• Title/Summary/Keyword: 소진조건

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Stripping Voltammetric Determination of Osmium (벗김 전압전류법에 의한 오스뮴 정량)

  • Kwon, Young-Soon;Kim, So-Jin;Czae, Myung-Zoon
    • Analytical Science and Technology
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    • v.10 no.2
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    • pp.114-118
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    • 1997
  • A stripping voltammetric scheme for the determination of osmium, based on the adsorptive accumulation of osmium in the presence of hydroxylamine, was described. Cyclic voltammetry was used to characterize the redox and interfacial processes. Optimal experimental conditions were found to be a stirred 0.05M hydroxylamine hydrochloride solution(pH 1.8), accumulation at -0.65V for 60s, and a differential pulse mode with a scan rate of 10mV/s. The detection limit was $6.3{\times}10^{-8}M$(12ppb) with the optimal condition.

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Adsorptive Catalytic Wave of Chromium-Cupferron Complex (크롬-쿠페론 착물의 흡착 촉매파)

  • Kwon, Young-Soon;Seo, Soh-Jin;Lee, Sang-Mi
    • Analytical Science and Technology
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    • v.15 no.3
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    • pp.214-220
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    • 2002
  • The interfacial accumulation of the chromium-cupferron complex and the catalytic wave of its redox process is characterized by cyclic voltammetry. One cathodic peak is observed in the forward scan at -1.45 V. Scanning in the reverse direction produces a inverted peak at -1.39 V, which is indicative of a catalytic process. The optimal conditions of inverted peak were found to be 1 mM borate buffer solution(pH 9.48) containing $1{\times}10^{-4}M$ cupferron, holding potential of -1.8 V and scan rate of 20 mV/s. Using main peak, a preconcentration time of 1 min results in a detection limit of $3.2{\times}10^{-10}M$.

Numerical Simulation of High-Velocity Oblique Impact of Mild Steel Spheres Against Mild Steel Plates (연강 판재에 대한 연강 구의 고속경사충돌 수치해석)

  • Yu, Yo-Han;Jang, Sun-Nam;Jeong, Dong-Taek
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.3
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    • pp.576-585
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    • 2002
  • A three-dimensional Lagrangian explicit time-integration finite element code for analyzing the dynamic impact phenomena was developed. It uses four node tetrahedral elements. In order to consider the effects of strain rate hardening, strain hardening and thermal softening, which are frequently observed in high-velocity deformation phenomena, Johnson-Cook model is used as constitutive model. For more accurate and robust contact force computation, the defense node contact algorithm was adopted and implemented. In order to evaluate the performance of the newly developed three-dimensional hydrocode NET3D, numerical simulations of the oblique impact of mild steel plate by mild steel sphere were carried out. Ballistic limit about various oblique angle between 0 degree and 80 degree was estimated through a series of simulations with different initial velocities of sphere. Element eroding by equivalent plastic strain was applied to mild steel spheres and targets. Ballistic limits and fracture characteristics obtained from simulation were compared with experimental results conducted by Finnegan et al. From numerical studies, the following conclusions were reached. (1) Simulations could successfully reproduce the key features observed in experiment such as tensile failure termed "disking"at normal impacts and outwards bending of partially formed plus segments termed "hinge-mode"at oblique impacts. (2) Simulation results fur 60 degrees oblique impact at 0.70 km/s and 0.91 km/s were compared with experimental results and Eulerian hydrocode CTH simulation results. The Lagrangian code NET3D is superior to Eulerian code CTH in the computational accuracy. Agreement with the experimentally obtained final deformed cross-sections of the projectile is excellent. (3) Agreement with the experimental ballistic limit data, particularly at the high-obliquity impacts, is reasonably good. (4) The simulation result is not very sensitive to eroding condition but slightly influenced by friction coefficient.

