• Title/Summary/Keyword: 수소 재순환

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Two-Phase Flow Analysis of The Hydrogen Recirculation System for Automotive Pem Fuel Cell (자동차용 고분자 연료전지 수소 재순환 시스템의 이상 유동해석)

  • Kwag, Hyun-Ju;Chung, Jin-Taek;Kim, Jae-Choon;Kim, Yong-Chan;Oh, Hyung-Seuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.6
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    • pp.446-454
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    • 2008
  • The purpose of this paper is to analyze two-phase flows of the hydrogen recirculation system. Two-phase flow modeling is one of the great challenges in the classical sciences. As with most problems in engineering, the interest in two-phase flow is due to its extreme importance in various industrial applications. In hydrogen recirculation systems of fuel cell, the changes in pressure and temperature affect the phase change of mixture. Therefore, two-phase flow analysis of the hydrogen recirculation system is very important. Two-phase computation fluid dynamics (CFD) calculations, using a commercial CFD package FLUENT 6.2, were employed to calculate the gas-liquid flow. A two-phase flow calculation was conducted to solve continuity, momentum, energy equation for each phase. Then, the mass transfer between water vapor and liquid water was calculated. Through an experiment to measure production of liquid water with change of pressure, the analysis model was verified. The predictions of rate of condensed liquid water with change of pressure were within an average error of about 5%. A comparison of experimental and computed data was found to be in good agreement. The variations of performance, properties, mass fraction and two-phase flow characteristic of mixture with resepct to the fuel cell power were investigated.

Ammonia-fueled Solid Oxide Fuel Cell Recirculation Systems for Power Generation (암모니아 활용 고체산화물 연료전지 재순환 발전 시스템)

  • JIN YOUNG PARK;THAI-QUYEN QUACH;JINSUN KIM;YONGGYUN BAE;DONGKEUN LEE;YOUNGSANG KIM;SUNYOUP LEE;YOUNG KIM
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.1
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    • pp.40-47
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    • 2024
  • Ammonia is drawing attention as carbon free fuel due to its ease of storage and transportation compared to hydrogen. This study suggests ammonia fueled solid oxide fuel cell (SOFC) system with electrochemical hydrogen compressor (EHC)-based recirculation. Performance of electrochemical hydrogen pump is based on the experimental data under varying hydrogen and nitrogen concentration. As a result, the suggested system shows 62.04% net electrical efficiency. The efficiency is 10.33% point higher compared to simple standalone SOFC system (51.71%), but 0.02% point lower compared to blower-based recirculation system (62.06%). Further improvement in the EHC-based SOFC recirculation system can be achieved with EHC performance improvement.

Combustion Characteristics of Hypersonic SCRamjet Engine (극초음속 스크램제트 엔진의 연소특성)

  • 원수희;정은주;정인석;최정열
    • Journal of the Korean Society of Propulsion Engineers
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    • v.8 no.1
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    • pp.61-69
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    • 2004
  • This paper describes numerical efforts to characterize the flame-holding and air-fuel mixing process of model SCRamjet engine combustor, where a hydrogen jet injected into a supersonic cross flow and in a cavity Combustion phenomena in a model SCRamjet engine, which has been experimentally studied at University of Queensland and Australian National University using a free-piston shock tunnel, was observed around separation region of upstream of the normal injector and inside of cavity. The results show that the separation region and cavity generates several recirculation zones, which increase the fuel-air mixing. Self ignition occurs in the separation-freestream and cavity-freestream interface.

Study on characteristics of compression and transportation of syngas produced from gasification process of high-calorific waste and Sewage Sludge (고발열량폐기물 및 탈수슬러지 혼합가스화를 통해 생산된 합성가스 압축, 이송 운전 특성)

  • Park, Soo-Nam;Ku, Jae-Hoi
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.832-835
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    • 2009
  • 폐기물의 감량화 및 자원화 기술 중 가장 대표적인 기술로 폐기물의 가스화 용융 기술을 들 수 있다. 폐기물 가스화 용융 기술은 폐기물 내의 탄소 및 수소 성분은 가스화 하여 CO, $H_2$가 주성분인 합성가스(synthesis gas, syngas)로 전환하고, 불연물은 용융하여 환경적으로 무해한 슬래그 또는 금속으로 회수하는 기술이다. 본 연구에서는 고발열량폐기물과 탈수슬러지 혼합가스화를 통하여 생산된 합성가스를 합성가스 압축기를 통하여 유용한 원료물질을 제조하는 공정인 수성가스 전환 반응(water gas shift reaction)과 가스화 반응기의 보조연료로 투입하기 위한 합성가스 압축, 이송 시스템의 운전 특성을 고찰하였다. 그 결과 고발열량폐기물과 탈수슬러지 혼합가스화에서 합성가스는 안정적으로 발생하였으며, 합성가스 압축, 이송시스템을 위한 정제설비에서의 분진제거는 99.07 %의 효율을 얻었고, 또한 합성가스 재순환 장치의 성능시험을 통하여 대기 중의 산소가 유입이 안 되는 기밀성을 확인하였다. 합성가스 압축, 이송 공급 유량 제어 실험 결과로는 합성가스 압축기 기동 시 합성가스 압축압력과 공급유량은 비례적으로 증감하는 것을 알 수 있었다.

