• Journal of the Korean Chemical Society
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• v.55 no.3
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• pp.385-391
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• 2011

The time-dependent density functional theory (TDDFT) method has been carried out to investigate the excitedstate hydrogen-bonding dynamics of phenol-$(H_2O)_2$ complex. The geometric structures and infrared (IR) spectra in ground state and different electronically excited states ($S_1$ and $T_1$) of the hydrogen-bonded complex have been calculated using the density functional theory (DFT) and TDDFT method. A ring of three hydrogen bonds is formed between phenol and two water molecules. We have demonstrated that the intermolecular hydrogen bond $O_1-H_2{\cdots}O_3-H$ of the three hydrogen bonds is strengthened in $S_1$ and $T_1$ states. In contrast, the hydrogen bond $O_5-H_6{\cdots}O_1-H$ is weakened in $S_1$ and $T_1$ states. These results are obtained by theoretically monitoring the changes of the bond lengths of the hydrogen bonds and hydrogen-bonding groups in different electronic states. The hydrogen bond $O_1-H_2{\cdots}O_3-H$ strengthening in both the $S_1$ and $T_1$ states is confirmed by the calculated stretching vibrational mode of O-H (phenol) being red-shifted upon photoexcitation. The hydrogen bond strengthening and weakening behavior in electronically excited states may exist in other ring structures of phenol-$(H_2O)_n$.

• Journal of the Korean GEO-environmental Society
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• v.11 no.8
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• pp.5-14
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• 2010

Recent researches on the behavior of gravelly soils have been focused mainly on the relative density or on the gravel content. And some researchers presented the liquefaction behavior based on the relative density whereas others based on the gravel content of gravelly soil. However the relative densities vary with gravel content and relative density is not enough to fully express the behavior of gravelly soils. Therefore in this research state parameter which considers void ratio and effective confining pressure is introduced and Steady State Line(SSL) of gravelly soils for various gravel content are determined by undrained triaxial tests in order to express the behavior of gravelly soils. From the research the position of SSL moved downward with gravel content. And the same density of soil showed dense sand behavior or loose sand behavior depending upon the confining pressure. Especially relative density 80% of gravelly soil showed loose sand behavior under high confining pressure. However the gravelly soils with similar state parameters showed similar stress behaviors. It can bee seen that state parameter is useful tool to evaluate undrained behavior of gravelly soils. Also state parameter and undrained strength showed good correlations.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1991.06a
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• pp.70-75
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• 1991

기어는 기계시스템에서 동력전달 및 운동전환을 담당하는 기본 요소로 공작기계, 건설기계, 농업기계 등의 산업기계와 항공기, 자동차, 선박등의 운송분야, 사무용 및 계측기기 등 산업전반에 걸쳐 사용되고 있으며, 최근에는 로보트를 위시한 자동화 장치의 구동 및 동력전달 장치로 사용되고 있다. 최근의 기어시스템은 기계류의 일반적인 경향인 고속, 고부하, 결량화 추세에 따라 고정밀, 소형화되어 가고 있으며 부하한계에 가깝도록 큰 하중에 견딜것이 요구되고 있다. 따라서 기어의 설계 및 제작시, 여유있는 설계가 허용되지 않으며 정밀성을 높이기 위한 설계로, 설계인자의 세분화가 요구되어지고 있다. 국제적으로 통용되고 있는 강도설계 규격에서 면압강도시 표면상태계수(Surface condition factor)를 정의하고 있다. 본 연구에서는 동력순환식 기어 시험장치를 이용하여 표면처리 상태가 다른 3종류(열처리를 하지 않은 기어, 침탄 및 고주파 표면 열처리한 기어)의 스퍼어 기어를 이요하여 회전수별 표면거칠기의 변화 상태를 고찰하고, 변수를 응용하여 물리적 의미를 파아갛고, 윤활해석을 통한 윤활조건과 치면상태와의 상호 관계에 대하여 고찰해 보고자 한다.

• Journal of Korea Society of Industrial Information Systems
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• v.7 no.3
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• pp.9-14
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• 2002

In this paper we propose a method for performance enhancement of speech recognizer under noisy conditions. The parallel combination model which is presented at the PMC method using multiple Gaussian-distributed mixtures have been adapted to the variation of each mixture. The CDHMM(continuous observation density HMM) which has multiple Gaussian distributed mixtures are combined by the proposed PMC method. Also, the EM(expectation maximization) algorithm is used for adapting the model mean parameter in order to reduce the variation of the mixture density. The result of simulation, the proposed PMC adaptation method show better performance than the conventional PMC method.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1992.04a
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• pp.216-222
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• 1992

현재의 가공 시스템에 있어서 가공 작업자체는 NC 공작기계, 머시닝 센터등에의해 자동적으로이루어 지고있으나, 작업 상태에 대한 감시 및 공구교환 시기의 결정은 주로 숙련된 작업자에 의해이루어 지고 있으므로완전 자동화, 무 인화에 큰장애가 되고 있다. 특히 공구 파손 및 공구 마멸에 대한 감시는 공구 교환 시점의 자동결정 뿐 아니라 가공 시스템의 무인 운전을 위해서 필수적인 것으로, 기계 정지 시간(down time)을 줄일 수 있고, 제품의 정밀도를 높일 수 있다. 본 연구에서는 이를 위한 기초 연구로, 가공상태를 나타내는 감시신호로 AC 주축 모터 전류와 주축대진동 신호 를 선정하여 엔드밀 공구와 드릴 공구를 이용한 작업에서의 공구 상태변화에 따른 감시신호의 성능을 조사하였다.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.469-469
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• 2010

