• Title/Summary/Keyword: 시간분해법

Search Result 562, Processing Time 0.032 seconds

Rate Enhancement of Thermal Decomposition Reaction in the $Ca(OH)_2$ Packed Bed ($Ca(OH)_2$ 충전층의 열분해 반응 촉진)

  • Chung, Soo-Yull;Kim, Do-Wan;Kim, Jong-Shik
    • Solar Energy
    • /
    • v.15 no.1
    • /
    • pp.73-84
    • /
    • 1995
  • The present paper is on the utilization of a thermal decomposition reaction $Ca(OH)_2=CaO+H_2O$, for thermal energy storage. One of the important problems in this case is how to heat up and decompose the particle of $Ca(OH)_2$ effectively where the thermal conduction is poor. In this study, the effects of Cu-plates which are placed in the $Ca(OH)_2$ packed bed as heat transfer fins are investigated experimentally. The results show that the Cu-plates are very effective for heat transfer and the thermal decomposition in the $Ca(OH)_2$ packed bed. The amount of time to dehydrate took less than a half than that without fins under the conditions of this study.

  • PDF

Optimization of Peptide Production from Leg Meat of Yeonsan Ogae by High Hydrostatic Pressure and Protein Hydrolytic Enzyme and Its Characteristic Analysis (고압처리와 단백질 분해효소를 이용한 연산오계 다리육 펩타이드 생산 최적화 및 특성 분석)

  • Ha, Yoo-jin;Kim, A-Yeon;Yoo, Sun-Kyun
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.17 no.7
    • /
    • pp.182-191
    • /
    • 2016
  • The purpose of this research was the optimization of protein hydrolysate production using a commercial enzyme bromelain 1200 derived from the leg of Yeonsan Ogae by response surface methodology. Yeonsan Ogae has long been known as supporting health and high efficacy treatment. In recent days, as the efficacy of functional peptides becomes more known, optimization of oligopeptide production and its characteristics from Ogae leg meat has been performed. Response surface methodology was performed for optimization of enzyme hydrolysis. The process was varied in pressure (30 to 100 MPa), time (1 to 3 h), and substrate concentration (10 to 30%). The degree of hydrolysis, amino acids, and molecular weight of products were analyzed. The optimum conditions were determined to be a pressure of 100 Mpa, time of 3 h, and substrate concentration of 20%. Under optimized conditions, degree of hydrolysis was 34.10%. The average molecular weight of protein hydrolysates was less than 1,000 Da. Major amino acids were leucine, lysine, alanine, glutamic acid, and phenylalanine.

Simulation of Energy Resolution of Time of Flight System for Measuring Positron-annihilation induced Auger Electrons (양전자 소멸 Auger 전자 에너지 측정을 위한 Time of Flight의 분해도 향상에 관한 이론적 연구)

  • Kim, J.H.;Yang, T.K.;Lee, C.Y.;Lee, B.C.
    • Journal of the Korean Vacuum Society
    • /
    • v.17 no.4
    • /
    • pp.311-316
    • /
    • 2008
  • Since the presence of the chemical impurities and defect at surfaces and interfaces greatly influence the properties of various semiconductor devices, an unambiguous chemical characterization of the metal and semiconductor surfaces become more important in the view of the miniaturization of the devices toward nano scale. Among the various conventional surface characterization tools, Electron-induced Auger Electron Spectroscopy (EAES), X-ray Photoelectron Spectroscopy (XPS) and Secondary Electron Ion Mass Spectroscopy (SIMS) are being used for the identification of the surface chemical impurities. Recently, a novel surface characterizaion technique, Positron-annihilation induced Auger Electron Spectroscopy (PAES) is introduced to provide a unique method for the analysis of the elemental composition of the top-most atomic layer. In PAES, monoenergetic positron of a few eV are implanted to the surface under study and these positrons become thermalized near the surface. A fraction of the thermalized positron trapped at the surface state annihilate with the neighboring core-level electrons, creating core-hole excitations, which initiate the Auger process with the emission of Auger electrons almost simultaneously with the emission of annihilating gamma-rays. The energy of electrons is generally determined by employing ExB energy selector, which shows a poor resolution of $6{\sim}10eV$. In this paper, time-of-flight system is employed to measure the electrons energy with an enhanced energy resolution. The experimental result is compared with simulation results in the case of both linear (with retarding tube) and reflected TOF systems.

