• Title/Summary/Keyword: 수리화학

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Development of one-dimensional river storage model for mixing analysis of hazardous chemicals in rivers (하천에 유입된 유해화학물질 혼합해석을 위한 저장대모형 개발 및 적용)

  • Kim, Byunguk;Seo, Il Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.148-148
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    • 2020
  • 산업의 고도화가 진행됨에 따라 화학원료의 사용이 증가하고 있고 독성을 가진 화학물질이 하천으로 유입되는 사고가 빈번하게 발생하고 있다. 수환경으로 유입되는 유해화학물질은 주로 무색무취의 물질들로 사고가 발생하더라도 초기 발견이 어려워 어류폐사를 유발하거나 취수시설에서 용수로 취수되는 경우가 발생하기 때문에 이에 대한 대응책 마련이 필수적이다. 하천에 유입된 오염물질의 거동을 신속하게 예측하기 위해 1차원 오염물질 추적 모형이 활용되는데, Fickian 이송-분산 모형(Fickian Advection-dispersion equation model; FADE)이 주로 사용되고 있다. 하지만 FADE는 오염물질이 하천 저장대에서 지체되는 현상을 반영하지 못하기 때문에 농도곡선의 왜곡도를 구현하지 못하는 단점을 가지고 있다. 따라서 본 연구에서는 하천저장대모형(River Storage Model; RSM)을 개발하고 이를 국가하천인 감천에 적용하였다. 본 연구에서 개발한 RSM은 분산계수, 본류대 면적, 저장대 면적, 저장대 교환계수의 네 가지 매개변수를 통해서 하천의 물질 저장 및 교환 특성를 구현한 non-Fickian 모형으로서, 생화학반응, 휘발, 흡·탈착항을 추가하여 유해화학물질의 혼합 거동을 정확하게 모의할 수 있도록 개발하였다. 저장대 모형의 매개변수를 산정하기 위해서 하천 유량과 지형자료를 기반으로 HEC-RAS를 모의하여 계산된 수리특성을 입력변수로 사용하였다. 저수기, 평수기, 풍수기 유량을 기준으로 세 경우의 시나리오 모의를 수행하였는데, 5ton의 톨루엔이 김천산업단지에서 감천으로 유입된 경우 약 20km 하류에 위치한 취수장에서 톨루엔의 농도변화를 예측했다. 보존성 물질에 대한 모의 결과, 풍수기의 경우 저수기에 비해 유속이 크기 때문에 취수장에서 20.56시간 먼저 기준농도에 도달하고, 7.21시간 더 짧게 머무는 것으로 나타났다. 유해화학물질의 반응특성에 대한 민감도 분석을 시행한 결과, 생화학적 반감기가 18.98시간보다 길고, 옥탄올-물 분배계수가 2.267 이하인 물질은 생분해 및 흡·탈착 반응에 둔감한 것으로 나타났다. 1m 수심 기준 0.114m/s 이하 유속에서의 하천 수리조건에서는 화학물질의 휘발성을 무시할 수 있는 것으로 밝혀졌다.

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Impacts of Combined Hydrogeological and Chemical Heterogeneities on the Transport of Leachate through Landfill Sites (수리지질학적, 화학적 특성의 복합 불균질성이 매립지반 내 침출수 이동에 미치는 영향)

  • Lee, Kun-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.4
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    • pp.300-307
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    • 2009
  • The transport of landfill leachate in the subsurface formations of unlined landfill sites is considered. The impacts of hydrogeological and chemical heterogeneities on the leachate transport are assessed by examining the results from a series of Monte-Carlo simulations. The landfill system simulated in this study is hypothetically represented with three levels of spatial variability for the hydrogeological and chemical parameter; (1) homogeneous hydraulic conductivity (K) and distribution coefficient ($K_d$), (2) K heterogeneity only, and (3) combined heterogeneities of K and $K_d$. To calculate the transport of leachate through negatively-correlated random hypothetical K-$K_d$ fields generated using geostatistical input parameters, a saturated flow model is linked with a contaminant transport model. Point statistic values such as mean, standard deviation, and coefficient of variation of the concentration were obtained from 100 Monte-Carlo trials. Results of point statistics show that the heterogeneities of K and $K_d$ in the landfill site prove to be an important parameter in controlling leachate concentrations. Consideration of combined K and $K_d$ heterogeneities results in enhancing the variability of contaminant transport. The variability in the leachate concentration for different realizations also increases as the distance between source and monitoring well increase.

Hydrogeologic and Hydrogeochemical Assessment of Water Sources in Gwanin Water Intake Plant, Pocheon (포천 관인취수장 수원에 대한 수리지질 및 수리지구화학적 평가)

  • Shin, Bok Su;Koh, Dong-Chan;Chang, Yoon-Young
    • Journal of Environmental Impact Assessment
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    • v.25 no.3
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    • pp.209-221
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    • 2016
  • The section from water source to 2.6km upper stream of Hantan River is protected as the drinking water quality protection area according to guidelines of Ministry of Environment, because water source of the Gwanin water intake plant has been known the river. However, opinions were consistently brought up that the standard of water source protection zone must be changed with using underground water as water source because of contribution possibility of underground water as the water source of Gwanin water intake facility. In this regard, hydrogeologic investigation including resistivity survey and hydrogeochemical investigation were carried out to assess water source and infiltration of contaminant for the plant. Quaternary basaltic rocks (50m thick with four layers) covered most of the study area on the granite basement. As the result of the resistivity survey, it is revealed that permeable aquifer is distributed in the boundary of two layers: the basaltic layer with low resistivity; and the granite with high resistivity. Considering of outflow from Gwanin water intake facility, the area possessing underground water was estimated at least $5.7km^2$. The underground water recharged from Cheorwon plain was presumed to outflow along the surface of unconformity plane of basalt and granite. Based on field parameters and major dissolved constituents, groundwater and river water clearly distinguished and the spring water was similar to groundwater from the basaltic aquifer. Temporal variation of $SiO_2$, Mg, $NO_3$, and $SO_4$ concentrations indicated that spring water and nearby groundwater were originated from the basaltic aquifer and other groundwater from granitic aquifer. In conclusion, the spring of the Gwanin water intake plant was distinguished from river water in terms of hydrogeochemical characteristics and mainly contributed from the basaltic aquifer.

Numerical Identification of a Strain Producing Novel Aminopeptidase M Inhibitors MR-387A and B (신규의 Aminopeptidase M 저해제 MR-387A 및 B 생산균주의 수리동정)

  • Chung, Myung-Chul;Park, Dong-Jin;Kim, Chang-Jin;Kim, Su-Il;Kho, Yung-Hee
    • Applied Biological Chemistry
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    • v.38 no.3
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    • pp.196-201
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    • 1995
  • Chemo- and numerical taxonomic studies on the isolate SL-387 producing novel aminopeptidase M inhibitors MR-387A and B were carried out The genus of the isolate was determined as Streptomyces by cultural and morphological data and chemical indices. Forty one taxonomic unit characters were tested for determining the species of the isolate, and the data were analyzed numerically using a computer program as called TAXON. The isolate was best matched to Streptomyces neyagawaensis in the major cluster 18 of Streptomyces with $S_{SM}$ value of 75.67%. On the base of chemotaxonomic data and TAXON analysis, the isolate SL-387 was identified to be a member of Streptomyces neyagawaensis.

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