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Performance Enhancement and $NO_x$ Reduction in a Hydrogen-Fueled Engine with External Injection by Using VVT (VVT 사용에 의한 흡기관 분사식 수소기관의 성능 향상 및 $NO_x$ 감소)

  • Huynh, Thanhcong;Lee, Kwang-Ju;Lee, Jong-Tai
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.6
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    • pp.474-481
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    • 2008
  • 수소 기관에서 역화없이 고성능과 저$NO_x$를 실현시키기 위하여 밸브 타이밍 변화에 따른 흡기관 분사식 수소 기관의 성능을 파악하고 가솔린의 경우와 비교하였다. 그 결과 흡기밸브 타이밍은 역화억제와 성능향상에 큰 영향을 미치는 것을 확인하였다. 흡기밸브타이밍의 진각은 역화를 억제하며 효율과 출력을 동시에 향상된다. 비록 흡기밸브 타이밍 변화에 의해 NOx는 증가하지만, 희박영역인 출 ${\Phi}=0.5$에서 현저히 감소된다. 또한 열효율은 ${\Phi}=0.5$ 토크는 ${\Phi}=1.0$에서 가장 높게 나타난다. 흡기밸브 타이밍을 $ATDC20^{\circ}$에서 TDC로 변화시켰을 때, ${\Phi}=1.0$에서 토크는 약 28% 증가되고, ${\Phi}=0.5$에서 효율은 약 7%향상된다.

The Design and Test of Ejectors for a 75-kW Fuel Cell System (75kW급 연료전지 시스템의 이젝터 설계 및 시험)

  • Kim, Beom-Joo;Kim, Do-Hyeong;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.678-685
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    • 2011
  • An Ejector enhances system efficiency, are easily operated, have a mechanically simple structure, and do not require a power supply. Because of these advantages, the ejector has been applied to a variety of industrial fields such as refrigerators, power plants and oil plants. In this work, an ejector was used to safely recycle anode tail gas in a 75-kW Molten Carbonate Fuel Cell (MCFC) system at KEPCO Research Institute. In this system, the ejector is placed at mixing point between the anode tail gas and the cathode tail gas or the fresh air. Commercial ejectors are not designed for the actual operating conditions for our fuel cell system. A new ejector was therefore designed for use beyond conventional operating limits. In the first place, a few sample ejectors were manufacured and the entrainment ratio was measured at a dummy stack. Through this experiment, the optimum ejector was chosen. The 75-kW MCFC system equipped with this optimum ejector was operated successfully.

Gasification characteristics of wood pellet in Twin-Bed gasifier (Twin-Bed 가스화기에서의 우드펠릿의 가스화 특성)

  • Lee, Moon-Won;Hwang, Hun;Hong, Jae-Jun;Choi, Sun-Yong;Kim, Lae-Hyun
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2010.04a
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    • pp.188-188
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    • 2010
  • 수소 에너지는 화석연료의 한정된 매장량과 연소시 발생되는 환경문제를 해결하기 위해 가장 이상적인 대체에너지로서 주목을 받고 있다. 그러나 현재까지의 기술로는 경제성 있는 수소 제조가 쉽지 않다. 그 방법 중 바이오매스 및 유기성폐기물의 가스화를 통한 수소제조분야는 자원의 재순환, 페기물 처리, 열원의 이용, 직접적인 $CO_2$ 삭감 등의 부수적인 효과가 높아 경제성 있는 수소제조법으로 평가되고 있다. 이에 본 연구에서는 수소 생산을 목적으로 하는 가스화기와 초고온개질기로 구성된 Twin-Bed 가스화 시스템을 개발하고, 이를 이용한 Wood pellet(미송)의 가스화 특성 및 생성 가스의 초고온개질 특성을 고찰하는 것을 목적으로 한다. 가스화기의 시간변화에 따른 생성 가스 수율에 대한 결과, 생성 가스 수율은 약 20분경과 후 안정화되었으며, 실험 2시간 동안의 $H_2,\;CH_4,\;CO,\;CO_2$의 평균 수율은 각각 17.77, 11.94, 42.13, 28.16 Vol.%의 결과를 보였다. 가스화기로부터 생성된 가스는 down-draft 형태의 고온개질기로 도입시켜, $1100^{\circ}C$의 초고온에서 개질반응을 수행하였다. $CH_4$의 경우 11.95 Vol.%에서 0 Vol.%로 거의 대부분 분해되었으며, $H_2$는 17.77 Vol.%에서 25.46 Vol.%로 약 65.8% 증가하는 결과를 나타냈다. 또한 수소 생성량은 평균 5 L/min kg-Biomass이었다. 냉가스 효율은 72.1%로서 나타나, 일반적으로 폐기물의 냉가스 효율인 약 50% 전후의 결과에 비하여 높은 효율을 보였다.