Modeling of Gasifier with PRO/II (PRO/II를 사용한 가스화기 모델링)

  • Kim, KwangSin;Joo, Yong-Jin;Kim, Mi Yeong;Kim, Si-Moon;Lee, Joongwon;Kim, Ki-Tae
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.131.2-131.2
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    • 2010
  • 서부 발전 태안화력발전소에 건설 예정인 IGCC Demo plant의 설계 자료를 근거로 석탄 가스화기의 정상 상태 전산모사를 PRO/II를 사용하여 수행하였다. 석탄을 PRO/II가 받아들일 수 있는 성분으로 바꾼 후 가스화기를 버너와 가스화기 본체의 두 부분으로 나누어 모델링하였다. 버너는 단열조건의 Gibbs Reactor로 모델링하였다. 모사 결과 산소가 완전 소진될 때까지 반응이 진행되는 것을 확인하였다. 가스화기는 char gasification 반응은 kinetic reaction equation으로, gas phase reaction은 equilibrium reactor로 모사하는 알고리듬을 개발 하였으나 PRO/II의 기능에 한계가 있어 간단한 Gibbs Reactor로 모사하였다. 가스화기는 membrane wall에 의하여 냉각되는 것을 고려하여 $1550^{\circ}C$의 균일한 온도에서 반응이 일어나는 것으로 고려하였다. 전산 모사 결과 주요 성분의 조성이 실제 syngas의 조성과 5% 정도 오차가 있는 것으로 나타났다.

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Optimal Growth Condition of Pleurotus ostreatus Cultured in the Foodwastes Extracts (음식폐기물 추출물을 이용한 느타리버섯균의 최적성장조건)

  • Lim, Joung-Soo;Lee, So-Jin;Lee, Eun-Young
    • Microbiology and Biotechnology Letters
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    • v.37 no.1
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    • pp.85-89
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    • 2009
  • For the purpose of the methodological development to convert the food wastes into resources, we have attempted to culture the mushroom hypha, Pleurotus ostreatus. The food-wastes were mixed with distilled water, and the mixture was autoclaved to produce fluid, which was centrifugated and used as the growth media. Concentrations of the food wastes extracts were prepared with 10, 20, 30, 40, and 50%(W/V), and the initial pH were set variously with 4, 5, 6, and 7. These were cultured for 9 days at the temperature of $25^{\circ}C$ and the rotation rate of 120 rpm. The result is that the fluid form of the mushroom hypha have been grown best at the concentration of 30% and the optimal pH was 5 and 6.

Effects of Annealing on the Microstructure and Electrical Properties of ZnO Varistor (ZnO 바리스터 제조시 소결후 열처리 조건에 따른 미세구조 및 전기적 특성에 관한 연구)

  • Soh, J.J.;Han, S.W.;Kim, H.S.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1679-1681
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    • 1996
  • ZnO varistor with composition of 89wt%-ZnO, 3.0wt%-$Bi_{2}O_{3}$, 3.6wt%-$Sb_{2}O_{3}$, 1.16wt%-CoO, 0.88wt%-NiO, 0.71wt%-$MnO_2$, 0.93wt%-$Cr_{2}O_{3}$, 0.013wt%-$Al_{2}O_{3}$ was fabricated by sintering methods. The effects of annealing on the J-E characteristics of ZnO varistors were investigated. These changes of electric properties were found to be caused by the variation of grains and grain boundary related to annealing. And the conductive mechanism and micostructure of ZnO varistor were researched using I-V meter, SEM and XRD.

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Development of Current transformer by APG process (APG(Automatic Pressure Gelation)의 주형방식에 따른 변류기 제조에 대한 기술)

  • Soh, Jin-Joong;Kim, Pyung-Joong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.240-241
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    • 2006
  • 변류기의 제조공법에는 conventional 방식이 있다. Conventional 방식은 부분적으로 불규칙한 경화에 의한 굴곡형태, 단기간에 금형의 손상이 많이 가고, 제한된 생산량으로 금형이 많아야하고 또한 금형의 예열이 필요한 단점을 가지고 있다. 이를 개선한 APG(Automatic Pressure Gelation) 주형방식은 제품의 외관을 매끄럽게 하고, 자동화에 따른 금형수명을 연장하고, 1일 생산량이 conventional 방식보다 8배나 많고 제품의 후경화 설비만 필요한 장점이 있다. 생산성 향상 및 제조원가 절감을 위하여 새로운 제조공법인 APG 방식의 제조공법에 맞는 원재료 및 작업조건을 표준화하고 한국전기연구원이 보유하고 있는 고가장비인 내후성시험기, 성분분석시험기, 충격시험기, 단락시험설비 등을 이용하여 시제품에 대한 평가 시험을 하여 제품의 품질을 향상하고 안정성을 확보함으로써 국내 기업의 기술 경쟁력을 향상하고자 하였다.

