• Title/Summary/Keyword: 수분 흡착

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ADZ500 흡착제에 의한 아세톤 증기 중 수분의 선택흡착에 관한 연구

  • Na, Yeong-Su;Yun, Yeong-Sam;Jeong, Jae-Hyeon;Lee, Gwang-Ho;An, Chang-Deok
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2007.05a
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    • pp.65-68
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    • 2007
  • 수분선택흡착-VOCs흡착-압축응축식 hybrid 공정에서 수분의 선택분리가 가능한 흡착제를 선정하였다. 또한 수분흡착탑에서 미리 수분을 제거하여 VOCs의 흡착효율을 높임으로써 배출환경기준을 만족시키고 수분 혼합성 VOCs와 수분 비혼합성 VOCs 회수가 가능한 공정 운영이 가능함을 알 수 있었고, 회수된 VOCs를 곧바로 생산 공정에 재투입할 수 있는 원료물질 수준으로 회수가 가능하였다.

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The Properties of Carbonaceous Desiccant Derived from Phenolic Resin (페놀레진으로부터 유도된 탄소질 수분 흡수제의 특성)

  • Oh, Won-Chun
    • Analytical Science and Technology
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    • v.13 no.3
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    • pp.332-337
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    • 2000
  • The study on the nitrogen adsorption, surface properties and water adsorption capacity of the carbonaceous desiccants derived from phenolic resin was carried out. In the nitrogen adsorption study on the carbonaceous desiccants, Type II isotherm for each sample was obtained. Furthermore, the adsorbed volume decrease with water washing of the desiccant. The $S_{BET}$ of the carbonaceous desiccants was $648.7m^2/g$ before washing and $189.3m^2/g$ after washing, respectively. The morphology of needlelike formation before washing and spherical particle after washing with water were observed from SEM micrographs. Finally, from the water adsorption effects, the percentage of the water loading capacity was 25-63%, and the capacity was good at relatively low humidity.

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Adsorption Characteristics and Moisture Content Prediction Model of Coffee with Water Activity and Temperature (수분활성과 온도변화에 따른 커피의 흡착특성 및 흡착량 예측모델)

  • Youn, Kwang-Seop;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
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    • v.22 no.6
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    • pp.690-695
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    • 1990
  • The adsorption characteristics of coffee were mvestigated at $5, 15, 25, and 35^{\circ}C$ under various water activities such as 11, 32, 57, 75 and 90% and prediction models were developed by optimization program. The moisture adsorption isotherm curves were similar to the typical sigmoid type. The values of equilibrium moisture content and the monolayer moisture content were highest in the Freeze Dried, which was due to porous structure by the drying method. In the result of adjusting the isotherm models in this paper, Halsey model generally gave the best fit for isotherms of coffee. Prediction model for equilibrium moisture content was established with water activity and temperature. Adsorption prediction models were also developed with water activity, with water activity and time, and with water activity, time and temperature, respectively.

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Physical Properties of Fabric E-Glass Fiber Reinforced Laminated Timber (II) - Peeling and vapor adsorption properties - (직물유리섬유강화 집성재의 물리적 특성(제2보) - 박리 및 흡습성 -)

  • Jung, In-Suk;Lee, Weon-Hee;Kim, Jong-Man
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.5
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    • pp.35-42
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    • 2003
  • This study was conducted to estimate peeling and vapor adsorption properties made with fabric glass fiber reinforced laminated timber according to our earlier report(Jung et al., 2002). In adsorption peeling test, three all types solid wood were not appeared the peeling. However, solid wood appeared to the peeling in boiling peeling test except for control wood. Vapor adsorption test was performed at 40℃, 90% relative humidity for 48 hours. Cross sections were not different all solid wood. Radial section and tangential section with glass fiber were delayed vapor adsorption compared to control wood. In anisotropy of vapor adsorption, solid wood with glass fiber were small values.

