• Title/Summary/Keyword: 수성 수지

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Development of Concrete-Polymer Composite(II) -Physical Properties of Polymer(Resin) Concrete- (콘크리트-폴리머 복합재료 개발(II) -폴리머(레진) 콘크리트의 물성-)

  • Hwang, Eui-Hwan;Hwang, Taek-Sung;Kil, Deog-Soo
    • Applied Chemistry for Engineering
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    • v.10 no.7
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    • pp.1066-1072
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    • 1999
  • The physical properties of polymer concrete were investigated for development of high-performance construction materials. Various specimens of polymer concrete were prepared using unsaturated polyester resin as the polymer-binder with the various dosage of calcium carbonate as microfiller (5~20 wt %) and fine aggregate(10~50 wt %). For the evaluation of the physical properties of polymer concretes, tests such as compressive strength, flexural strength, water absorption test, hot water immersion test, acid resistance test and pore size distribution analysis were conducted. As a result, it is concluded that compressive and flexural strengths of polymer concretes increased up to 4 times than those of conventional cement concrete. Whereas the compressive and flexural strengths of polymer concretes tested after hot water immersion, compared with those of polymer concretes tested before hot water immersion, decreased about 67%, 47%, respectively. By hot water immersion, total pore volume and porosity(%) of polymer concretes were remarkable increased due to decomposition of polymer binder. And also, it is showed that water absorption(%) and weight loss(%) of polymer concrete specimens by acid immersion, compared with those of ordinary portland cement concrete, decreased about 1/100, 1/27, respectively.

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Physical Properties of Fabric E-glass Fiber Reinforced Laminated Timber (I) - Mechanical Properties - (직물유리섬유 강화집성재의 물리적 특성(제1보) - 기계적 특성 -)

  • Jung, In-Suk;Lee, Weon-Hee;Byeon, Hee-Seop
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.5
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    • pp.23-34
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    • 2003
  • This study was carried out to investigate the mechanical properties of fabric E-glass fiber reinforced laminated timber. Specimens used to Korean red pine(Pinus densiflora) and Japanese larch(Larix kaemferi). Fabric E-glass fiber was inserted in the solid wood with aqueous polymer-isocyanate resin(MPU-500). The results were as follows: 1. Aqueous polymer-isocyanate resin(MPU-500) was good resin to manufacture laminated timber. specially, it was satisfied to property standard of construction laminated timber(KS F 3021) except for two ply glass fiber. 2. Bending and shear strengths of solid wood inserted with fabric glass fibers were not different from control solid wood. But, proportional limit bending stress was increased following the number of fabric glass fibers. Therefore, it was considered that to improve the bending and shear strength of fabric glass fiber reinforced laminated timber, the glass fiber thickness and its mesh should be modified to fitness following working conditions.

Sustainable Yield of Groundwater Resources of the Cheju Island (제주도 지하수자원의 최적 개발가능량)

  • Hahn, Jeong-Sang;Hahn, Kyu-Sang;Kim, Chang-Kil;Kim, Nam-Jong;Hahn, Chan
    • Journal of the Korean Society of Groundwater Environment
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    • v.1 no.1
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    • pp.33-50
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    • 1994
  • The Hydrogeologic data of 455 water wells comprising geologic log and aquifer test were analyzed to determine hydrogeologic characteristics of the Cheju island. The groundwater. of the Cheju island is occurred in unconsolidated pyroclastic deposits and crinker interbedded in highly jointed basaltic and andesic rocks as high level, basal and parabasal types under unconfined condition. The average transmissivity and specific yield of the aquifer are at about 29,300㎡/day and 0.12 respectively, The total storage of groundwater is estimated about 44 billion cubic meters. Average annual precipitation is about 3,390 million ㎥ among which average recharge is estimated for 1,494 million ㎥ being equivalent 44.1% of total annual precipitation with 638 million ㎥ of runoff and 1,256 million ㎥ of evapotranspiration. Based on groundwater budget analysis, the sustainable yield is about 620 million ㎥(41% of annual recharge)and rest is discharging into the sea. The geologic logs of recently drilled thermal water wells indicate that very low-permeable marine sediments(Sehwa-ri formation) composed of loosely cemented sandy silt derived from mainly volcanic ashes at the 1st stage volcanic activity of the area is situated at the 120${\pm}$68m below sea level. Another low-permeable sedimentary rock called Seogipo-formation which is deemed younger than the former marine sediment is occured at the area covering north-west and western part of the Cheju island at the ${\pm}$70m below sea level. If these impermeable beds art distributed as a basal formation of fresh water zone of the Cheju island, the most of groundwater in the Cheju island will be para-basal type. These formations will be one of the most important hydrogeologic boundary and groundwater occurences in the area.