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The Concept and Role of Truth as Inflationary Property (실체적 속성으로서의 진리의 개념과 역할)

  • Kim, Dong-Hyun
    • Korean Journal of Logic
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    • v.15 no.1
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    • pp.53-85
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    • 2012
  • There are various views in the boundary of deflationism of truth in regarding the nature and role of truth. This paper surveys the issue on how the core thesis uniting the deflationism is characterized. First, I will examine some comments on what is the central thesis supported or rejected by the deflationists and inflationists, mainly discussing Armour-Garb and Beall's work, and will show on which aspects they are unsatisfying. From this, I will suggest these statements: first, the central cores of deflationism are conceptual fundamentality and explanatory exhausting. Second, the particularity thesis, understood in an alternative way, cannot be a central claim of deflationism. Third, another important claim from deflationists, the expression thesis, can be derived from the two main thesis above. But it is still not clear enough what the non-expressive explanatory role of truth, which is denied by the expression thesis. So I will check some possible clarifications on it and discuss why they should be rejected. And I will introduce Dummett's view on the role of truth condition in truth conditional explanation of meaning, and I will claim that if Dummett is right why the role must be a inflated one. Finally, I will suggest a further implication that the understanding on the both sides can be widened by connecting considerations on both views.

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Effect of Temperature and pH on the Biosorption of Heavy Metals by Exophiala sp. (Exophiala sp.의 중금속 흡착에 미치는 온도 및 pH의 영향)

  • Lim, Joung-Soo;Lee, So-Jin;Lee, Eun-Young
    • Microbiology and Biotechnology Letters
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    • v.36 no.2
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    • pp.165-172
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    • 2008
  • To find the optimum growth and metal removal condition of isolated strain LH2, effects of the environmental factors such as medium pH, growth temperature, and metal concentrations were investigated. Based on the 18S rDNA analysis, the isolated strain was identified to Exophiala sp. with 100% homology. Isolated strain Exophiala sp. LH2 showed maximum removal efficiency of metals at the shaking conditions of pH 7 and $25^{\circ}C$. When the concentration of metal was under 200ppm, the specific metal removal velocity at pH 7 increased from 0.01 to 4.43 mg-metal $L^{-1}{\cdot}d^{-1}{\cdot}mg{\cdot}DCW^{-1}$ as the concentration of metal increased from 10 ppm to 200 ppm. When 200 ppm of each metal was contained in the culture medium adjusted with pH 7, metal removal efficiencies Cr, Cu, Ni, Pb and Zn were 99.28%, 97.67%, 91.94%, 99.77%, 99.61%, respectively.

One-Time Password Authentication Scheme Based on Cryptographic Hash Chain without Re-Registration (재등록이 필요 없는 암호 해시체인 기반의 일회용 패스워드 인증기법)

  • Shin, Dong-jin;Park, Chang-seop
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.27 no.6
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    • pp.1251-1259
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    • 2017
  • One-time password has been proposed for the purpose of addressing the security problems of the simple password system: fixed passwords and pre-shared passwords. Since it employs the consecutive hash values after a root hash value is registered at the server, the security weakness of the fixed passwords has been addressed. However, it has a shortcoming of re-registering a new root hash value when the previous hash chain's hash values are exhausted. Even though several one-time password systems not requiring re-registration have been proposed, they all have several problems in terms of constraint conditions and efficiency. In this paper, we propose the one - time password scheme based on a hash chain that generates one - time passwords using only two cryptographic hash functions at each authentication and satisfies the existing constraints without re-registration, Security requirements and efficiency.