• Title/Summary/Keyword: 속도 상호스펙트럼

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The Effect of Pressure on the $S_F2$ Cleavage Reaction of Tetramethyltin with Iodine (Tetramethyltin과 Iodine의 $S_F2$ 분해반응에 대한 압력의 영향)

  • Oh Cheun Kwun;Jin Burm Kyong;Young Hoon Lee
    • Journal of the Korean Chemical Society
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    • v.37 no.3
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    • pp.287-293
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    • 1993
  • Ultraviolet spectrophotometric investigation has been carried out on the system of charge-transfer(CT) complex with iodine and tetramethyltin in n-hexane and acetone. From these results, the transient CT absorption spectrum can be observed and the subsequent disappearance of CT absorption spectrum is accompained by the cleavage of tetramethyltin with iodine (iododestannylation). Therefore, the rate constants for the iododestannylation were determined at 10, 25 and 35$^{\circ}C$ up to 1600 bar and the rates of reaction were increased with increasing temperature and pressure. From these rate constants, the values of the activation parameters (${\Delta}V^{\neq}$, ${\Delta}{\beta}^{\neq}$, ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$) were obtained and discussed in terms of solvent structure variation of transition state and mechanism from these values. It could postulated that the reaction is followed with S$_F$2 mechanism and weakened S$_F$2 mechanism nature by increasing pressure.

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Measurements of Ultrasonic Velocity and Attenuation by Signal Processing Techniques in Time and Frequency Domains (시간 및 주파수 영역에서의 신호 처리 기술에 의한 초음파 속도와 감쇠의 측정)

  • Jang, Young-Su;Kim, Jin-Ho;Jeong, Hyun-Jo;Nam, Young-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.19 no.2
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    • pp.118-128
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    • 1999
  • There are many ultrasonic measurement methods that are used in nondestructive testing applications. Some typical applications include material property determination, microstructural characterization. and flaw detection. Ultrasonic parameters such as velocity and attenuation are most commonly required in these applications. The accuracy and repeatability of testing results are dependent on both the hardware used to generate and receive the ultrasonic waves and on the analysis software for calculating these parameters. In this study, five analysis algorithms were implemented on a computer for measuring wave speed in a pulse echo. immersion testing configuration. In velocity measurements comparisons were made between the overlap. cross-correlation. Fourier transform. Hilbert transform, wavelet transform algorithms. Velocity measurement was applied to an isotropic steel sample using the five analysis algorithms. Frequency-dependent phase/group velocity and attenuation were also measured using the Fourier transform and wavelet transform algorithms on a composite laminate containing voids.

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The Quantification and Validation of Loxoprofen using Near-infrared(NIR) Spectrum Method (근적외부스펙트럼 측정법을 이용한 록소프로펜의 정량화 및 밸리데이션)

  • Choi, Sung-Up
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.1
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    • pp.396-401
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    • 2014
  • In this study, we used NIR spectrum method instead of conventional HPLC method to shorten the analysis and manufacturing time of the loxoprofen products. Loxoprofen mixtures with other pharmaceutical additives were prepared and evaluated by the NIR spectrometer and the HPLC system. Validation of both methods was performed for specificity, accuracy and precision. NIR spectrometer method was validated and revealed proper results for the in-process quality control in the pharmaceutical field. In conclusion, NIR spectrometry can be replaced by HPLC method.

Derivation of a Monte Carlo Estimator for Dose Equivalent (몬테칼로법을 위한 선량당량 산정법의 도출)

  • Lee, Jai-Ki
    • Journal of Radiation Protection and Research
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    • v.10 no.2
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    • pp.89-95
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    • 1985
  • An alternative estimator for dose equivalent was derived. The original LET distribution concept was transformed into a charged particle fluence spectrum concept along with the definition of an average quality factor named slowing-down averaged quality factor by adopting the continuous slowing down approximation. With the alternative estimator, the dose equivalent delivered into a receptor located in a given radiation field can be directly and conveniently estimated in a Monte Carlo procedure. The slowing-down averaged quality factors for the energy range below 10 MeV were evaluated and tabulated for the charged particles which may be generated from the interactions of neutron with the nuclei composing soft tissue.

