도(tearing resistance) 및 구김기공도(crumpled porosity)를 인쇄하기 전 용지상태에서 측정하여 4:4:2의 가중치를 주어 구하였다. 내오염성 요소는 국가별 기후특성에 따라 연평균 상대습도가 60% 이상인 경우 인쇄 시료를 대상으로하여 습식 내오염성, 건식 내오염성 및 내석검성을 평가한 후 6:3:1의 가중치를 주어 구하였다. 또한 연평균 60% 미만인 국가의 경우 3:6:1의 가중치를 부여하였다. 이렇게 구해진 강도적 성질요소와 내오염성 요소에 있어 강도적 성질요소는 궁극적으로 내오염성 요소에 영향하기 때문에 3:7의 비율로 가중치를 부여하여 최종적으로 내구성 지수를 구하였다. 이때의 점수가 60점 이상이면 내구성 용지로 정의하였다. 본 논문에서는 현장실험을 통하여 시제품을 제조하였다. 상기 설명된 방법으로 내구성 지수를 구한 결과, 일반 유통지 제조방법으로 제조한 경우 내구성 지수가 약 45점이었다. 반면, 새로 개발된 방법에 의한 고내구성용지(durability paper)의 경우 70점 이상을 나타내어 내구성이 향상되었음을 확인할 수 있었다.

• Science of Emotion and Sensibility
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• v.10 no.2
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• pp.169-175
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• 2007

This study surveys the variation of the physical properties such as denier, tensile property and thermal shrinkage between seven domestic and foreign PET filaments manufactured by China and Taiwan. For this purpose, the specimens prepared were PET POY 239d/96f made in china, and PET POY 255d/48f made in Korea as a coarse filament. As a fine filament, 120d PET POY made by Taiwan, China and 6 domestic companies were prepared. The various physical properties such as yarn denier, yarn mechanical property and wet and dry thermal shrinkages were measured according to the each layer divided by 50,000m of the cake, and between and within yarn physical properties were analysed and discussed with the domestic and foreign yarns. These results provide fundamental data to the SME related to the yarn finishing and weaving for developing high added-value and high sensitive fabrics.

• Journal of Environmental Impact Assessment
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• v.25 no.5
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• pp.357-368
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• 2016

Cambodia is the representative of developing country in Southeast Asia region. As a view point of water resource, Cambodia has in abundance but public sanitation problems persist in rural areas due to unsafe drinking water and untreated human waste. The purpose of this research is to prepare and develop new strategies for the water aid program in Cambodia by assessing, reviewing, and analyzing the present situation of water pollution for rural areas and the existing water use cycle in these regions. Pproyap and Langthle regions in Pursat province are selected as research areas. Cambodian's rural population in research areas relies on surface water stored in drinking-detention swamps, rain-water jars, and unprotected wells. The two types of main measures, thermotolerant coliform(TTC) bacteria and general pollutants, were conducted to assess the quality of selected water samples for research areas. TTC is a bacterial indicator of waterborne fecal contamination. For the 26 water samples, only one of the samples met the WHO standard for safe drinking water of 0 TTC colony forming units/100 mL.

• The Korean Journal of Pesticide Science
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• v.8 no.2
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• pp.88-94
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• 2004

In order to evaluate NMR spectrometer as the analytical tool for identification of individual adjuvant in crop protection products, the standard sample of individual adjuvant was analyzed by NMR spectrometer and then the formulation of crop protection products was also analyzed. Almost polymer system of surfactant was a co-polymer and there was an excess of ethylene. The most intense signal comes from long polyethylene blocks, 70.5 ppm. The carbonyl groups of ester group resonate at 173.5 ppm. Analytical sample was prepared in NMR tube without extraction, cleanup, concentration, or chromatographic separation. Identification of individual adjuvant in crop protection products was conducted by comparison of sample and reference spectra. NMR spectrometer was useful to analyze adjuvant in crop protection products without preparation process.