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LES Analysis on Combustion Characteristics of a Hydrogen/Methane Gas Turbine Combustor (LES 기법을 이용한 수소/메탄 가스터빈 연소기의 연소특성 분석)

  • Nam, Jaehyun;Lee, Younghun;Yoh, Jai-ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.48 no.8
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    • pp.589-595
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    • 2020
  • Large eddy simulation (LES) of a partially premixed gas turbine combustor is conducted. Four different hydrogen compositions are considered to investigate the fuel composition effects on the flow field inside the combustor. The comparison with the experimental flame structure and velocity profile is conducted to verify the LES results, revealing that the partially premixed flame structure is altered when hydrogen composition is changed. The flame structure becomes shorter and thicker as the hydrogen composition is increased, and therefore, the flame effect in the rigid wall is minimized. The change in the recirculation zone at the combustor wall with hydrogen addition is further investigated. Overall, the LES with combustion model is quite promising for accurately predicting the reactive flow characteristics in connection with the fuel composition.

Evaluation of Concrete Materials for Desulfurization Process By-products (황부산물의 콘크리트 원료 활용 가능성 평가)

  • Park, Hye-Ok;Kwon, Gi-Woon;Lee, Kyeong-Ho;Kim, Moon-Jeong;Lee, Woo-Weon;Ryu, Don-Sik;Lee, Jong-Gyu
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.4
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    • pp.15-22
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    • 2020
  • The landfill gas produced in landfill is generally made up of methane(CH4) and carbon dioxide(CO2) of more than 90%, with the remainder made up of hydrogen sulfide(H2S). However, separate pre-treatment facilities are essential as hydrogen sulfide contained in landfill gas is combined with oxygen during the combustion process to generate sulfur oxides and acid rain combined with moisture in the atmosphere. Various desulfurization technologies have been used in Korea to desulfurize landfill gas. Although general desulfurization processes apply various physical and chemical methods, such as treatment of sediment generation according to the CaCO3 generation reaction and treatment through adsorbent, there is a problem of secondary wastes such as wastewater. As a way to solve this problem, a biological treatment process is used to generate and treat it with sludge-type sulfide (S°) using a biological treatment process.In this study, as a basic study of technology for utilizing the biological treatment by-products of hydrogen sulfide in landfill gas, an experiment was conducted to use the by-product as a mixture of concrete. According to the analysis of the mixture concrete strength of sulfur products, the mixture of sulfur by-products affects the strength of concrete and shows the highest strength value when mixing 10%.

Study on Emission Characteristics in a Hydrogen-fueled Engine (수소기관에서의 배기가스에 관한 연구)

  • Cho, U.L.;Ghoi, G.H.;Bae, S.C.
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.1
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    • pp.83-89
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    • 2002
  • The goal of this research is to understand the NOx emission in direct injected diesel engine with premixed hydrogen fuel. Hydrogen fuel was supplied into the test engine through the intake pipe. Amount of hydrogen-supplemented fuel was 70 % basis on heating value of the total input fuel. The effects of intake air temperature and exhaust gas recirculation(EGR) on NOx emission were studied. The intake air temperatures were varied from $23^{\circ}C$ to $0^{\circ}C$ by using liquid nitrogen. Also, the exhaust gas was recirculated to the intake manifold and the amount of exhaust gas was controlled by the valve. The major conclusions of this work include: ( i ) nitrogen concentrations in the intake pipe were increased by 30% and cylinder gas temperature was decreased by 24% as the intake air temperature were changed from $23^{\circ}C$ to $0^{\circ}C$; ( ii ) NOx emission per unit heating value of supplied fuel was decreased by 45% with same decrease of intake air temperature; and (iii) NOx emission was decreased by 77% with 30% of EGR ratio. Therefore, it may be concluded that EGR is effective method to lower NOx emission in hydrogen fueled engine.