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한일공동VLBI상관기의 지연 보상 및 프린지 멈춤 알고리즘

  • No, Deok-Gyu;O, Se-Jin;Yeom, Jae-Hwan;Park, Seon-Yeop;Gang, Yong-U
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.45.1-45.1
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    • 2010
  • 한국천문연구원과 일본 국립천문대는 공동으로 한일공동VLBI상관기(Korea-Japan VLBI Correlator, KJJVC)를 개발하였다. 이 상관기는 최대 16 관측국에 대하여 16 세트의 자기상관 및 120 세트의 상호상관을 계산할 수 있다. 각 관측국당 최대 8,192 Mbits/sec의 입력 데이터를 처리할 수 있으며, 8,192개의 주파수채널을 갖는 상관 스펙트럼을 약 25.4 밀리초~수초의 적분 시간으로 출력할 수 있는데, 최대 상관 출력 속도는 1.4GB/sec이다. 한편, 이 상관기는 한국우주전파관측망(KVN) 뿐만 아니라 동아시아VLBI관측망 및 우주공간VLBI관측망의 관측 데이터도 처리할 수 있도록 설계 제작되었으며, 최대 지연 추적 범위는 ${\pm}35,000km$이며, 보상 가능한 최대 기선 속도는 7.5km/sec이다. 현재 다른 VLBI관측망에서 사용하고 있는 타 상관기의 경우 지연은 2차 미분까지 보상하고, 프린지 위상은 3 단계로 보상하고 있는 것에 비하여, 한일공동VLBI상관기에서는 지연은 3차 미분까지 보상하여 지연 잔차를 최소화하고 프린지 위상은 16 단계로 세분하여 보상 수준의 정밀도를 최대화하였다. 이러한 지연 보상 및 프린지 멈춤 알고리즘을 상세히 소개하고 그 특성 및 장점을 보고한다.

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Linear estimation of conditional eddies in turbulence (난류구조의 조건와류에 대한 선형적 평가)

  • 성형진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.5
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    • pp.1175-1188
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    • 1988
  • Linear estimation in isotropic turbulence is examined to approximate conditional averages in the form of fluctuating velocity fields conditioned on local velocity. The conditional flow fields and their associated vorticity field are computer using experimental data [Van Atta and Chen] and energy spectrum model [Driscoll and Kennedy]. It appears that ring vorticies could be the dominant structure. Due to the extremely large vorticity in the viscous region of a conditional ring vortex, the energy spectrum model can be used appropriately by changing the Reynolds number. The hairpin vortex could be detected by combining vorticies in isotropic field with an anisotropic orientation imbedded in uniform mean shear flow and this is consistent with other studies [Kim and Moin].

A Analysis on the Estimation Method of the 3D Underwater Radiation Noise Pattern of Cylindrical Structure with the Underwater Experiments (수중실험을 통한 원통구조물의 3차원 수중방사소음 패턴 산출기법 분석)

  • Yi, Jongju;Kang, Myunghwan;Han, Seungjin;Jeong, Hyunjoo;Oh, Junseok;Bae, Sooryong;Jung, Woojin;Seo, Young Soo
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.24 no.11
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    • pp.907-918
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    • 2014
  • In this study for the prediction of 3D underwater radiated noise pattern, a comparison between the proposed method(DHIE, Discrete Helmholtz Integral Equation) and the 3D underwater radiated noise calculation results using the measurement of near-field acoustic pressure data is performed. The near-field acoustic pressure in water is measured for the calculation of the far-field radiated noise pattern and the far-field acoustic power. Also the vibration field of the underwater structure is measured in simultaneously. Using the total far-field acoustic power and the vibration field on the surface of the structure, the proposed method(DHIE) can predict the underwater radiated noise pattern of the far-field The predicted results show the reasonable agreement within about 5dB comparing with the experiment result.