A Study on Moisture Adsorption Capacity by Charcoals (숯의 수분 흡착성능 연구)

  • Kim, Dae Wan;An, Ki Sun;Kwak, Lee Ku;Kim, Hong Gun;Ryu, Seung Kon;Lee, Young Seak
    • Korean Chemical Engineering Research
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    • v.60 no.3
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    • pp.377-385
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    • 2022
  • Surface morphology and adsorption characteristics of charcoals prepared from Korean traditional kiln were analyzed, and their moisture adsorption capacities were examined with respect to humidity and temperature change. Moisture adsorption capacities of red-clay powder, activated carbon fiber fabric (ACF fabric) and activated carbon fiber paper(ACF paper) were also examined to compare with those of charcoals. Moisture adsorption capacity of charcoal was low less than 45% humidity due to its hydrophobic property, but it slowly and linearly increased as increasing the humidity. Moisture adsorption capacity of red-clay powder was similar to charcoal at low level humidity, it increased exponentially as increasing the humidity showing Type V adsorption isotherm. Therefore, the weather forecast annal prepared by employee of weather centre in Joseon Dynasty is experimentally approved. ACF fabric and ACF paper show excellent moisture adsorption capacities, which can be used to humidity measuring sensor. Adsorption isotherm of charcoal slice was peculear showing the mixed Type I and Type IV due to low-pressure hysteresis that was occurred from embedment of nitrogen in crevice of charcoal. The specific surface area of charcoal increased by grinding charcoal slice to powder, resulted in increasing the desorption amount of adsorbent at low relative pressure.

Computation of Electric Field by Droplet on HV Insulator Surface (고체 절연물 표면의 흡착수분에 따른 전계분포 해석)

  • Kim, Ju-Han;Han, Sang-Ok;Lee, Sei-Hyun
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.2027-2029
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    • 2008
  • 옥외용 고전압 절연물의 절연성능은 표면저항과 밀접한 관계를 가지며, 이는 절연물 표면에 존재하는 수분의 거동에 의해 민감하게 반응하게 된다. 또한 절연물 표면에 흡착된 수분의 존재로 인해 절연물과 수분, 공기층의 유전율 차이로 인해 경계면에서의 전기력선속과 공간전하밀도의 변화가 급격해지므로 불평등전계를 형성할 우려가 있다. 따라서 본 논문에서는 옥외용 고전압 절연물의 표면에 작은 물방울 형태로 존재하게 되는 흡착수분에 의한 전계분포를 확인하기 위해 FEM을 이용하여 전산해석을 수행하였다.

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A study on the water sorption and the effect of water sorption on micro-hardness of dual-cure resin cements (이원 중합 레진시멘트의 수분 흡착도와 수분 흡착에 따른 경도 변화 비교 연구)

  • Choi, Su-Jeong;Cho, Jin-Hyun;Lee, Cheong-Hee
    • Journal of Dental Rehabilitation and Applied Science
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    • v.30 no.2
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    • pp.138-144
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    • 2014
  • Purpose: This study examined the water sorption of commonly used dual-cure resin cements and compared the change in the micro-hardness among the cements. Materials and Methods: Five types of dual-cure resin cements (Maxcem, Duo-link, Panavia F, Variolink II, Rely X Unicem) were selected. Fifty specimens were classified into five groups containing ten specimens in each group. The water sorption of the five specimens in each group was evaluated after being immersed in distilled water (DDW) for seven days. The following results were obtained by comparing the specimens immersed in DDW with those not immersed in DDW. Results: 1. The water sorption of Maxcem showed the highest score, followed by Panavia F. These two cements were followed by Duo-link and Rely X Unicem. The water sorption of Variolink II showed the lowest score among the cements used in this study. 2. Among the specimens not immersed in DDW, the micro-hardness of Rely X Unicem showed the highest score followed by Panavia F and Variolink II. These cements were followed in order by Duo-link and Maxcem. 3. Among the specimens immersed in DDW, the microhardness of Rely X Unicem showed the highest score followed by Maxcem, Panavia F and Variolink II. Duo-link shoed the lowest score among the cements used in this study. 4. Maxcem, Duo-link, Panavia F and Rely X Unicem showed significant differences in micro-hardness due to water resorption but Variolink II was unaffected by immersion in water. Conclusion: Using the resin cement which has lower water sorption and higher micro-hardness is recommended.

Dryer Design for High Altitude Engine Test (고공 엔진시험을 위한 Dryer 개발)

  • Park, Berm-Joo;Kim, Tea-In
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.419-423
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    • 2008
  • 엔진 성능의 시험에 있어서 작동유체인 압축공기의 물성중 수분은 매우 중요한 부분으로, 엔진의 작동과 성능에 영향을 미치는 대표적인 요인이다. 특히 고공환경 시험에서는 습도의 조건에 따라 성능의 차이가 커지므로 엔진의 정확한 성능과 운용성을 파악하는데 작동유체인 압축공기중에 포함된 수분의 조건은 대단히 중요하다. 압축상태인 작동유체의 수분 함유량을 고공의 조건과 같은 $-40^{\circ}C$ 이하의 이슬점(Dew Point) 상태로 제습 하기 위한 장치인 흡착식 Air Dryer의 개발을 위해 흡착과정 및 재생과정에 대한 이해와 흡착제의 흡착효율을 극대화하고, 재생비용을 최소화하여 에너지를 저감 할 수 있는 Air Dryer System에 대하여 기술한다.