공정 플라즈마에서 가장 중요한 요소 중 하나는 챔버 내 균일도 제어이다. 챔버 내 플라즈마 상태가 공간적으로 불균일한 경우 과에칭, 미증착 등의 문제가 웨이퍼의 특정 영역에 나타나게 되어 공정 수율이 감소된다. 이 연구에서는 2차원 평면 탐침을 챔버 내에 삽입하여 플라즈마 전자온도, 밀도, 이온 전류량 등의 상태변수를 측정 가능한 방법을 연구하였다. 기존의 2차원 평면 탐침과 달리, 측정 회로와 계산 모듈을 모두 삽입하여 외부의 컨트롤러가 필요 없어 반도체나 디스플레이의 플라즈마 공정의 사이사이에 삽입되어서 플라즈마 상태변수를 측정할 수 있는 장점을 가지고 있다. 본 임베디드 2차원 평면 탐침은 측정회로가 외부와 단절되어 전기적으로 절연되어 있어, 측정 방법으로 이중 탐침법을 응용하였다. 이중탐침에 정현파 전압을 인가하고 이 경우 들어오는 전류의 제 1 고조파와 제 3 고조파를 크기를 측정하는 방법으로 플라즈마 변수 계산이 가능하다. 이 측정 방법은 플라즈마 공정에서 쉽게 관찰할 수 없었던 공간적인 상태변수의 분포를 알 수 있고 플라즈마 균일도 제어에 기여할 수 있을 것이다.

• Journal of Astronomy and Space Sciences
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• v.10 no.2
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• pp.163-188
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• 1993

On the framework of Tolman spacetime model, the caustics around a local perturbed region in redshift is due to the local expansion rate induced by a local density inhomogeneity in real space. We have compared the caustics in redshift space, which are analytically obtained, with the observed redshift-distance patterns of galaxies which are belonging to Coma and Perseus clusters. For the Abell density distribution model and polytropic density profiles which are well-fitting the optical and X-ray observations, respectively, the size of caustics which is defined by "turnaround radius" of a local density perturbed region should give constraints on the sizes and masses of rich clusters and give also a clue to understand the state of hot X-ray emitting gas.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2005.05a
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• pp.162-167
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• 2005

Recently, the advanced industries using micro parts are rapidly growing. Micro endmilling is one of the prominent technology that has wide spectrum of application field ranging from macro to micro parts. Also, the method of micro-grooving using micro endmilling is used widely owing to many merit, but has problems of precision and quality of products due to tool wear and tool fracture. This study deals with condition monitoring using acoustic emission(AE) signal in the micro-grooving. First, the feature extraction of AE signal directly related to machining process is executed. Then, the distinctive micro endmill state according to the each tool condition is classified by using the fuzzy C-means algorithm, which is one of the methods to recognize data patterns. These result is effective monitoring method of micro endmill state by the AE sensing techniques which can be expected to be applicable to micro machining processes in the future.

• Journal of Korean Society of Transportation
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• v.23 no.3 s.81
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• pp.137-147
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• 2005

This study is to define new road capacity concept, and to develop and propose an estimation method, through the analysis of individual vehicular behaviors in continuum flow. Developments in detection technology enable various and precise traffic data collection. The U.S. HCM (Highway Capacity Manual) method does not require such various and precise traffic data, and outputs only limited results. Alternative capacity concepts, which can be classified into a stochastic model and behavioral or deterministic model, are attempts for modeling some prominent traffic flow features, namely so-called a capacity drop and a traffic hysteresis, using such various and precise traffic data. Yet, no capacity concept up-to-date can describe both features. The analysis of individual vehicular behaviors, including speed-density plot per time lap, traffic flow-speed-density diagram per each sampling interval, time headway distribution, and free flow speed distribution, is performed for overcoming the limits of the previous capacity concepts. A stochastic methods are applied to determine time headway for estimating freeway capacity for traffic control.

• Clean Technology
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• v.15 no.1
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• pp.42-46
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• 2009

Solvent-free direct preparation of dichloropropanol (DCP) from glycerol (by-product of bio-diesel production) and hydrochloric acid gas was carried out over acetin catalyst in a gas-liquid batch reactor. For this purpose, acetin mixture and triacetin were used as a homogeneous acetin catalyst. Performance in the acetin-catalyzed reaction was compared to that in the non-catalytic reaction under the same reaction conditions ($110^{\circ}C$, 3 bar, 3 h). Conversion of glycerol in the acetin-catalyzed reactions was ca. 3% higher than that in the non-catalytic reaction, and selectivity for dichloropropanol in the acetin-catalyzed reactions was ca. 50% higher than that in the non-catalytic reaction. It was also revealed that the catalytic performance of triacetin was ca. 2% higher than that of acetic mixture.