• Title/Summary/Keyword: 수소 수요 예측

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A Study on the Collection Efficiency of A Tritium Bubbler (삼중수소 버블러의 포집효율에 대한 고찰)

  • Shin Jae-sin;Lee Seung-Ho;Park Kwang-Ryeol
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.172-181
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    • 2005
  • Collection Efficiency of a tritium bubbler being used at domestic nuclear power plants was studied. Equilibrium is attained while tritium vapour in air passes through the bubbler. When a lot of gas sample passes through the bubbler, the tritium concentration of water is raised and volume of water is decreased or increased. These phenomena give effect to the collection efficiency. Estimation of the tritium concentration of the water agreed with our experiments. If relative humidity is higher than 0.5, the efficiency becomes lower than 1 and if relative humidity is lower than 0.5, the efficiency becomes higher than 1, provided collected tritium is evaluated with original volume of the water. Though the relative humidity is riot 0.5, the efficiency can be maintained near 1 by making $\frac{saturated\; water\; vapour(cm^3_w)\times volume \; of \; gas \; sample(cm^3)}{volume\; of\; water(cm^3)}$ small

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Comparison of the Regulatory Models Assessing Off-Site Radiological Dose due to the Routine Releases of Tritium (삼중수소의 환경방출에 따른 주민선량 규제모델의 비교)

  • Hwang Won-Tae;Kim Eun-Han;Han Moon-Hee;Choi Yong-Ho;Lee Han-Soo;Lee Chang-Woo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.2
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    • pp.125-133
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    • 2005
  • Methodologies of NEWTRIT model, NRC model and AIRDOS-EPA model, which are off-site dose assessment models for regulatory compliance from routine releases of tritium into the environment, were investigated. Using the domestic data, if available, the predictive results of the models were compared. Among them, recently developed NEWTRIT model considers only doses from organically bounded tritium (OBT) due to environmental releases of tritiated water (HTO) . A total dose from all exposure pathways predicted from AIRDOS-EPA model was 1.03 and 2.46 times higher than that from NEWTRIT model and NRC model, respectively. From above result, readers should not have an understanding that a predictive dose from NRC model may be underestimated compared with a realistic dose. It is because of that both mathematical models and corresponding parameter values for regulatory compliance are based on the conservative assumptions. For a dose by food consumption predicted from NEWTRIT model, the contribution of OBT was nearly equivalent to that of HTO due to relatively high consumption of grains in Korean. Although a total dose predicted from NEWTRIT model is similar to that from AIRDOS-EPA model, NEIIfTRIT model may be have a meaning in the understanding of phenomena for the behavior of HTO released into the environment.

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GaN 미소결정의 형상에 미치는 결정 극성의 영향

  • 김병훈;이수민;정수진
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.21-21
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    • 2002
  • 극축을 따라 나타나는 결정학적 이방성이 결정성장에 미치는 영향을 알아보기 위해서 SiO₂막 위에서 GaN 미소결정들을 성장시켰다. 미소결정을 구성하는 면들은 PBC이론이 예측한 바와 같이 {10-11], {0001}, {10-10}이었다. 극축인 c축을 따라서 현저한 성장의 이방성을 관찰할 수 있었으며 (0001)면이 매우 빨리 성장 하여 사라지는 현상을 확인하였다. 이것은 sp3결합에서 나타나는 고립전자쌍이 (000-1)면의 성장을 저지함으로서 나타나는 현상이라고 생각된다. 성장 중 결정표면의 전자상태에 따라 수소흡착이 일어날 수 있는데, 특히 {10-11}면과 같은 한 개의 전자로 이루어진 sp3결합 팔은 매우 많은 양의 수소를 흡착하여 {10-11}면의 성장을 저지한다. 따라서 +c축 방향의 경우 빨리 성장하고 수소흡착을 위한 전자가 없는 (0001)면 대신 {10-11}면이 외형상 매우 중요한 면으로 나타나게 된다. 저온에서는 {10-10}, {10-12}면들도 나타났으며 극축을 따라 나타나는 쌍정을 대부분의 미소결정 성장과정에서 관찰 하였다. r-plane 사파이어 기판 위에서 성장시킨 GaN 미소 결정을 통하여 극성과 GaN의 성장속도 차이를 확인할 수 있었다.

