• The Korean Journal of Pesticide Science
• /
• v.17 no.2
• /
• pp.94-106
• /
• 2013

The proficiency testing for the residue laboratories of pesticide registration was conducted in order to improve the reliability and the ability for pesticide residue analysis. On October 2011 the testing was carried out using the soil collected and kept as the moistened state for five years, which is expected to very low residue levels of pesticides. The soil was fortified with chlorpyrifos, metolachlor and procymidone in a manner similar to prepare soil sample for indoor soil degradation test, and then sub-samples were prepared for the distribution to participants. Some of them were randomly selected for confirm of homogeneity and to ensure the stability of samples at room temperature. Samples were consisted of two soil treated as different levels, one of which was used to the assesment and another used to confirm. In addition, provide three standard solutions, respectively concentration of 10 mg/L, and untreated soil. Forty seven institutions submitted results. The medians of results were used as the assigned values for pesticide residues. Fitness for purpose standard deviation of proficiency test was calculated by applying 20% RSD as the coefficient of variation allowed in the soil residue test. Z-score was applied for evaluation of individual pesticides, and the average of the absolute value of the Z-score for the overall assessment of pesticides. Laboratories evaluated the absolute value of the Z-score less than 2 to fit the case of chlorpyrifos and procymidone were 44, metolachlor 40.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2015.08a
• /
• pp.98.2-98.2
• /
• 2015

한국항공우주연구원에서는 Military Standard 801G:2014 문서의 500.6 방법에 따른 고도시험 서비스를 제공하고 있으며, 이를 위해 직경 1.6 미터, 길이 1.8 미터의 진공챔버를 활용하고 있다. 규격에서 요구하는 고도변화율(10 m/s 이하)를 만족시키기 위해서, 건식펌프를 이용하여 챔버 내부 진공도를 낮추고, 동시에 매뉴얼밸브의 개도를 적절히 조절하여 왔다. 따라서, 작업자의 능력과 숙련도에 따라 실제 고도변화율이 달라지게 되고, 이는 곧 시험의 재현성을 방해하는 요소로 작용하였다. 이러한 단점을 보완 하고자 기존의 데이터를 바탕으로 하여 원격 유량조절밸브 적용 후 질소의 챔버내부 유입을 통한 고도시험의 자동화를 구현하였다. 고도시험의 자동화를 통해, 일정한 고도변화율을 유지할 수 있으며, 정확한 시험결과를 도출 할 수 있었다. 본 논문에서는 고도시험 자동화 구현 방법과 일련의 진행 과정에 대해 기술하였다.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.29 no.2
• /
• pp.25-30
• /
• 2021

This study investigated how the indicators of quality control are improved by proficiency in the measurement of phosphate concentration. In addition, analysis equipments were to be compared to see if there were any differences in measurements depending on the type of analysis device. In order to find out the effect of the proficiency of the analyst on the analysis results, three analysts measured phosphate concentration seven times in accordance with the Korean water pollution test standards, and met the quality control indices if repeated more than five times. The limit of quantification for phosphate was calculated at 0.02 mg/L. If the analysis devices are different, the absorbance and concentration of the samples near the limit of quantification are statistically significant difference.

• Journal of Korean Society for Quality Management
• /
• v.45 no.3
• /
• pp.447-462
• /
• 2017

Purpose: This study aims to develop distributable samples that can be used for proficiency testing to verify the ability of the testing laboratory to perform high temperature and low temperature tests. Method: In this study, the temperature-resistance characteristics of the NTC thermistor were used to develop samples. The homogeneity and stability of samples were examined according to the proficiency testing requirements. Results: Thirty samples with homogeneity and stability were developed and used for the proficiency testing. Thus, it was possible to distinguish between the test laboratories that showed satisfactory results and those that did not. Conclusion: It was the first time to develop samples that can be used for proficiency testing in high temperature and low temperature tests. and it was proved that the proficiency test program can be operated using the characteristics of NTC thermistor.

• Analytical Science and Technology
• /
• v.14 no.3
• /
• pp.230-237
• /
• 2001

In general, the pH measurement follows calibration of glass electrode system using pH standard solution. When pH is measured at constant temperature, uncertainty factors are mainly related to the accuracy of pH standard solution and the accuracy and precision of glass electrode. Participants in this proficiency test were the volunteers trying to know the distribution of the measured pH values for the same sample and the sources of error through 1998 and 1999. The samples for proficiency test are phosphate salt standard solutions specially prepared in KRISS, of which pH values were 6.860, 7.415(at $25^{\circ}C$), and the stability test was performed for the same periods of proficiency test. The results of the proficiency test were plotted according to Youden plot, which shows whether the error is random or systematic. The results of Youden plot showed that the source of error was from the systematic effect of laboratories in each year. This shows that the source of error is the standard solutions used in laboratories.

