• Title/Summary/Keyword: 수착

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Evaluation of 1,1,2-trichloroethylene Removal Efficiency Using Composites of Nano-ZnO Photocatalyst and Various Organic Supports (다양한 유기계 지지체와 광촉매 Nano-ZnO 복합체를 활용한 1,1,2-trichloroethylene 제거 효율 평가)

  • Jang, Dae Gyu;Ahn, Hosang;Kim, Jeong Yeon;Ahn, Chang Hyuk;Lee, Saeromi;Kim, Jong Kyu;Joo, Jin Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.11
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    • pp.771-780
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    • 2014
  • In this study, the various organic supports (i.e., silicone, acrylonitrile-butadiene-styrene, epoxy, and, butadiene rubber) with great sorption capacity of organic contaminants were chosen to develop nano-ZnO/organic composites (NZOCs) and to prevent the detachment of nano-ZnO particles. The water resistance of the developed NZOCs were evaluated, and the feasibility of the developed NZOCs were investigated by evaluating the removal efficiency of 1,1,2-trichloroethylene (TCE) in the aqueous phase. Based on the results from water-resistance experiments, long-term water treatment usage of all NZOCs was found to be feasible. According to the FE-SEM, EDX, and imaging analysis, nano-ZnO/butadiene rubber composite (NZBC) with various sizes and types of porosity and crack was measured to be coated with relatively homogeneously-distributed nano-ZnO particles whereas nano-ZnO/silicone composite (NZSC), nano-ZnO/ABS composite (NZAC), and nano-ZnO/epoxy composite (NZEC) with poorly-developed porosity and crack were measured to be coated with relatively heterogeneously-distributed nano-ZnO particles. The sorption capacity of NZBC was close to 60% relative to the initial concentration, and this result was mainly attributed to the amorphous structure of NZBC, hence the hydrophobic partitioning of TCE to the amorphous structure of NZBC intensively occurred. The removal efficiency of TCE in aqueous phase using NZBC was close to 99% relative to the initial concentration, and the removal efficiency of TCE was improved as the amount of NZBC increased. These results stemmed from the synergistic mechanisms with great sorption capability of butadiene rubber and superior photocatalytic activities of nano-ZnO. Finally, the removal efficiency of TCE in aqueous phase using NZBC was well represented by linear model ($R^2{\geq}0.936$), and the $K_{app}$ values of NZBC were from 2.64 to 3.85 times greater than those of $K_{photolysis}$, indicating that butadiene rubber was found to be the suitable organic supporting materials with enhanced sorption capacity and without inhibition of photocatalytic activities of nano-ZnO.

음양오행론의 발생과 그 응용;음양오행론적발생화응용(陰陽五行論的發生和應用)

  • Yun, Chang-Yeol
    • Journal of Korean Medical classics
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    • v.19 no.4
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    • pp.212-218
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    • 2006
  • 당금시대(當今時代), 정진입도동서방문명형성상호간적융합공제(正進入到東西方文明形成相互間的融合共濟), 병탐색착이상생적관계진행발전적전절기(幷探索着以相生的關係進行發展的轉折期). 동양사상통과관찰정체적직관여통합적사유방법(東洋思想通過觀擦整體的直觀與統合的思維方法), 설명료우주변화규율화인간적각종난해지미(設明了宇宙變化規律和人間的各種難解之謎), 종이창조출료위대적음양오행론사상(從而創造出了偉大的陰陽五行論思想). 단시수착 '서세동점' 적조류(但是隨着 '西勢東漸' 的潮流), 신위동양인이교육화사유방법이축보서양화(身爲東洋人而敎育和思維方法已逐步西洋化), 미능계승아문적위대전통(未能繼承我們的偉大傳統), 반피서양적과학문명화물질문명소흡수(反被西洋的科學文明和物質文明所吸收). 연이(然而), 서양적임하일종철학급과학(西洋的任何一種哲學及科學), 몰유일개능구이일종원리래설명우주화인간급만물적변화(沒有一個能구以一種原理來說明宇宙和人間及萬物的變化), 즉몰유일개능여동양적음양오행론상필적적철학화이론(卽沒有一個能與東洋的陰陽五行論相匹敵的哲學和理論). 포괄음양오행론재내(包括陰陽五行論在內), 동양사상이기흔강적설복력, 수착과학진보(隨着科學進步), 기가치개시중신피인식(其價値開始重新被認識). 이전뇌화수자혁명위대표적현대문명(以電腦和數子革命爲代表的現代文明), 역시근거음양론적이진법위기초이창조출래적(亦是根據陰陽論的二進法爲基礎而創造出來的). 애인사탄(愛因사坦), 탕천수수(湯川秀樹), 니극발이(尼克勃이), 가포라등(기布羅等), 균대동양사상적위대성가이인가(均對東洋思想的偉大性加以認可), 병종차득도영감(幷從此得到靈感), 취득위대적과학성과(取得偉大的科學成果). 음양오행론시불가마살적절대진리(陰陽五行論是不可磨殺的絶對眞理). 불관대기이론가치급본질무지적인(不管對其理論價値及本質無知的人), 즘양급여평가, 단시저일이론시일개해석자연화인간본질급설명기변화적이론(但是這一理論是一個解釋自然和人間本質及說明其變化的理論), 결부회상실기진정적가치(決不會喪失其眞正的價値).

