• Title/Summary/Keyword: 생체흡착

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Biosorption of $Pb^{2+}$ and $Cr^{3+}$ by using Sargassum hornei (Sargassum horneri를 이용한 $Pb^{2+}$$Cr^{3+}$ 생체흡착)

  • 서근학;안갑환;조문철
    • Journal of Environmental Science International
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    • v.8 no.3
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    • pp.387-391
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    • 1999
  • $Pb^{2+}$ and $Cr^{3+}$ uptake capacity by Sargassum horneri was 185.5 mg $Pb^{2+}$/g biomass and 102.6 mg $Cr^{3+}$/g biomass, respectively. An adsorption equilibria were reached within about 0.5 hr for $Pb^{2+}$ and 1 hr for $Cr^{3+}$. The adsorption parameters for $Pb^{2+}$ and $Cr^{3+}$ were determined according to Langmuir and Freundlich model. With an increase in pH values of 2 to 5, $Pb^{2+}$ uptake was increased, however $Cr^{3+}$ uptake jwas constant. The selectivity of mixture solution showed the uptake order of $Pb^{2+}$>$Cu^{2+}$>$Cr^{3+}$>$Cd^{2+}$. $Pb^{2+}$ and $Cr^{3+}$ adsorbed by S. horneri could be recovered from 0.1M HCl, 0.1M ${HNO}_3$ and 0.1M EDTA by desorption process, and the efficiency of $Pb^{2+}$ desorption was above 98%, whereas the efficiency of $Cr^{3+}$ desorption was below 34%.

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Socket Pressure Distribution of the Uni-Lateral Trans-Femoral Amputee with a Suction Socket (흡착식 소켓을 착용한 일측 대퇴절단환자의 소켓내부압력분포)

  • Jang, Yun-Hui;Yang, Gil-Tae;Im, Song-Hak;Mun, Mu-Seong;Kim, Yeong-Ho
    • Journal of Biomedical Engineering Research
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    • v.19 no.4
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    • pp.417-422
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    • 1998
  • The study was explored socket pressure distributions on a trans-femoral amputee with a suction socket in static and dynamic situations. Even when the amputee stood in the anatomically neutral position, significant pressure concentrations were observed in the lateral, medial, and posterior planes of the socket. During free level walking, a significant shifting pattern of pressure concentration areas was observed. High socket pressure was observed in the lateral, medial-anterior and posterior walls during mid-stance or push-off period. Socket pressure measurement will be one of the good tool to determine the optimal socket-limb interface.

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Study on protein adsorption resistant soft contact lens (단백질흡착을 막는 소프트콘택트렌즈에 관한 연구)

  • Jeong, Young-Il;Cho, Chong-Su;Na, Jae-Woon;Kim, Sung-Ho
    • Proceedings of the KOSOMBE Conference
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    • v.1996 no.05
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    • pp.223-225
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    • 1996
  • Poly (ethylene glycol) (PEG)macromers terminated with acrylate groups and interpenetrating polymer networks(IPN) composed of poly(hydroxyethyl methacrylate)(PHEMA) or poly(hydroxyethyl methacrylate-co-hydropropyl methacrylate-co-N-vinyl pyrrolidone) [P(HEMA-co-HPMA-co-NVP)] and PEG macromer were synthesized with the aim of obtaining protein adsorption resisatnt soft contact lens. Polymerization of PEG macromer resulted in the formation of cross-linked gels due to the multifunctionality of macromer. Crosslinked P(HEMA) or P(HEMA-co-HPMA-co-NVP) chains were interpenetrated into the cross-linked three-dimensional networks of PEG. It was found that albumin adsorption onto the contact lens prepared by P(HWMA)/PEG IPN decreases with a decrease of molecular weight of PEG whereas its adsorption onto the contact lens prepared by P(HEMA-co-HPMA-co-NVP)/PEG IPN decreases with an increase of molecular weight of PEG. Also, it was found that albumin adsorption onto the both contact lens decreases with an increase of concentration of PEG macromer in the IPN preparation. There are also more adequate in the bioinertness and bioadhesion for the contact lens by P(HEMA)/PEG IPN or P(HEMA-co-HPMA-co-NVP)/PEG IPN than that by P(HEMA) or P(HEMA-co-HPMA-co-NVP).