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Heats of Moisture Adsorption for Sunflower Nutmeat Products (해바라기 종실제품의 수분흡착열)

  • Mok, Chul-Kyoon;Hettiarachchy, N.S.
    • Korean Journal of Food Science and Technology
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    • v.23 no.6
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    • pp.656-660
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    • 1991
  • Heats of moisture adsorption of the sunflower nutmeat products (ground nutmeat, meal, protein concentrate and protein isolate) were determined from their isosteres at temperatures 10, 20 and $30^{\circ}C$. The changes in the heat of adsorption with moisture level were analyzed by Hunter equation. The Hunter equation was valid for representing the relationship between the heat of adsorption and the moisture content for the sunflower nutmeat products, and the accuracy-of-fit increased as protein content of the materials increased. The heat of adsorption decreased as moisture content increased, but increased as protein content increased. The heats of adsorption were 11.8-10.6 kcal/mole for the ground nutmeat at 4-12% moisture (d.b.) and 12.4-11.0 kcal/mole for the protein isolate at 6-20% moisture (d.b.).

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Control of Water-Adsorption Properties of Mesoporous Silica and MOF by Ion Exchange and Salt Impregnation (양이온 교환 및 염 함침을 통한 메조다공성 실리카와 유기-금속 구조체의 수분 흡착 특성 조절)

  • Lee, Eun Kyung;Cho, Kanghee;Kim, Sang Kyum;Lim, Jong Sung;Kim, Jong-Nam
    • Clean Technology
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    • v.24 no.1
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    • pp.55-62
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    • 2018
  • The adsorbent used in water-adsorption cooling system utilizing low-temperature heat of below $90^{\circ}C$ is required to exhibit high water uptake capacity at a relative humidity ($P/P_0$) between 0.1 and 0.3. Mesoporous silica (MCM-41) and MOF(MIL-101) exhibit quite large water adsorption capacity under saturated water vapor at $35^{\circ}C$. However, these adsorbents show small water adsorption capacity ($0.027{g_{water}\;g_{ads}}^{-1}$, $0.074{g_{water}\;g_{ads}}^{-1}$, respectively) in the relative humidity ($P/P_0$) range of 0.1 to 0.3. In this study, the surface properties of mesoporous silica and MOF were modified by simple methods to develop an adsorbent having a higher water uptake than the conventional water adsorbents at a relative humidity ($P/P_0$) of 0.1 ~ 0.3. In the case of mesoporous silica (MCM-41) exhibiting mainly water adsorption at $P/P_0=0.5{\sim}0.7$, aluminum species was functionalized on the mesopore walls and then cations existing near the aluminum were exchanged with various cations (e.g., $Na^+$, ${NH_4}^+$, and $(C_2H_5)_4N^+$). In addition, 20 wt% (to total weight of the composites) of hygroscopic inorganic salt ($CaCl_2$) was impregnated on the MCM-41. In the case of the MIL-101 (MOF), 20 wt% of hygroscopic inorganic salt ($CaCl_2$) was impregnated on the MIL-101. The MCM-41 which was ion-exchanged with various cations has main adsorption branch around 0.5 of $P/P_0$ which was slightly shifted with low-pressure direction in comparison with pristine MCM-41. However, tiny increases were observed on the adsorption in the range of $P/P_0$ between 0.1 and 0.3. After salt impregnation on the MCM-41, the adsorption capacity under $P/P_0=0.1{\sim}0.3$ at $35^{\circ}C$ was increased from $0.027{g_{water}\;g_{ads}}^{-1}$ to $0.152{g_{water}\;g_{ads}}^{-1}$. In the case of MIL-101, the amount of water adsorption at $35^{\circ}C$ under $P/P_0=0.1{\sim}0.3$ was increased from $0.074{g_{water}\;g_{ads}}^{-1}$ to $0.330{g_{water}\;g_{ads}}^{-1}$ after the salt impregnation.