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The Change of Water Balance due to Urbanization in Gwangju River Basin (도시화에 수반되는 광주천 유역의 물수지 변화)

  • Yang, Hea-Kun;Kim, Jong-Il
    • Journal of the Korean association of regional geographers
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    • v.10 no.1
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    • pp.192-205
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    • 2004
  • The purpose of this paper is to analyze the factors, which have influence upon changes of hydrological environment in time series, and evaluate water balance changes caused by urbanization. The results of the analysis and evaluation are as follow: At first, the river runoff at Gwangju River Basin keep base flow of river by storage capacity recharged in June to September and show peak in August and minimum flow in May. The groundwater recharge by urbanization accounted for 46.1% of rainfall at early-urban stage, and decreased to 36.5% and 29.9% in the 1960's and the 1990's respectively, and is likely to decrease to 27.8% in the 2010's. On the other hand, the overland flow was 9.6% of rainfall in the 1960's and 16.2% in the 1990's, and is likely to increase to 18.3% in the 2010's. When such a phenomenon is kept continuously, distorted water balance shall be worsened to create not only frequent occurrence of urban flood but also decreased base flow of Gwangju River to accelerate dry stream phenomenon. The time series study on urban redevelopment and environment maintenance describes distorted phenomenon to supply the information for nature-friendly land use, and examines relations between human activities and natural environment.

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Property and performance comparative analysis of yacht sail product using high modulus polyester (고강력 폴리에스터 소재 요트 세일 제품의 특성 및 성능 비교 분석)

  • Son, Hyun-Sik;Sim, Seung-Bum;Yang, Sung-Young;Kim, Su-Sung
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.105-105
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    • 2011
  • 국내 해양레저산업 중 세일요트산업은 현재 초기시장을 형성하고 있으나, 현재 정부의 해양레저 활성화 정책과 해양레저 인구 또한 관련 협회, 클럽 등의 중심으로 급속한 증가세를 이루고 있다. 이에 요트수요 증대에 따라 요트 관련 부품 소재의 경우에도 향후 그 수요가 대폭 증가할 것으로 예상되어지고 있으며, 그 중 요트용 돛(Sail)의 경우에는 전량 해외 수입에 의존하고 있어 제품개발을 통해 국산화함으로써 해외 제품의 수입대체가 요구되고 있다. 본 연구는 해외의 산업용 폴리에스터 원사로 제조된 요트세일 제품의 특성 및 성능 분석 결과와 국산 고강력 폴리에스터 소재로 제조된 요트 세일 개발 제품의 물성 및 성능을 비교 분석하고자 한다. 세일 제품 개발을 위해 해외 요트용 세일 제품을 분석한 결과, 소재는 고상중합형태의 폴리에스터 산업용 원사를 사용하여 직물자체의 고강도 및 저신도 특성발현을 위한 고밀도 제직을 실시한 것으로 분석 되었으며, 가공에서는 해양에서 사용하는 세일 직물의 특성 상 일광 및 자외선에 대한 내구성을 높이고, 황변을 방지할 수 있도록 하기 위해 직물표면에 멜라민계 수지를 이용한 함침방식의 특수코팅을 실시한 것으로 분석되었다. 이러한 해외 요트용 세일 제품의 분석결과를 바탕으로 국산 고강력 폴리에스터 고밀도 직물에 자외선 및 일광에 대한 내구성이 우수한 무황변 타입의 폴리에스터계 수지를 사용하여 단면 코팅으로 양면코팅 가공효과를 부여하는 나이프 방식의 특수코팅, 에이징 처리를 통해 세일을 제조하였다. 본 연구에서는 제조된 세일 직물 제품에 대해, 물리적 특성을 분석하기 위해 인장 강신도, 무게, 두께 및 주사전자현미경 관찰 등의 테스트를 실시하였으며, 세일 성능 분석을 위해 공기투과도, 일광견뢰도 자외선 조사 후 강도변화, 황변 Test 등의 테스트를 실시하여, 해외 선진 제품과 개발제품의 물성 및 성능에 대해 고찰하였다.

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Preparation and Thermal Insulation Property of UV Curable Hybrid Coating Materials Based on Silica Aerogel (실리카 에어로겔을 이용한 자외선 경화형 복합 코팅 물질의 제조 및 단열 특성)

  • Kim, Nam-Yi;Kim, Seong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.141-148
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    • 2012
  • In this study, the composite coating materials with improved thermal insulation property were prepared by incorporating the hydrophobic silica aerogel. The surface modification of silica aerogel was performed to obtain UV curable urethane acrylate hybrid coating sols with good compatibility by using surfactant(Brij 56). The polycarbonate substrates were coated by the prepared composites and cured under UV radiation. The incorporation of aerogel with only 10 vol% of content resulted in remarkable improvement by about 28% in the thermal insulation property of the coated film, as compared with substrate. In addition, increasing aerogel content was found to give minor effect on the variation of optical transparency, adhesion, and surface hardness of the coated film.

