• Title/Summary/Keyword: 생용출

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Remediation of Arsenic Contaminated soils Using a Hybrid Technology Integrating Bioleaching and Electrokinetics (생용출과 전기동력학을 연계한 통합기술을 이용한 비소 오염 토양의 정화)

  • Lee, Keun-Young;Kimg, Kyoung-Woong;Kim, Soon-Oh
    • Journal of Soil and Groundwater Environment
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    • v.14 no.2
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    • pp.33-44
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    • 2009
  • The objective of the study was to develop a hybrid technology integrating biological and physicochemical technologies to efficiently remediate arsenic contaminated lands such as abandoned mine area. The tailing soil samples contaminated with As at a high level were obtained from Songchon abandoned mine, and the content of arsenic and heavy metals as well as physicochemical properties and mineral composition were investigated. In addition, two sets of sequential extraction methods were applied to analyze chemical speciations of arsenic and heavy metals to expect their leachability and mobility in geoenvironment. Based on these geochemical data of arsenic and heavy metal contaminants, column-type experiments on the bioleaching of arsenic were undertaken. Subsequently, experiments on the hybrid process incorporating bioleaching and electrokinetics were accomplished and its removal efficiency of arsenic was compared with that of the individual electrokinetic process. With the results, finally, the feasibilty of the hybrid technnology was evaluated. The arsenic removal efficiencies of the individual electrokinetic process (44 days) and the hybrid process incorporating bioleaching (28 days) and electrokinetics (16 dyas) were measured 57.8% and 64.5%, respectively, when both two processes were operated in an identical condition. On the contrary, the arsenic removal efficiency during the bioleaching process (28 days) appeared relatively lower (11.8%), and the result indicates that the bioleaching process enhanced the efficacy of the electrokinetic process as a result of mobilization of arsenic rather than removed arsenic by itself. In particular, the arsenic removal rate of the electrokinetics integrated with bioleaching was observed over than 2 times larger than that obtained by the electrokinetics alone. From the results of the study, if the bioleaching which is considered a relatively economic process is applied sufficiently prior to electrokinetics, the removal efficiency and rate of arsenic can be significantly improved. Consequently, the study proves the feasibility of the hybrid process integrating both technologies.

Hot- Water Soluble and Insoluble Materials of Waxy Black Rice Starch (찰흑미(상해항혈나) 전분의 열수가용성 및 불용성 물질)

  • Choi, Gyeong-Cheol;Na, Hwan-Sik;Oh, Geum-Soon;Kim, Sung-Kon;Kim, Kwan
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.2
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    • pp.219-222
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    • 2005
  • Some structural characteristics of hot-water soluble and insoluble starches (waxy black rice starch) were investigated. The hot-water soluble material content of waxy black rice starch was higher (16.6%) than that (13.4%) of Shinsunchalbyeo starch heated at 98$^{\circ}C$ for 8 min. The Amax and absorbance at 625 nm for hot-water soluble and insoluble material of waxy black rice starch were lower than those of Shinsunchalbyeo. Elution patterns of hot water soluble and insoluble materials by gel permeation chromatography (Sepharose CL-2B) were similar in both samples.

Effects of biodegradable polymer coating urea to nitrogen release in the soil column (생분해성 코팅 요소 종류별 질소 용출 및 온실가스 발생량에 미치는 영향)

  • Jaeyee Choi;JoungDu Shin;HyunJong Cho;Woojin Chung;Sang Beom Lee;Seok In Yun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.32 no.1
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    • pp.49-59
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    • 2024
  • Biodegradable coating urea plays an important role in reducing the non-pollutants in agroecosystems, maximizing the plant nutrient utilization efficiency and slow-releasing nitrogen. Herein, the objective of this study was to investigate the nitrogen-releasing patterns and greenhouse gas emissions on different biodegradable coating urea. The treatments consisted of the control as an application of chemical fertilizers, NBCF as the non-biodegradable coating urea, NB60, and MDS as biodegradable coating urea. As a result of this study, the maximum accumulated total nitrogen (TN) concentration in the NBCF was higher at 33% than one in the NB60 during the precipitation periods. Its leaching period in the NCBF was prolonged for day 10 compared to the NB60. TN and NO3-N releasing patterns in the NBCF and NB60 were fitted well on linear types(R2≥0.991), but their control and MDS were fitted well on Sigmoid curves(R2≥0.994) with high releasing concentration in the MDS compared to the control during leaching periods. For the greenhouse gas emissions, CH4 emissions in the NBCF, NB60, and MDS were increased at 0.38%, 11.36%, and 5.91%, and N2O emissions were also increased at 50.5%, 32.4%, 58.8% as compared to the control, respectively. Therefore, application of biodegradable polymer coating urea might mitigate the non-point pollutants in agro-ecosystem.