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Trickle Bed에서의 용존산소 제거반응

  • 이한수;강희석;정흥석;안도희;백승우;이성호;김광락
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11a
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    • pp.140-144
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    • 1996
  • Trickle bed를 이용하여 고분가 촉매에 의한 용존산소 제거반응을 수행하였다. 고분자 촉매는 폴리스티렌-디비닐 벤젠의 공중합체로 이루어진 담체를 제조하여 백금 용액을 함침시킨 후 수소로 환원하여 제조하였다. trickle bed는 수소 및 산소로 포화되어 있는 물을 향류식으로 접촉할 수 있도록 설계하였다. 이 경우는 액상 실험 장치와 달리 포화기가 없기 때문에 장치는 비교적 단순하였으나 컬럼내에 축적되는 액상의 축적이 중요한 운전변수로 나타났다. trickle bed에서의 용존산소 제거 거동을 semi-empirical relation으로 나타내어 실험치와 비교한 결과 예측된 모델과 매우 잘 일치하는 것으로 나타났다.

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A Numerical Modeling of the Temperature Dependence on Electrochemical Properties for Solid Oxide Electrolysis Cell(SOEC) (고체 산화물 수전해 시스템(SOEC)에서 전기화학적 특성의 온도 의존성에 대한 수치 모델링)

  • Han, Kyoung Ho;Jung, Jung Yul;Yoon, Do Young
    • Journal of Energy Engineering
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    • v.29 no.2
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    • pp.1-9
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    • 2020
  • In recent days, fuel cell has received attention from the world as an alternative power source to hydrocarbon used in automobile engines. With the industrial advances of fuel cell, There have been a lot of researches actively conducted to find a way of generating hydrogen. Among many hydrogen production methods, Solid Oxide Electrolysis Cell(SOEC) is not only a basic way but also environment-friendly method to produce hydrogen gas. Solid Oxide Electrolysis Cell has lower electrical energy demands and high thermal efficiency since it is possible to operate under high temperature and high pressure conditions. For these reasons, experimental researches as well as studies on numerical modeling for Solid Oxide Electrolysis Cell have been under way. However, studies on numerical modeling are relatively less enough than experimental accomplishments and have limited performance prediction, which mostly is considered as a result from inadequate effects of electrochemical properties by temperature and pressure. In this study, various experimental studies of commercial Membrane Electrode Assembly (MEA) composed of Ni-YSZ (40wt%, Ni-60 wt% YSZ)/8-YSZ (TOSOH, TZ8Y)/LSM (La0.9Sr0.1MnO3) was utilized for improving effectiveness of SOEC model. After numerically analyzing effects of electrochemical properties according to operating temperature, causing the largest deviation between experiments and simulation are that Charge Transfer Coefficient (CTC), exchange current density, diffusion coefficient, electrical conductivity in SOEC. Analyzing temperature effect on parameter used in overpotential model is conducted for modeling of SOEC. cross-validation method is adopted for application of various MEA and evaluating feasibility of model. As a result, the study confirm that the numerical model of SOEC based on structured process of effectiveness evaluation makes performance prediction better.

뇌의 수소 분광선 연구를 위한 다중 체적 화학적 이동 영상기법의 개발

  • Choe, Jeong-Hwan;Park, Seung-Hun;Kim, Si-Seung;Jeong, Seong-Taek;Lee, Yun
    • Proceedings of the KSMRM Conference
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    • 2002.11a
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    • pp.105-105
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    • 2002
  • 목적: 수소 자기 공명 분광기법은 자기공명 영상으로는 얻을 수 없는 화학적 성분에 대한 정보를 제공하여 암을 포함한 여러 질환의 진단과 예측에 사용된다. 이 기법으로는 어떤 특정한 작은 체적을 선택하여 그 부위에만 자기공명 분광신호를 획득하는 단일 체적기법과 체적 전체를 위상변화를 주면서 여기시킨 후, 데이터 후처리 과정에서 체적별로 분리해내는 다중체적기법이 있다. 다중체적기법은 더 긴 영상 획득시간에도 불구하고 단일 체적기법에 비하여 분광상을 대조군과 비교할 수 있는 잇점이 있다. 뇌를 진단하는데 사용하기 위한 수소분광선을 얻기 위하여 다중체적 화학적 영상기법을 개발하여 모형과 자원자에 대하여 적용하여 그 유용성 확인하였다.

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뇌의 수소 분광선 연구를 위한 다중 체적 화학적 이동 영상기법의 개발

  • Choi, Jung-Hwan;Park, Seung-Hoon;Kim, Si-Seung;Jung, Sung-Taek;Lee, Yoon
    • Proceedings of the KSMRM Conference
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    • 2002.11a
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    • pp.81-81
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    • 2002
  • 목적: 수소 핵 자기 공명 분광기법은 자기공명 영상으로는 얻을 수 없는 화학적 성분에 대한 정보를 제공하여 암을 포함한 여러 질환의 진단과 예측에 사용된다. 이 기법으로는 어떤 특정한 작은 체적을 선택하여 그 부위에만 자기공명 분광신호를 획득하는 단일 체적기법과 체적 전체를 위상변화를 주면서 여기 시킨 후, 데이터 후처리 과정에서 체적별로 분리해내는 다중체적기법이 있다. 다중체적기법은 더 긴 영상 획득시간에도 불구하고 단일 체적기법에 비하여 분광상을 대조군과 비교할 수 있는 잇점이 있다. 뇌를 진단하는데 사용하기 위한 수소분광선을 얻기 위하여 다중체적 화학적 영상기법을 개발하여 모형과 자원자에 대하여 적용하여 그 유용성 확인하였다.