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Poly(dimethylsiloxane)/Ceramic 복합막을 이용한 투과증발에서의 선택도에 대한 온도의 영향

  • 홍연기;홍원희
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.124-126
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    • 1997
  • 1. 서론 : 투과증발이란 비다공성 고분자막을 이용하여 수착, 확산, 및 증발기구를 통해 액체혼합물을 분리하는 기술이다. 따라서 투과증발의 분리효율은 고분자막의 종류 및 형태의 다양성뿐만 아니라 여러 단계의 기구 특성에 의해 결정된다. 일반저긍로 투과증발막의 성능은 분리하고자 하는 물질에 대한 선택도와 투과도로서 나타날 수 있다. (중략) 본 연구에서는 Poly(dimethylsiloxane)과 세라믹 지지체의 복합막을 이용하여 IPA(Isopropanol)/물 계에서의 여러 조업변수에 따른 IPA의 분리특성을 연구하였다.

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Study on the Hydroxyapatite Body Using with the Eugenol (유진놀을 이용한 수산화아파타이트 성형체에 관한 연구)

  • Ryu, Su-Chak
    • Korean Journal of Materials Research
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    • v.14 no.6
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    • pp.375-378
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    • 2004
  • The samples were prepared with hydroxyapatite(HAp) powder and eugenol (Eugenol/HAp = 15, 20, 25, 30wt%). The samples were dried at room temperature. The higher mechanical properties was observed in HAp sample with 25wt% Eugenol. The average compressive and bending strength in HAp with 25wt% Eugenol are 542 kgf/$\textrm{mm}^2$ and 366 kgf/$\textrm{mm}^2$ respectively. This strength is higher compare to that of the cortical bone.

Sorption of Chlorinated Organics in Zeolite-filled PDMS Membranes (Zeolite가 혼합된 PDMS막에 의한 유기염화물의 수착)

  • 최상규;조민석;김진환
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.72-75
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    • 1998
  • 1. 서론 : 막분리기술의 발달과 더불어 휘발성 유기화합물(Volatile Organic Compounds, VOC)의 회수에 막분리기술의 이용이 가능하게 되어 VOC에 대한 선택성와 투과속도가 큰 막재료와 분리효율이 높은 공정의 개발에 관한 연구가 활발히 이루어지고 있다. 막분리기술에 의한 VOC의 회수는 소각이나 흡착등과 같은 기존의 정화방법에 비하여 설비비용과 운전비용이 저가이면서 오염물질을 제거한다는 측면 외에 오염물질을 재이용할 수 있다는 장점 때문에 앞으로 그 이용이 확대되어 갈 전망이다. (생략)

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Pervaporation Separation of Trace Dicholoromethane from Water Using Fluorinated Polysiloxaneimide do Membranes (불소계 폴리실록산이미드 공중합체막을 이용한 저농도 Dichloromethane 수용액의 투과증발)

  • Kim, Jeong-Hoon;Chang, Bong-Jun;Lee, Soo-Bok
    • Membrane Journal
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    • v.17 no.3
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    • pp.184-190
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    • 2007
  • This study reports on the pervaporation separation of a volatile organic compound(VOC), dichloromethane(DCM) from water using fluorinated copolysiloxaneimide membranes. The copolysiloxaneimide membranes were prepared from 4,4'-(hexafluoroisopropylidene)diphthalic anhydride(6FDA) and two diamines(polysiloxane diamine(SIDA), 2-(perfluorohexyl)ethyl-3,5-diaminobenzene(PFDAB)). By varying the ratio of flexible polysiloxane diamine(SIDA)/rigid fluorinated aromatic diamine(PFDAB) from 0/100 to 100/0 mol%, five copolysiloxaneimide membranes were prepared success- fully. The pervaporation properties of DCM/water were examined in terms of two diamine monomer ratio at room temperature and the feed composition of 0.05 wt% in water. It was found that the increase in SIDA content led to high permeation flux and pervaporation selectivity towards DCM by the enhanced sorption/sorption selectivity and diffusion coefficient/diffusion selectivity due to the increased hydrophobicity and fractional free volume.

Flow Lab. : Flow Visualization and Simulation (핵종이동 가시적 현상관찰및 수치모사)

  • Park Chung-Kyun;Cho Won-Jin;Hahn Pi1-Soo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11a
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    • pp.134-142
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    • 2005
  • The experimental setups for flow visualization and processes identification in laboratory scale (so cal led Flow Lab.) has developed to get ideas and answer fundamental questions of flow and migration in geologic media. The setup was made of a granite block of $50{\times}50cm$ scale and a transparent acrylate plate. The tracers used in this experiments were tritiated water, anions, and sorbing cations as well as an organic dye, eosine, to visualize migration paths. The migration plumes were taken with a digital camera as a function of time and stored as digital images. A migration model was also developed to describe and identify the transport processes. Computer simulation was carried out not only for the hydraulic behavior such as distributions of pressure and flow vectors in the fracture but also for the migration plume and the elution curves.

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Simultaneous Removal of Nitrate and Trichloroethylene by Zero Valent Iron and Peat (영가철과 피트를 이용한 질산성질소와 트리클로로에틸렌의 제거)

  • Min, Jee-Eun;Kim, Mee-Jeong;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.10
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    • pp.1074-1081
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    • 2006
  • As common pollutants in surface and groundwater, nitrate nitrogen($NO_3-N$) and trichloroethylene(TCE) can be chemically and biologically reduced by zero valent iron(ZVI) and peat soil. In batch microcosm experiments, chemical reduction of TCE and nitrate was supported by hydrogen from ZVI. For biological degradation of TCE and denitrification peat soil was introduced. ZVI reduced TCE, while peat provided TCE sorption site and microbes performing biological degradation. Nitrate reduction was also achieved by hydrogen from ZVI. In addition, indirect evidence of denitrification was observed. More reduction of TCE and nitrate was achieved by ZVI+peat treatment however nitrated reduction was hindered in the presence of TCE in the system due to the competition for hydrogen. TCE reduction mechanism was more dependent on ZVI, while nitrate was peat-dependent. Hydrogen and methane concentration showed that peat had various anaerobic denitryfing and halorespiring bacteria.