• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.1
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• pp.29-37
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• 2018

In this study, optimum extraction conditions for phosphorus recovery from sewage sludge ash(SSA) were investigated. For this purpose, an experiment was conducted to determine optimal recovery conditions for Ca-P type phosphorus by using calcium component in the recycled aggregate residue. The phosphorus content of sewage sludge ash was confirmed to be 5.0 %. When $H_2SO_4$ was used as an extract, concentration of 1 N $H_2SO_4$, L/S ratio of 10, and extraction time of 30 min were found to be the optimal extraction conditions. Phosphorus was extracted by using optimal extraction conditions, and then the heavy metals eluted with phosphorus were removed using 1~20 g of cation exchange resin. In 20 g of cation exchange resin, Fe 71.3%, Cu 82.4%, Zn 79.9%, and Cr 15% were removed. After that, the mixing ratio of the calcium extract obtained from the recycled aggregate residue (RAR) was changed to 1:1, 1:5, 1:10. The pH of the SSA to RAR mixture was adjusted to 2, 4, 8 and 12 by the addition of 5 N NaOH to the mixture of 1:5, and the phosphorus was recovered as Ca-P type precipitate. The optimum pH was 8. When recycled aggregate residues were used, the weight of calcium phosphate increased, but the amount of wastewater generated also increased. Therefore, it was concluded that the use of recycled aggregate residue was not economically feasible.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.6
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• pp.659-665
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• 2008

This study is about zeolite synthesis from the sewage sludge incinerator fly ash of "S" sewage treatment center located in Seoul. For this purpose, the properties of raw fly ash as starting material, the hydrothermal conditions for zeolite synthesis and the environmental applicabilities of synthesized zeolites were examined. Fly ash from sewage sludge incinerator has large quantities of SiO$_2$ and Al$_2$O$_3$ and their contents are 42.8 wt.% and 21.2 wt.% respectively. So fly ash is considered to be possible starting material for zeolite synthesis. The results from leaching test of fly ash showed that the concentration of hazardous metals were very low as compared with the Korea leaching standard of the Waste Management Law. But the concentration from total recoverable test of fly ash were higher than the fertilizer standard of Fertilizer Management Law. Major zeolite products synthesized by hydrothermal reaction are analcime in teflon vessel and zeolite P1 in borosilicate flask. Optimum conditions for the synthesis of analcime were 1 N of NaOH concentration, 16 hour of reaction time and 135$^{\circ}C$ of reaction temperature. For the zeolite P1 formation, the proper conditions were demonstrated to be 5 N of NaOH concentration, 16 hour reaction time and 130$^{\circ}C$ of reaction temperature in this study. Hazardous metal contents in the analcime product are similar with those in raw fly ash. In case of the zeolite P1, the contents are reduced to nearly a half. Raw fly ash and the analcime product showed NH$_4{^+}$ ion exchange capacity of 0$\sim$1.0 mg of NH$_4{^+}$g$^{-1}$ and 3.0$\sim$7.4 mg of NH$_4{^+}$g$^{-1}$, respectively. However, the zeolite P1 product reached exchange capacity to 14.6$\sim$17.8 mg of NH$_4{^+}$g$^{-1}$. This values are in the range of those of natural clinoptilolite and phillipsite. From this point of view, zeolite synthesis from sewage treatment sludge incinerator fly ash is a good alternative for solid waste recycling.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.2
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• pp.114-118
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• 2009

With the advance of industrialization and urbanization, a lot of waste has been discharged and treated by incineration. But fly and bottom ashes are generated in this process. In addition, the treatment method to recycle sewage sludge and melting slag is required to manage these wastes. The objective of this research was to prepare of multi-functional brick which were made from MSWI (Municipal solid wastes incinerator) fly ash, sewage sludge and slag. The bricks were made by mixing raw materials and then drying for 24 hours. Next, they were dried for 24 hours at $160^{\circ}C$ and fired for 2 hours. Calcination temperature was changed to discuss the effect of temperature from $1,080^{\circ}C$ to $1,130^{\circ}C$. Compressive strength of a brick was creased with the increase of temperature. To increase mixing ratio of fly ash and slag reduce the compressive strength the optimal condition was the mixing ratio of fly ash : melting slag : sewage sludge : clay as 10 : 20 : 5 : 65 and $1,150^{\circ}C$ of calcination temperature. Compressive strength was obtained as about 41 MPa at this condition.

• Journal of the Korean Chemical Society
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• v.54 no.1
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• pp.115-119
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• 2010

Neutral red5 (BR 5) adsorption from aqueous solution was investigated. New solid adsorbent was prepared from paper sludge incinerated at $250^{\circ}C$ during 2 hours. Experiments were carried out, in batch system, to remove RB5 dye from the synthetic waste water. Maximum adsorption of 374.98 mg/g at pH 5, at room temperature and contact time of 80 min was obtained. The Langmuir and Freundlich adsorption models were applied to interpret the equilibrium isotherm. The Freundlich isotherm fits quite well with the experimental data (with highly regression coefficient $R^2$). The incinerated sludge solid samples untreated and treated with BR5 dye were characterized by FT-IR spectrophotometer.

• Journal of the Korean Ceramic Society
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• v.41 no.4
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• pp.323-327
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• 2004

This study has been carried out to use the municipal solid waste sewage sludge ash generated at sewage disposal field as the raw materials of Ordinary Portland Cement (OPC). Limestone, shale, converter slag, and fly ash were used as the main raw materials. After the raw materials were mixed, these were fired at 1,300, 1,350, 1,400, 1,450, and 1,500$^{\circ}C$ for 1 h and cooled rapidly in air. The properties of clinker synthesized were examined with XRD, SEM, and burnability index by polysius method.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2017.10a
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• pp.68-68
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• 2017

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2001.05a
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• pp.397-400
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• 2001

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2001.05a
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• pp.183-186
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• 2001

• Resources Recycling
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• v.17 no.4
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• pp.30-36
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• 2008

The preparation of porous lightweight materials as well as the measurement of physical properties has been performed by using SSA(sewage sludge ash) as the raw material. For this aim, two types of lightweight filler, that is, perlite and silica sphere were employed respectively and bentonite was also used as an inorganic binder. The properties of lightweight specimen calcined at 1,000 were measured in terms of density, compressive strength, thermal conductivity and sound absorption to examine the effect of material composition as well as the preparation condition on the properties of lightweight material. As a result, the density of specimen prepared with perlite was ranged from 1.23 to $1.37g/cm^3$ and the compressive strength was ranged from 242.3 to $370.5kg/cm^2$. In case of specimen prepared with silica sphere, it was found that the compressive strength was less than $100kg/cm^2$ even though density was lower than that of specimen with perlite. As far as the thermal conductivity of specimen was concerned, it was ranged from 0.3 to $0.5W/m^{\circ}K$ depending on material composition so that the insulation effect was superior to conventional concrete.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11b
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• pp.310-311
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• 2003

본 연구에서는 폐수산자원인 불가사리와 조개껍질 분말을 이용한 탈수보조제(물리개량제)의 가능성을 확인하였다. 불가사리와 조개껍질을 이용한 탈수보조제는 유가자원 소모라는 기존의 탈수보조제의 문제점을 보완하여 폐자원의 자원화라는 이점이 있으며 탈수케이크의 함수율을 효과적으로 낮추어 주어 소각등의 후속공정에 도움을 줄 수 있는 것으로 사료된다. 뿐만아니라 천연 비료로 사용되어지는 불가사리의 활용이라는 점에서 탈수슬러지 퇴비화등 자원 재이용에의 적용성 또한 증대시킬 수 있다.