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Prediction of the Edge Sealing Shape on the Vacuum Glazing Using the Nonlinear Regression Analysis (비선형회귀분석을 이용한 진공유리 모서리 접합단면 형상예측)

  • Kim, Youngshin;Jeon, Euysik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.3
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    • pp.1016-1021
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    • 2013
  • While using the hydrogen mixture gas torch, the glass edge sealing and the shape of the edge sealing parts is affected by many parameters such as flow rate of gas, traveling speed of torch, distance between glass and torch. As the glass edge sealing shape have effects on the insulation and airtightness and strength of the glass panel; the sealing shapes are predicted according to the process parameters. The paper highlight the nonlinear regression equations of the cross-sectional shape of the sealing shape according to the parameters, that is experimentally predicted later compared and verified the equation with the experimental result.

Analysis of $^1H$ Magnetic Resonance Spectroscopy Pattern in Invasive Ductal Carcinoma of Breast (유방 침윤성 관상피암에서 수소핵 자기공명분광상의 특성 분석)

  • Cho, Jae-Hwan;Park, Cheol-Soo;Lee, Sun-Yeob;Kim, Bo-Hui
    • Progress in Medical Physics
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    • v.21 no.1
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    • pp.22-28
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    • 2010
  • To evaluate the potential value of $^1H$ Magnetic resonance spectroscopy (MRS) for detecting and characterizing invasive ductal carcinoma of breast. We conducted $^1H$ Magnetic resonance spectroscopy (MRS), using a 3.0T MR scanner, on 40 patients who were histologically diagnosed to have invasive ductal carcinoma (IDC); tumor areas of the patients were designated as experimental samples, and non-tumor areas as control samples. The peak at 3.2 ppm is characteristically intense and observed in 34 cases of the total 40 invasive ductal carcinoma (sensitivity 86.2%; specificity 100%; positive predictive value 100%; negative predictive value 60%). In constrast peak at 1.3 ppm is characteristically intense and observed in normal breast (sensitivity 86.2%; specificity 100%; positive predictive value 100%; negative predictive value 60%). The study shows that $^1H$ MRS can effectively discriminate invasive ductal carcinoma from normal breast in most cases. It also demonstrates the feasibility of localized in vivo $^1H$ MRS technique as a new diagnostic modality in the detection of breast tumor.

Numerical Study of Heat Flux and BOG in C-Type Liquefied Hydrogen Tank under Sloshing Excitation at the Saturated State (포화상태에 놓인 C-Type 액체수소 탱크의 슬로싱이 열 유속과 BOG에 미치는 변화의 수치적 분석)

  • Lee, Jin-Ho;Hwang, Se-Yun;Lee, Sung-Je;Lee, Jang Hyun
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.35 no.5
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    • pp.299-308
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    • 2022
  • This study was conducted to predict the tendency for heat exchange and boil-off gas (BOG) in a liquefied hydrogen tank under sloshing excitation. First, athe fluid domain excited by sloshing was modeled using a multiphase-thermal flow domain in which liquid hydrogen and hydrogen gas are in the saturated state. Both the the volume of fluid (VOF) and Eulerian-based multi-phase flow methods were applied to validate the accuracy of the pressure prediction. Second, it was indirectly shown that the fluid velocity prediction could be accurate by comparing the free surface and impact pressure from the computational fluid dynamics with those from the experimental results. Thereafter, the heat ingress from the external convective heat flux was reflected on the outer surfaces of the hydrogen tank. Eulerian-based multiphase-heat flow analysis was performed for a two-dimensional Type-C cylindrical hydrogen tank under rotational sloshing motion, and an inflation technique was applied to transform the fluid domain into a computational grid model. The heat exchange and heat flux in the hydrogen liquid-gas mixture were calculated throughout the analysis,, whereas the mass transfer and vaporization models were excluded to account for the pure heat exchange between the liquid and gas in the saturated state. In addition, forced convective heat transfer by sloshing on the inner wall of the tank was not reflected so that the heat exchange in the multiphase flow of liquid and gas could only be considered. Finally, the effect of sloshing on the amount of heat exchange between liquid and gas hydrogen was discussed. Considering the heat ingress into liquid hydrogen according to the presence/absence of a sloshing excitation, the amount of heat flux and BOG were discussed for each filling ratio.