• Analytical Science and Technology
• /
• v.23 no.3
• /
• pp.284-294
• /
• 2010

In this study, river water-based reference materials (RMs), NIER-I08RW and NIER-I09, for trace metal analysis were prepared and certified for Pb, Cd, Cr and Cu with evaluation of uncertainties. The RMs were confirmed to be homogeneous enough to be used as proficiency testing materials since within-bottle homogenieties of the RMs were lower than 0.3 times of targeted standard deviation of proficiency testing. The RMs were distributed to environmental testing laboratories for the proficiency testing and the variation of Z scores of the proficiency testing results were compared for different assigned values. The relative bias, $B_{relative}$, deviations between reference values and consensus values, were lower than ${\pm}$1 except for cadmium of NIERI08RW. The results showed both values were in a good agreement and only 2.9% of Z scores changed by using a different assigned values such as consensus and reference values.

• Journal of Korean Society on Water Environment
• /
• v.29 no.4
• /
• pp.568-573
• /
• 2013

In this study, we conducted whole effluent toxicity (WET) proficiency testing based on the results which $EC_{50}$ value of 3 types (A, B, C) unknown samples calculated from 32 water quality measurement agencies in Korea. WET proficiency testing was expected to their improve of analysis skill and ensure reliability of analysis results. Ultimately, it is intended to promote the reliable enforcement of WET. WET proficiency testing was evaluated using the z-score, robust z-score and the results showed that 30 participating agencies were "compliance". In addition, $EC_{50}$ values of "unknown sample A" were the normal distribution. Therefore, "unknown sample A" was considered as the most suitable standard toxicity substance.

• Analytical Science and Technology
• /
• v.15 no.5
• /
• pp.433-438
• /
• 2002

Trace elements in two air filters (V-50, P-50) artificially loaded with urban dust provided from IAEA were determined non-destructively using instrumental neutron activation analysis. Standard reference material (Urban Particulate Matter, SRM 1648) of National Institute of Standard and Technology was used for analytical quality control. About 20 elements in both of loaded filter samples were determined. To evaluate inter-laboratory comparison and proficiency test, analytical data were statistically treated with the results which collected from 49 laboratories, 40 countries participated in this study using neutron activation analysis, particle induced X-ray emission, inductively coupled plasma mass spectroscopy, etc,. From the results of statistical treatment, Z-scores are within ${\pm}2$. Furthermore, accuracy and precision of obtained analytical values are passed according to the criteria of the proficiency test. Consequently, it was proved that analytical quality for air dust samples being performed has been controlled properly.

• Journal of the Korean Geotechnical Society
• /
• v.33 no.3
• /
• pp.5-15
• /
• 2017

In this study, the liquid and plastic limit tests were conducted on Paju clay with Casagarande method (dynamic) and the fall cone test method (static) to find out the effects of test methods and testers on their values. Six testers, who already have the experience of test, participated. As a results of liquid limit tests, the fall cone test method showed 4% smaller liquid limit compared to the value determined by Casagrande method. As the number of tests increased, the fall cone test method showed less variation between testers and the variation range of level of proficiency was also more stable. In the case of one point method, the liquid limit determined by the fall cone test method varied with smaller range compared to the Casagrande. Consequently, the fall cone test provided more stable liquid limit value than that of Casagrande method. For the results of plastic limit tests, there were no difference between Casagrande method and the fall cone test unlike liquid limit test results. In other words, both methods showed that plastic limit reached the average value as the number of tests increased, and the tendency level of proficiency also showed to get better.

• Analytical Science and Technology
• /
• v.20 no.3
• /
• pp.183-192
• /
• 2007

The various environmental regulation directives such as RoHS (restriction of hazardous substances in electrical and electronic products) and WEEE (waste from electrical and electronic equipments) are practically used as the technical barrier in international trade (TBT) of vehicles and electrical and electronic products recently. Regarding such an environmental regulation, Korea Research Institute of Standards Science (KRISS) organized a proficiency testing scheme to establish the reliability of measurement results produced by the relevant research institutes and test laboratories in Korea. Participants were 31 laboratories related to production of the electrical and electronic equipments and mobile vehicles. Two polypropylene samples of pellet type were employed as the proficiency testing materials (PTMs). Cadmium and lead were the analytes chosen among six components regulated in European Union (EU) RoHS directive. The PTMs were sent to the participants by post on September $1^{st}$ 2006, and deadline for results submission were October $10^{th}$ 2006. The results of each laboratory were evaluated in comparison with KRISS reference values using Robustic Z-score and Youden plot methods. The results of the various sample digestion methods were also compared. Most of participants reported good agreement within 10 % range of reference values. However, results from several laboratories showed significant biases from reference values. These laboratories should establish the quality assurance system for improvement of the measurement reliability.