• Economic and Environmental Geology
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• v.52 no.6
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• pp.627-635
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• 2019

Cement-asbestos slate is the main asbestos containing material. It is a product made by combining 10~20% of asbestos and cement components. Man- and weathering-induced degradation of the cement-asbestos slates makes them a source of dispersion of asbestos fibres and represents a priority cause of concern. When the asbestos enters the human body, it causes cellular damage or deformation, and is not discharged well in vitro, and has been proven to cause diseases such as lung cancer, asbestos, malignant mesothelioma and pleural thickening. The International Agency for Research on Cancer (IARC) has designated asbestos as a group 1 carcinogen. Currently, most of these slats are disposed in a designated landfill, but the landfill capacity is approaching its limit, and there is a potential risk of exposure to the external environment even if it is land-filled. Therefore, this study aimed to exam the possibility of detoxification of asbestos-containing slate by using exothermic reaction and heat treatment. Cement-asbestos slate from the asbestos removal site was used for this experiment. Exothermic catalysts such as calcium chloride(CaCl₂), magnesium chloride(MgCl₂), sodium hydroxide(NaOH), sodium silicate(Na₂SiO₃), kaolin[Al₂Si₂O₅(OH)₄)], and talc[Mg₃Si₄O₁₀(OH)₂] were used. Six catalysts were applied to the cement-asbestos slate, respectively and then analyzed using TG-DTA. Based on the TG-DTA results, the heat treatment temperature for cement-asbestos slate transformation was determined at 750℃. XRD, SEM-EDS and TEM-EDS analyses were performed on the samples after the six catalysts applied to the slate and heat-treated at 750℃ for 2 hours. It was confirmed that chrysotile[Mg₃Si₂O₅(OH₅)] in the cement-asbestos slate was transformed into forsterite (Mg₂SiO₄) by catalysts and heat treatment. In addition, the change in the shape of minerals was observed by applying a physical force to the slate and the heat treated slate after coating catalysts. As a result, the chrysotile in the cement-asbestos slate maintained fibrous form, but the cement-asbestos slate after heat treatment of applying catalyst was broken into non-fibrous form. Therefore, this study shows the possibility to safely verify the complete transformation of asbestos minerals in this catalyst- and temperature-induced process.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.4
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• pp.407-417
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• 2020

The capacity of the designated landfill site for asbestos-containing waste is approaching its limit because the amount of asbestos-containing slate is increasing every year. There is a need for a method that can safely and inexpensively treat asbestos-containing slate in large capacity and at the same time recycle it. A cement kiln can be an alternative for heat treatment of asbestos-containing slate. We intend to develop a pilot scale device that can simulate the high temperature environment of a cement kiln using a high temperature plasma reactor in this study. In addition, this reactor can be used to inactivate asbestos in the slate and to synthesize one of the minerals of cement, to confirm the possibility of recycling as a cement raw material. The high-temperature plasma reactor as a pilot scale experimental apparatus was manufactured by downsizing to 1/50 the size of an actual cement kiln. The experimental conditions for the deactivation test of the asbestos-containing slate are the same as the firing time of the cement kiln, increasing the temperature to 200-2,000℃ at 100℃ intervals for 20 minutes. XRD, PLM, and TEM-EDS analyses were used to characterize mineralogical characteristics of the slate before and after treatment. It was confirmed that chrysotile [Mg3Si2O5(OH)4] and calcite (CaCO3) in the slate was transformed into forsterite (Mg2SiO4) and calcium silicate (Ca2SiO4), a cement constituent mineral, at 1,500℃ or higher. Therefore, this study may be suggested the economically and safely inactivating large capacity asbestos-containing slate using a cement kiln and the inactivated slate via heat treatment can be recycled as a cement raw material.

• Nuclear Engineering and Technology
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• v.7 no.1
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• pp.9-14
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• 1975

Slate-plastic composite was prepared by impregnating methyl methacrylate monomer into the slate and subsequent curing the monomer either by gamma radiation or by thermal-catalytic method. Experiments were carried out to determine the polymerization rate and to investigate the properties of the composite. Significant improvements in flexural strength, water absorbability and acid resistance were observed in the products. Differences in properties between the composites obtained via two different methods were discussed as well as the cause of such results.