Cognitive-Motor Interaction-Based Instrument Playing for Improving Early Social Skills of Children With Autism Spectrum Disorder (ASD 아동의 초기 사회기술 향상을 위한 인지-운동 통합 기반 악기연주 중재)

  • Yu, Hyun Kyung
    • Journal of Music and Human Behavior
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    • v.20 no.1
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    • pp.75-97
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    • 2023
  • This study aimed to investigate the effect of cognitive-motor interaction-based instrument playing on the early social skills of children with autism spectrum disorder (ASD). Nine children with ASD, averaging 5.6 years of age, participated in twelve individual sessions lasting 30 minutes each. The intervention comprised five stages: self-regulation, motivation to engage in social interaction, acceptance of a partner in co-playing activities, interpersonal coordination with a partner, and engagement in joint music playing. To evaluate changes in early social skills, joint attention and social interaction behaviors were observed, and the Social Responsiveness Scale (SRS-2) was administered pre- and post-intervention. Social synchronization was measured through a dyadic drum task, measuring synchronization accuracy, duration, and timing. Following the intervention, all nine children demonstrated increased early social behaviors, although there were no significant differences in SRS scores. Moreover, synchronized movement improved significantly in accuracy and maintained duration but not in reaction time. This study highlights the significance of recognizing the cognitive-motor interplay as crucial element in facilitating early social skills development in children with ASD.

The Effect of Pressure on the Iododestannylation between Tetramethyltin and Iodine (Tetramethyltin과 Iodine 사이의 Iododestannylation에 대한 압력의 영향)

  • Kwun, Oh Cheun;Lee, Young Hoon;Jeun, In Seung
    • Journal of the Korean Chemical Society
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    • v.39 no.5
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    • pp.350-355
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    • 1995
  • UV spectrophotometric investigation has been carried out on the system of charge-transfer (CT) complex with iodine and tetramethyltin in carbon tetrachloride solvent. The transient CT absorption spectrum can be observed in ${\lambda}_{max}=270nm$ and the subsequent disappearance of CT absorption spectrum was accompained by the cleavage of tetramethyltin with iodine (iododestannylation). From there, the rate constants for the iododestannylation were determined at 10, 20 and $35^{\circ}C$ up to 1200 bar and the reaction rates were increased with increasing temperature and pressure. From these rate constants, the values of the activation parameters (${\Delta}V^{\neq},\;{\Delta}{\beta}^{\neq},\;{\Delta}H^{\neq}\;and\;{\Delta}S^{\neq}$) were obtained and from these values discussed in terms of solvent structure variation of transition state and mechanism. From these results, it was found that the reaction is followed with $S_F2$ mechanism and weakened $S_F2$ mechanism nature by increasing pressure.

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Trend Analysis of Affective Computing Technology for Diagnosis and Therapy of Autistic Spectrum Disorder (자폐스펙트럼장애 진단 및 치료를 위한 감성 컴퓨팅 기술 동향 분석)

  • Yoon, Hyun-Joong;Chung, Seong-Youb
    • Science of Emotion and Sensibility
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    • v.13 no.3
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    • pp.429-440
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    • 2010
  • It is known that as many as 1 in 91 children are diagnosed with an autistic spectrum disorder, and the incidence rate of the autistic spectrum disorder is much higher than that of cancer in Korea. It is necessary to develop a novel technology to sense their emotional status and give proper psychological diagnosis and therapy, since the children with autistic spectrum disorder usually do not express their own emotional status. This article presents the state-of-the-arts on the affective computing technologies that include recognition of emotional status through bio-sensing and virtual affective agent modeling, and then proposes a novel system architecture for diagnosis and therapy of autistic spectrum disorder. The diagnosis and therapy system of autistic spectrum disorder is composed of bio-sensing module, virtual environment module with affective agents, and haptic interface module. The architecture proposed in this paper will enhance the objectivity to diagnose autism spectrum disorders, and enable continuous treatment in daily life.

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