A Feasibility Study on the Brazing of Zircaloy-4 with Zr-Be Binary Amorphous Filler Metals (비정질 이원계 합금 Zr-Be 용가재를 이용한 지르칼로이-4의 브레이징 타당성 검토)

  • 고진현;박춘호;김수성
    • Journal of Welding and Joining
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    • v.17 no.4
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    • pp.26-31
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    • 1999
  • An attempt was made in this study to investigate the brazing characteristics of Zr-Be binary amorphous alloys for the development of a new brazing filler metal for joining Zircaloy-4 nuclear fuel cladding tubes. This study was also aimed at the feasibility study of rapidly solidified amorphous alloys to substitute the conventional physical vapor-deposited(PVD) metallic beryllium. The $Zr_{1-x}Be_{x}$($0.3\leq$x$\leq0.5$) binary amorphous alloys were produced in the ribbon form by the melt-spinning method. It was confirmed by x-ray diffraction that the ribbons were amorphous. The amorphous. the amorphous alloys were used to join bearing pads on Zircaloy-4 nuclear fuel cladding tubes. Using Zr-Be amorphous alloys as filler metals, it was found that the reduction in the tube wall thickness caused by erosion was prevented. Especially, in the case of using $Zr_{0.65}Be_{0.35}$ and $Zr_{0.7}Be_{0.3}$ amorphousalloys, the smooth and spherical primary $\alpha$-Zr particles appeared in the brazed layer, which was the most desirable microstructure from the corrosion-resistance standpoint.

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Preparation and Mechanical Properties of Bulk Molding Compound Composite Prepared using Recycled FRP Waste Powder (폐FRP 미분말을 재활용한 BMC 복합재료의 제조 및 기계적 물성)

  • Hwang, Eui-Hwan;Jeon, Jong-Ki
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.217-223
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    • 2010
  • In general, fiber-reinforced plastics (FRP) wastes are simply buried or burned. Landfill brings about a permanent contamination of soil due to the inability of FRP to decompose and incineration causes an issue of generating toxic gases and dusts. There have been several ways to treat the FRP wastes such as landfill, incineration, chemical recycling, material recycling and the utilization of energy from combustion. Most methods excluding material recycling are known to have critical limitations in economic, technical and environmental manners. However it is known that material recycling is most desirable among the methods handling FRP wastes. In this study, to investigate the purpose of feasibility of material recycling, various bulk molding compound (BMC) specimens were prepared with the various contents of unsaturated polyester resin binder (25, 30, 35 wt%) and the various replacement ratios of FRP wastes powder (0, 25, 50, 75, 100 wt%) substituted for filler. To evaluate the physical properties BMC specimens, various tests such as tensile strength, flexural strength, impact strength, hot water resistance and SEM imaging were conducted. As a results, mechanical strengths decreased with an increase of replacement ratio of FRP waste powder and physical properties of BMC specimens were deteriorated in the hot water resistance. The fluidity of BMC with more than 50 wt% of the replacement ratio of FRP wastes powder decreased remarkably, causing a problem in the BMC composite.

A Study on the Elution of the PVC Film Containing Norbornene Dialkylester (노보넨 다이알킬에스터를 포함한 PVC필름의 용출성 연구)

  • Jang, Hye-Jin;Park, Seong-Ho;Woo, Je-Wan
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.225-228
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    • 2018
  • Plasticizers added to thermoplastic polymers are known to shorten the life of products due to the elution to outside, and some of them are harmful to our environment and human body. Since the use of phthalate plasticizers suspected of being carcinogens has been gradually prohibited, there is a need for environmentally friendly plasticizers that can replace them. Most of the substances have a low compatibility with resin, high cost and lack of safety verification. Therefore, in this study, four kinds of norbornene dialkyl ester compounds possessing excellent physical properties, which are also reported as safe compounds from the toxicity evaluation, were added to PVC resin to evaluate the possibility of human exposure by leaching, and also the potential usage as plasticizer candidates alternative to commercial ones including DEHP, DINCH and DOTP. The test was carried out according to the American standard test method (ASTM). The results showed that di-2-ethylhexyl-5-norbornene-2,3-dicarboxylate (DEHN) in aqueous solvents and diisopentyl-5-norbornene-2,3-dicarboxylate (DIPN) compounds in oil solvents were superior or equivalent to DEHP. In addition, all four norbornene compounds showed lower values than 100 ppm, which is considered to have an influence on the environment, indicating that the polar norbornene structure affects the elution.

A Conceptual Design on Performance Test Facility of Disposal Cover for the Near Surface Disposal of Low and Intermediate Level Radioactive Waste (중.저준위 방사성폐기물 천층처분을 위한 처분덮개의 성능실증 시험시설 개념설계)

  • 이찬구;박세문;김창락;염유선;이은용
    • The Journal of Engineering Geology
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    • v.11 no.3
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    • pp.245-254
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    • 2001
  • The experimental study on disposal cover through the performance test facility offers reliability in the safety of near surface disposal of low and intermediate level radioactive waste. To ensure the long-term safety of the repository, the impermeability, integrity, resistance to degradation and ease of maintenance might be considered as the basic performance requirement of the disposal cover. considering the difficulties to meet these performance requirement by using single layer, the disposal cover design which is composed of top layer, middle drainage layer and bottom low permeability layer is schemed for the test facility. The water balance of the cover was evaluated by using HELP code. For the long-term monitoring of the soil moisture content and matric potential, TDR probes and tensiometers will be installed in 6 test cells. Each test cell is dimensioned 3$\times$3$\times$3.3m.

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