• Environmental engineer
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• s.325
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• pp.14-14
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• 2013

• Journal of the Korean association of regional geographers
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• v.21 no.4
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• pp.660-672
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• 2015

The rural housing is a key element of the rural landscape. The studies on the rural housing have focused on folk housing, but this study focuses on the comtemporary rural housing. The research area is the eight rural settlements on the sea islands of Gyeongnam. This study may provide the base for an understanding Korean rural landscape through the analysis of the rural housing types with special reference to the roofing types and materials. Most roofing types but the flat roofing type belong to the traditional roofing types. Among the combined-style roofing(결합양식지붕) types, the pitched-and-flat roofing(경사-평지붕) type is about ten times more frequent than the pitched-and-pitched roofing(경사-경사지붕) type. The most frequent roofing materials are cement, precoated steel plate(컬러강판), and artificial slate(인조슬레이트). Five typical types of rural housing are derived from the remarkable combinations of roofing types and roofing materials in the research area.

• The Journal of Engineering Geology
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• v.24 no.1
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• pp.137-146
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• 2014

The geology of the study area which is located in Samkoe-dong, Dong-gu, Daejeon city comprises black slate, limestone, and pebble-bearing phyllitic rock as meta-sedimentary rocks; and biotite granite and quartz porphyry intrusions. Face mapping revealed sliding in three or four sites of contained coaly slate, where the dip of the foliation and other discontinuities is parallel to the surface slope. The cause of the slope sliding is this parallelism as well as the swelling of the coaly slate when wet. In contrast, the slop on the opposite side of the road is relatively stable because the dip of the foliation and other discontinuities are oblique or normal to the surface slope. To ensure slope stability, a cut-and-cover tunnel was designed and constructed for the new road.

• 월간산업보건
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• no.7 s.243
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• pp.83-84
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• 2008

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.159.2-159.2
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• 2010

Asbestos is the collective name for a group of naturally occurring minerals in their fibrous form and hydrous silicates of magnesium and a mineral fiber that has been used commonly in a variety of building construction materials for insulation and as a fire-retardant. Asbestos has been used for a wide range of manufactured goods, because of its fiber strength and heat resistant properties. Nevertheless harmful of asbestos is quite serious. Exposure to airborne friable asbestos may result in a potential health risk because persons breathing the air may breathe in asbestos fibers. Continued exposure can increase the amount of fibers that remain in the lung. Fibers embedded in lung tissue over time may cause serious lung diseases including asbestosis, lung cancer. In this paper, we carried out as fundamental study for dispose of asbestos cement slate safely and perfectly. Melting Temperature of asbestos need to more than $1,520^{\circ}C$ and specially asbestos cement slate need more energy than that of pure asbestos. We need to decrease melting temperature of asbestos cement slate for economical efficiency. To the purpose, glass and bottom ash were chosen as additives for basicity control. we analyzed about properties of asbestos cements slate, melting characteristics on the additives ratio and temperature. We confirmed about harmlessness of melting slag through analysis of scanning electron microscope(SEM) and x-ray diffractometer(XRD).

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.3
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• pp.2308-2313
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• 2015

In order to produce an optimal performance solid lubricant used in the refractory slates, various compositions of starch, graphite and water were evaluated by testing their viscosity, coefficient of friction and wear performance. At 15% starch content, the degree of viscosity increment rose in proportional to graphite content and the lowest coefficient of friction was observed when the graphite content was at 30 wt%. Our results demonstrate that, as the water content decrease, the ratio of solid content increases, which compromises the surface coating resulting in increase of coefficient of friction. The best wear test result was obtained when the starch content was at 15 wt% with graphite content at either 25 wt% or 30 wt%.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.9
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• pp.623-629
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• 2012

The objective was to evaluate the quality of harvested rainwater of the roofing materials used and the presence of lichens/mosses on the roofing surface. This experiment was studied in the field where five pilot structures with different roofing materials (i.e., wooden shingle tiles, wooden shingle tiles (including mosses), concrete tiles, clay tiles [Gi-Wa] and slate tiles) were installed. As a result, the clay tiles [Gi-Wa] was found to be the most suitable for rainwater harvesting applications. It was due to the disinfection from ultraviolet light and high temperature according to characteristic of roofing materials. Comparison with quality of rainwater on that wooden shingle tiles with and without including mosses, which may affect the concentration of and wooden shingle tiles including mosses, mosses may affect concentration of TOC, nitrate, and sulfate. Additionally, the average concentration of asbestos was determined to be measured at $0.002/cm^3$ for the slate tiles. The value satisfied with it met the Ministry of Environment's Multi-use facility standard and Ministry of Labor's Office standard ($0.01/cm^3$).