Production of Chiral Styrene Oxide by Microbial Enantioselective Hydrolysis Reaction (미생물 입체선택성 가수분해 반응을 이용한 광학활성 Styrene Oxide 생산)

  • 윤성준;이은열
    • KSBB Journal
    • /
    • v.15 no.6
    • /
    • pp.630-634
    • /
    • 2000
  • Chiral epoxides are useful chiral synthons in organic synthesis, and various biological methods have been investigated for their production. In this work, the enantioselective resolution of racemic styrene oxide was investigated using Aspergillus niger sp. for the production of optically pure (S)-styrene oxide. The enantioselectivity and initial hydrolysis rates of the racemic substrate were highly dependent of the pH, temperature, and the volume ratio of cosolvent. Experimental sets of pH, temperature, and the volume ratio of cosolvent were investigated using a central composite experimental design, and reaction conditions were optimized by response surface analysis. The optimal conditions of pH, temperature, and the volume ratio of cosolvent were determined to be 7.78, $28.32^{\circ}C$, and 2.4%(v/v), respectively, and optically pure (S)-styrene oxide (>99% ee) was obtained at 35% yield using this microbial enantioselective hydrolysis reaction.

  • PDF

Theory of Acoustic Quanta and its Application on Sound Design (음향 양자 이론의 사운드 디자인적 응용)

  • Koo, Jahwan
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.19 no.9
    • /
    • pp.420-426
    • /
    • 2018
  • Acoustic Quanta, which British Physicist Dennis Gabor created, is the theoretical background for granular synthesis and has influenced many computer music artists and sound designers. Acoustic Quanta is a very short sound burst, lasting only 1 to 100 ms. Granular synthesis is a sound synthesis technique which slices original sound into sound grains and re-combines them into a new acoustic event. Concept of sound grain is borrowed from the acoustic quanta. Granular Synthesis can make very unique sound, so that it can be useful in many ways, especially in sound design. This paper presents concept of acoustic quanta and granular synthesis. It then discusses making a synthesizer as an implementation of synchronous granular synthesis and its applications on sound design. As a result, the duration of acoustic quanta should range between 0.239 and 33.367 ms, in consideration of audible frequencies, which is different from the original concept of the acoustic quanta.

Time-lapse Inversion of 3D Resistivity Monitoring Data (3차원 전기비저항 모니터링 자료의 시간경과 역산)

  • Kim, Yeon-Jung;Cho, In-Ky;Yong, Hwan-Ho;Song, Sung-Ho
    • Geophysics and Geophysical Exploration
    • /
    • v.16 no.4
    • /
    • pp.217-224
    • /
    • 2013
  • We developed a time-lapse inversion using new cross-model constraints based on change ratio and resolution of model parameters. The cross-model constraint based on change ratio imposes the same penalty on the model parameters with equal change ratio. This constraint can emphasize the model parameters with significant change regardless of their increase or decrease. The resolution cross-model constraint imposes a small penalty on the model parameters with poor resolution, but a large penalty on the model parameters with good resolution. Thus, the model parameter with poor resolution can be effectively identified in the inversion result if they are significantly changed with time. Through the numerical tests for 3D resistivity monitoring data sets, the performance of these two cross-model constraints was confirmed. Finally, for the safety estimation of a sea dyke, we applied the developed time-lapse inversion to the 3D resistivity monitoring data that were acquired at a sea dike located in western coastal area of Korea. The result of time-lapse inversion suggested that there were no significant changes at the sea dike during the monitoring period.

Development of Temporary Preservation Method for Small Scale Dairy Farm Milk by $H_2O$$_2$ Catalase Treatment (Part 1) Bactericidal Effect of Hydrogen Peroxide and Its Stability in Milk ($H_2O$$_2$-Catalase처리에 의한 소규모 목장우유의 일시적 보존법의 개발 (제1보) 우유에 있어서 과산화수소의 살균효과 및 안정성)

  • Park, I.S.;Pack, M.Y.
    • Microbiology and Biotechnology Letters
    • /
    • v.5 no.3
    • /
    • pp.113-118
    • /
    • 1977
  • Into the precontaminated farm milk hydrogen peroxide ($H_2O$$_2$) was added at the concentrations ranging from 0.01% to 0.05% and kept at 3$0^{\circ}C$ for 16 hours with periodical determinations for viable counts, residual $H_2O$$_2$, and lactic acid. Under the tested conditions the initial level of contaminated bacteria could be arrested from growing at least for 8, 12, and 16 hours by treating the milk with 0.01, 0.02. and 0.03 per cent of $H_2O$$_2$, respectively. Furthermore, when the $H_2O$$_2$concentrations ware limited within the level of 0.03 Per cent the added $H_2O$$_2$was completely decomposed within 12 hours without the aid of external catalase and the decomposition time decreased in parallel with the $H_2O$$_2$ concentrations. A safer use of $H_2O$$_2$for preserving farm milk temporarily by limiting its concentration has been discussed.