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The Developing Trend in Bioresorbable Stent for Treatment of Coronary Artery Disease (관상동맥질환 치료를 위한 생체흡수형스텐트의 개발 동향)

  • Jeong, Gyeong-Won;Kim, Tae-Hoon;Nah, Jae-Woon;Park, Jun-Kyu
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.497-502
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    • 2018
  • The coronary artery disease (CAD) is rapidly increasing such as angina pectoris and atherosclerosis. The CAD is induce by cholesterol and calcium like plaque absortion to artery wall. The percutaneouss coronary intervention is non-invasive treatment that narrowed-artery is expand by using balloon catheter and bare metallic stent. The metallic stents have been effective in reducing the dead by coronary artery disease, but the permanent presence of the metallic stent has been associated with persistent inflammation, and incidence of late thrombosis. Therefore, development bioresorbable vascular scaffold (BRS) is rapidly increasing for treatment of long-term complications and arterial restenosis by permanentmetal prosthesis such as stent. The review discusses the BRS trend for successfully development.

Removal Characteristics of Nitrogenous Organic Chlorination Disinfection By-Products by Activated Carbons and Biofiltration (활성탄과 생물여과 공정에서의 유기질소계 염소 소독부산물 제거 특성)

  • Seo, In-Suk;Son, Hee-Jong;Choi, Young-Ik;Ahn, Wook-Sung;Park, Chung-Kil
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.2
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    • pp.184-191
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    • 2007
  • Coal-, coconut- and wood-based activated carbons and anthracite were tested for an adsorption and biodegradation performances of nitrogenous chlorinated by-products such as chloropicrin, DCAN, DBAN and TCAN. In early stage of operations, an adsorption performance was a main mechanism for removal of nitrogenous chlorinated by-products, however as increasing populations of attached bacteria, the bacteria played a major role in removing nitrogenous chlorinated by-products in the activated carbon and anthracite biofilter. It was also investigated that the compounds were readily subjected to biodegrade. Whilst the coal- and coconut-based activated carbons were found most effective in adsorption of the compounds, the anthracite was worst in adsorption of the compounds. Highest populations and activity of attached bacteria were shown in the coal-based activated carbon. The populations and activity of attached bacteria decreased in the order: coconut-based activated carbon > wood-based activated carbon > anthracite. The attached bacteria were inhibited for removal of the compounds at temperatures below $10^{\circ}C$. The attached bacteria were more active at higher water temperatures$(20^{\circ}C\;<)$ but less active at love. water temperature$(10^{\circ}C\;>)$. The removal efficiencies of the compounds obtained using coal-, coconut- and wood-based activated carbons and anthracite were directly related to the water temperatures. In particular, water temperature was the most important factor for removal of the compounds in the anthracite biofilter because the removal of the compounds depended mainly on biodegradation. Therefore, the main removal mechanism of the compounds the main mechanism on the removal of the compounds using activated carbon was both adsorption and biodegradation by the attached bacteria. The observation suggests that using coal-based activated carbon is the best for removal of nitrogenous chlorinated by-products in the water treatment.

A study on the reaction characteristics at the biosorption of Rhodamine B using waste sludge (폐 슬러지를 이용한 Rhodamine B의 생체흡착시 반응특성에 관한 연구)

  • Lee, Chang Han;An, Gap Hwan;Song, Seung Gu
    • Journal of Environmental Science International
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    • v.13 no.7
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    • pp.689-695
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    • 2004
  • The properties of biosorption of dye(Rhodmine B) was investigated to figure out the effects of temperature as a function of dye concentration and sludge concentration by the Langmuir and Lagergen adsorption model. It was found that the uptake capacity of biosorption was increased at low temperature. The Langmuir adsorption model was found suitable for describing the biosorption of the dye. The experimental results indicated that the dye uptake process followed the pseudo-first-order kinetics.

나노입자와 표면증강라만분광학 (Surface Enhanced Raman Scattering: SIRS)을 활용한 탄소재료, 고분자 자기조립박막 및 생체분자 연구

  • 주상우
    • Polymer Science and Technology
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    • v.15 no.2
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    • pp.228-233
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    • 2004
  • 본 기고부분에서는 레이저 라만 분광법을 이용하여 나노입자에 흡착된 자기조립박막의 구조를 밝히고 응용성을 모색하는 일을 소개하고자 한다 Au 나노입자는 최근 재료과학과 의학 및 생물학에서 그 쓰임의 폭이 넓어지고 있다. 나노입자가 처음 사용된 예들 중에 가장 잘 알려진 것은 고대 로마 시대의 Lycurgus 컵에 기인한다고 한다. 컵 안에 함유된 미량의 은이나 금 나노입자에 의해서 반사했을 때와 투과할 때의 빛깔이 다르게 보이며 이러한 성질은 중세건축물의 스탠드 글라스에 이용되어 왔다. 근대적인 의미에서 Au 콜로이드의 수용액이 작은 미세입자가 분산되어 있다고 생각한 사람은 전기화학의 창시자라 할 수 있는 영국의 Faraday라 할 수 있다.(중략)