Analysis on the Reduction of Phosphorus Release in River and Lake Sediments through Application of Capping Technology (Capping 기술을 이용한 하천 및 호소 퇴적토의 인 용출 저감 효과 분석)

  • Kim, Seog-Ku;Yun, Sang-Leen
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.11
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    • pp.781-790
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    • 2014
  • Contaminants such as organic matters, nutrients and toxic chemicals in rivers and lakes with a weak flow rate are first removed from the water and accumulated in the sediments. Subsequently, they are released into the water column again, posing direct/indirect adverse effects on the water quality and aquatic ecosystems. In particular, phosphorus is known to accelerate the eutrophication phenomenon when it is released into the water column via physical disturbance and biological/chemical actions as one of important materials that determine the primary production of aquatic ecosystems and an element that is stored mainly in the sediments in the process of material circulation in the body of water. In this study, the effect on reducing phosphorus release in sediments was analyzed by applying different capping materials to lake water, where the effect of aquatic microorganisms is taken into account, and to distilled water, where the effect of microorganisms is excluded. The experimental results showed that capping with chemical materials such as Fe-gypsum and $SiO_2$-gypsum further reduced the phosphorus release by at least 40% compared to the control case. Composite materials like granule gypsum+Sand showed over 50% phosphorus release reduction effect. Therefore, it is determined that capping with chemical materials such as granule-gypsum and eco-friendly materials such as sand is effective in reducing phosphorus release. The changes in phosphorus properties in the sediments before and after capping treatment showed that gypsum input helped to change the phosphorus that is present in lake sediments into apatite-P, a stable form that makes phosphorus release difficult. Based on the above results, it is expected that the application of capping technology will contribute to improving the efficiency of reducing phosphorus release that occurs in river and lake sediments.

Effect of aging on the sorption and desorption behaviors of Pb and Cd in the coastal sediment (노화(aging)가 연안 퇴적물 내 납과 카드뮴의 흡/탈착 거동에 미치는 영향)

  • Gwak Mun-Yong;Sin Won-Sik
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.247-252
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    • 2006
  • 오염 퇴적물내 중금속의 방출과 이에 따른 생이용성(bioavalability)은 기존의 가역 평형관계로써 설명하기에 불충분한 것으로 알려져 있다. 최근 연구결과에 의하면 이러한 탈착 저항성을 설명하기 위한 비가역적 모델에 의해 퇴적물내 중금속의 탈착저항성 부분이 존재함이 밝혀졌다. 탈착저항성에 대해서는 아직 충분한 규명이 이루어지지 않았으나, 오염물질의 노화(aging)에 의해 일단 탈착저항성을 띠게 되면 생이용성(bioavailability)이 감소되는 것으로 알려져 있다. 본 연구에서는 노화(aging)가 연안 퇴적물 내 납과 카드뮴의 흡/탈착 특성에 미치는 영향을 알아보기 위해 연속 탈착실험과 biphasic 탈착모델을 적용함으로써 납과 카드뮴의 탈착저항성을 규명하고자 하였다. 그리고 연속 추출 실험을 통해서 노화(aging)에 따른 퇴적물 내 납과 카드뮴의 흡착 기작을 규명하고자 하였다. 연속탈착 실험 결과 시간이 경과함에 따라 탈착저항성부분의 크기가 증가하였으며, 연속추출 실험 결과 납의 경우 carbonate fraction에서 추출된 납이 가장 많았으며, 노화(aging) 따라 exchangeable fraction에서 추출된 납이 감소하는 반면 reducible, organic material, residual fraction에서 추출된 납의 양이 증가하였다. 카드뮴의 경우 가장 많은 양이 추출된 단계는 exchangeable fraction이였으며, organic material fraction에서는 카드뮴이 추출되지 않았다. 노화(aging) 따라 reducible fraction과 residual fraction에서의 추출량이 증가하는 경향을 보였으나 그 양은 매우 적은 것으로 나타났으며, 노화(aging)에 따른 exchangeable fraction과 carbonate fraction에서의 추출량은 큰 변화가 없었다. 대해서는 북한지역의 분포상황을 밝혔다.것을 알 수 있었으며, 크롬과 비소의 경우는 초기에 많이 용출되고, 구리의 경우는 꾸준히 용출되는 것을 알 수 있었다. 3년 된 통나무집이 8년 된 통나무집보다. 용출양이 더 컸으며, 이는 CCA성분이 초기에 많이 용출된다는 것을 의미한다. 억제 효과를 나타내었고 Hep3B에서는 부탄을 분획물 (1 mg/mL)에서 82%의 비교적 높은 성장억제효과를 나타내었다.as a "front" and "back". Thus, Germany′s private space may face a genuine public space and street, which is rare in the Korean housing. Although the layout of indoor space in the korean housing tends to be open, such an openness may be outstanding in living and dining spaces, kitchen and various accesses to rooms. In the case of Germany, such indoor spaces are usually closed to each other. Thus corridors act to separate these spaces. Such differences are analysed to be due to the different perceptions of interpersonal and socio-cultural attributes as intra-family and inter-neighbor relationships or communications. 알 수 있었다.도 질소와 인산처럼 토양지지대가 있는 경우가 낮은 함량을 유지하였다.pe from the daily life, to fantasize and daydre