  • PDF

Optimization of Microwave-Assisted Pretreatment Conditions for Enzyme-free Hydrolysis of Lipid Extracted Microalgae (탈지미세조류의 무효소 당화를 위한 마이크로파 전처리 조건 최적화)

  • Jung, Hyun jin;Min, Bora;Kim, Seung Ki;Jo, Jae min;Kim, Jin Woo
    • Korean Chemical Engineering Research
    • /
    • v.56 no.2
    • /
    • pp.229-239
    • /
    • 2018
  • The purpose of this study was to effectively produce the biosugar from cell wall of lipid extracted microalgae (LEA) by using microwave-assisted pretreatment without enzymatic hydrolysis process. Response surface methodology (RSM) was applied to optimization of microwave-assisted pretreatment conditions for the production of biosugar based on enzyme-free process from LEA. Microwave power (198~702 W), extraction time (39~241 sec), and sulfuric acid (0~1.0 mol) were used as independent variables for central composite design (CCD) in order to predict optimum pretreatment conditions. It was noted that the pretreatment variables that affect the production of glucose (C6) and xylose (C5) significantly have been identified as the microwave power and extraction time. Additionally, the increase in microwave power and time had led to an increase in biosugar production. The superimposed contour plot for maximizing dependent variables showed the maximum C6 (hexose) and C5 (pentose) yields of 92.7 and 74.5% were estimated by the predicted model under pretreatment condition of 700 w, 185.7 sec, and 0.48 mol, and the yields of C6 and C5 were confirmed as 94.2 and 71.8% by experimental validation, respectively. This study showed that microwave-assisted pretreatment under low temperature below $100^{\circ}C$ with short pretreatment time was verified to be an effective enzyme free pretreatment process for the production of biosugar from LEA compared to conventional pretreatment methods.

Improvement of Analytical Method for Determination of Germanium in Plant by Atomic Absorption Spectrometry (원자흡광분광법에 의한 식물체 중의 게르마늄 분석법 개선)

  • Han, Seong-Soo;Rim, Yo-Sup;Kim, Il-Kwang
    • Analytical Science and Technology
    • /
    • v.10 no.3
    • /
    • pp.179-186
    • /
    • 1997
  • This study was carried out to improve the analytical method for determination of germanium in plants by atomic absorption spectrometry with graphite furnace. For the decomposition of plant samples, the mixed acid of $HNO_3+HClO_4+H_2SO_4$(10 : 4 : 1, v/v) was used. Under this condition, time requirement for the decomposition was 4~5 days and recovery rate was more than 98%. Solution for filling up to constant volume after decomposition was 0.1M acetic acid-sodium acetate. Detection limit for determination of germanium was 0.02 ppm by atomic absorption spectrometry with graphite furnace and argon gas. These results were corresponded with the above-mentioned research projects for improving the determination method of germanium in plants.

  • PDF

An Alternative Method for a Rapid Urease Test Using Back-table Gastric Mucosal Biopsies from Gastrectomy Specimen for Making the Diagnosis of Helicobacter pylori Infection in Patients with Gastric Cancer (위암 환자의 헬리코박터 파이로리 감염 진단에 있어서 위절제술 직후 생검된 위점막 조직을 이용한 신속 요소 분해 효소 검사법 도입의 의의)

  • Kim, Sin-Ill;Jin, Sung-Ho;Lee, Jae-Hwan;Min, Jae-Seok;Bang, Ho-Yoon;Lee, Jong-Inn
    • Journal of Gastric Cancer
    • /
    • v.9 no.4
    • /
    • pp.172-176
    • /
    • 2009
  • Purpose: The rapid urease test is a rapid and reliable method for diagnosing Helicobacter pylori infection. However it requires gastric mucosal biopsies during endoscopy, and the test is not covered by national health insurance for patients with gastric cancer. So, we introduced an alternative method for a rapid urease test using back-table gastric mucosal biopsies from gastrectomy specimen. Materials and Methods: Ninety gastric cancer patients underwent an anti H. pylori IgG ELISA test and gastrectomy. Just after gastrectomy, two gastric mucosal biopsies from the prepyloric antrum and lower body of the gastrectomy specimen were taken from the back table in the operative room, and these were fixed immediately with the rapid urease test kit, and the color change was monitored for up to 24 hours. In this study, H. pylori infection was defined as positive when the serology or rapid urease test showed positive results. Results: The positive rate of the rapid urease test and serology was 91.1% and 77.8%, respectively. The sensitivity, specificity, positive predictive value and negative predictive value of the rapid urease test and serology were 94.3 and 80.5%, 100 and 100%, 100 and 100%, and 37.5 and 15%, respectively. The accuracy of the rapid urease test was higher than that of serology (94.4 vs. 81.1%, respectively). The rapid urease test showed a higher rate of detecting H. pylori infection than that of serology (McNemar's test, P=0.019). Conclusion: The result of the rapid urease test using back-table gastric mucosal biopsies from a gastrectomy specimen is comparable to the reference data of the conventional rapid urease test using gastric mucosal endoscopic biopsies. Therefore, it can be an alternative diagnostic method for H. pylori infection.

  • PDF