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The effect of phosphoric acid on the structural properties of regenerated chitin (재생 키틴의 특성에 미치는 인산 용매의 영향)

  • Oh, Byung-Ho;You, Young;Park, Won-Ho
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.157-158
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    • 2003
  • 키틴은 N-acethyl-D-glucosamine이 $\beta$-(1$\longrightarrow$4) 결합한 천연 고분자이며, 게나 새우 등의 갑각류, 오징어 등의 연체류, 그리고 곤충류 및 균류의 세포벽 등에 광범위하게 분포되어 있다. 키틴은 지구상에 존재하는 천연 다당류 중에 셀룰로오스 다음으로 많은 양이 존재하며 흡착성, 보습성, 유화성 및 생분해성을 가진 무독성 물질이고 항균작용, 생체적합성 등 다양한 특성을 기능을 가진다. 그러나, 분자내에 존재하는 아세트아미노기가 분자간의 수소결합으로 매우 강하게 결합되어 있기 때문에 화학약품에 대한 내성이 강할 뿐만 아니라 물과 대부분의 일반 유기용매에 녹지 않기 때문에 그 용도가 한정되어 있다. (중략)

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Adsorption of Glycerol on Hydroxyapatite Enhanced Colloidal Stability in Phosphate Buffered Saline Solution (글리세롤 흡착으로 인산완충식염수에서 콜로이드 안정성이 향상된 수산화인회석 합성)

  • Jaun An;Hyebin Choi;Keunyoung Lee;Ki-Young Kwon
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.670-673
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    • 2023
  • The biocompatibility of hydroxyapatite (HAP) has led to its application in various fields. To accomplish practical biological applications, such as drug/gene delivery, the colloidal stability of HAP in phosphate-buffered saline (PBS) is particularly important. In this study, we prepared a glycerol incorporated-HAP (Gly-HAP) by heating HAP in a glycerol environment at 200 ℃. To compare morphology and colloidal stability, HAP prepared at room temperature (RT-HAP) was thermally treated in water at 200 ℃ (H2O-HAP). The heat treatment of HAP in both water and glycerol solutions results in an increase in the crystallinity of HAPs. Due to the low solubility of HAP in glycerol and the adsorption of glycerol on the HAP surface, crystal growth is limited. However, the heat-treated HAP under water increased in size by approximately four times compared to the initial crystallites. Compared to RT-HAP and H2O-HAP, Gly-HAP shows improved colloidal stability in PBS, which originates from the adsorption of glycerol on the HAP surface that inhibits the agglomeration of individual HAP precipitates.

A Study on the Fluorescence Characteristics of Dye-doped Silica Nanoparticles for Integrated Bio Imaging (융합 바이오 이미징을 위한 염료 도핑 된 실리카 나노입자의 형광 특성에 관한 연구)

  • Kim, Ki-Chul
    • Journal of Convergence for Information Technology
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    • v.8 no.5
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    • pp.45-50
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    • 2018
  • The functional nanomaterials of fluorescent dye-doped silica nanoparticles(NPs) are applied to bio applications such as bio-labeling of DNA micro-array, and bio-imaging. Organic dye-doped fluorescent silica NPs exhibit excellent bio-compatibility, non-toxic, and highly hydrophilic properties. In this study, organic fluorescent dyes were dissolved in ethanol, and deionized(DI) water. Organic fluorescent dyes were physically adsorbed to silica NPs and chemically doped to silica NPs. The fluorescence characteristics(FLC) was investigated by UV lamp irradiation of 365 nm wavelength. As results, the FLC of dye-doped silica NPs exhibits better than dye-adsorbed silica NPs and the FLC was improved with the increase of concentration of doped-dyes. The fluorescent organic dyes were well dissolved in ethanol than DI water. The photostability of dye-doped silica NPs was superior than pure fluorescent organic dye. The FLC of optimized dye-doped silica NPs would be applied to agent of non-invasive fluorescence bio-imaging in live cell and in vivo.