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COLOR FIXING EFFECT OF TANNIC ACID IN LAVER (탄닌산처리에 의한 김색소 고정효과)

  • HA Bong-Seuk
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.8 no.1
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    • pp.31-36
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    • 1975
  • A combination of two specifically different pigments, phycoerythrine and chlorophyll, gives the laver shining black color. This shining black color is the dominant factor in deciding tile quality of the dried product of laver (dried laver). Therefore, this experiment was carried out to know the effect of tannic acid as a pigment fixing agent. Raw laver, Porphyra spp., was treated with tannic acid solutions to prevent dissolution of biliproteins especially phycoerythrine in to the fresh water. This danger is mostly revealed when the chopped and shredded lavers are suspended in fresh water before the laver sheets are finally made. The influence of mechanical damage with different diameters of chopper plate on dissolution of the pigment was also mentioned. Theresultsobtainedareasfollows: 1. When the raw laver not yet chopped was stored for 3 days at $1\~5^{\circ}C$ in a dark place, the contents of chlorophyll and phycoerythrine decreased. 2. In the organoleptic test (Table 2,3,4),: the dried laver with a good coloration and surface gloss was obtained from a chopper plate with 7 mm or 3 mm. 3. A tannic acid solution of $0.02\%$ and $0.004\%$ appeared effective In preventing dissolution of phycoerythrine.

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Study on the Preparation and Utilization of Sardine Protein (정어리 단백질 제조와 이용에 관한 연구)

  • 이경하;차월석;김종수
    • KSBB Journal
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    • v.16 no.4
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    • pp.426-429
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    • 2001
  • To utilize sardine protein more effectively, fish meat paste products mixing sardine protein concentrate with pollack frozen meat paste at the ratio 0%, 15%, 20% and 25% were produced, and the change of firmness, sensory evaluation and the properties of amino and fatty acid were investigated. The quantity of sardine protein and it was almost gushed out around one hour at 100$\^{C}$. The firmness of the meat paste product was found as 0.54% and was better when the concentrated sardine protein was added at the ratio 15% and it was much higher than just that of pollack meat paste. In that case, total amino acid was the highest as 90.701 mg/g from the point of view of the amino acid composition. In terms of the fatty acid composition, unsaturated fatty acid of raw and boiled sardine was 61,8634% and 61.9384% each. We could find out that the high value of C$\_$20:5/ and C$\_$22:6/ of raw sardine was 7.2931% and 27.7843%, respectively.

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A study on Surfactants for Electrokinetic Soil Remediation (동전기적 토양복원에 적합한 계면활성제의 선정)

  • 이현호;박지연;김상준;이유진;양지원
    • Journal of Soil and Groundwater Environment
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    • v.8 no.1
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    • pp.1-8
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    • 2003
  • Three different surfactants, APG, Brij30, and SDS, were tested to study the characteristics of sorption on soil surfaces, washing ability, biodegradability, and electrokinetic removal. Kaolinite and phenanthrene were selected as a model soil and a representative HOC, respectively. Phenanthrene was sorbed on kaolinite up to 2,200 mg/kg dry soil. The APG, Brij30, and SDS were sorbed on soil to 40, 7, and 4g/kg soil, respectively. The washing ability of phenanthrene was in order of Brij30>SDS>APG. The biodegradability tested with sludge was in order of APG>Brij30>SDS. In the electrokinetic test, the highest removal efficiency was obtained with APG that exhibited the highest electroosmotic flow. To increase the removal efficiency of HOC in the electrokinetic remediation, the most important factor was the selection of surfactant which maximized the electroosmotic flow.

Effect of the Physicochemical Properties of Soil on the Arsenic Bioaccessibility (비소용출에 대한 토양의 물리화학적 특성 영향)

  • Yang, Jae-Kyu;Chang, Yoon-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.7
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    • pp.731-737
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    • 2006
  • Four well-characterized soils collected from A- and B-horizon in the Department of Energy Oak Ridge Reservation in USA, mainly distributed with Inceptisol(Inc) and Ultisol(Ult) soils, were used in this work. The bioaccessibility of arsenic as well as oxidation phenomena of As(III) was investigated with soils spiked with As(III) and As(V) using a physiologically based extraction test(PBET) at pH 1.5 and 1:100 soil to solution ratio. Also effect of aging time on the bioaccessibility of arsenic was investigated over the 6 months. After 48 hours(fresh) contacting As(V) solution with soils, all soils rapidly and strongly sequestrated As(V), especially Ult-B. However, little sequestration was observed after 3-months. When As(III) was spiked on the same soils, a great portion of As(III) was oxidized to As(V) after 48 hrs, especially Inc-A and Ult-A soils, which is strongly related with Mn content in soils. By using As(III)-spiked soils, much reduced bioaccessibility as total arsenic was observed from Inc-B and Ult-B soils over the 6 months aging time compared to that from Inc-A and Ult-A soils. This result can be explained by the continuous sequestration of As(V), produced from oxidation of As(III), onto Inc-B and Ult-B soils having much amount of iron. The trend of As(III) sequestration over six months aging time was quite similar with that of As(V) sequestration.