• Title/Summary/Keyword: 상안전성

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Influence of CuO Dopants on the Sintering Ability and Phase Stability of Yttria-Stabilized Tetragonal Zirconia Polycrystals (Y-TZP의 燒結性 및 相 安定性에 대한 CuO添加의 影響)

  • Pee, Jae-Hwan;Kim, Yun-Hae;Motozo Hayakawa
    • Journal of Ocean Engineering and Technology
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    • v.13 no.2 s.32
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    • pp.35-40
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    • 1999
  • Effects of CuO addition on the sintering ability and the phase stability of Y-TZP. (Yttria doped Tetragonal Zirconia Polycrystals) were studied. The CuO dopants were found to be quite effective in reducing the sintering temperature to obtain full density and refining the grain size. The maximum allowable concentration of the dopants was limited to 0.3%mol% for CuO to maintain fully tetragonal phase. With the addition of these dopants, the flexual strength decreased by 20% in comparison with the undoped specimen but the fracture toughness increased by 15%.

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Electrical Conductivity of ZrO2 Doped with Sc2O3 and CeO2 (Sc2O3와 CeO2가 첨가된 ZrO2의 전기전도도)

  • Lee, Dong-Suek;Heo, Jang-Weon;Kim, Jae-Dong;Kim, Joo-Sun;Lee, Hae-Weon;Kim, Gyeung-Ho;Kim, Dae-Jun;Lee, Jong-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.4
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    • pp.346-351
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    • 2002
  • The electrical conductivity and phase stability of $ZrO_2$ doped with $Sc_2O_3$ and $CeO_2$ were investigated in order to search for better solid electrolyte material for solid oxide fuel cell. Present study showed that $ZrO_2$ doped with $Sc_2O_3$ and $CeO_2$ exhibited no phase transition during the heat treatment up to $1350^{Circ}C∼1550^{Circ}C$ and was stable as a cubic phase in whole temperature ranges. The $ZrO_2$ doped with $Sc_2O_3$ and $CeO_2$ showed much higher electrical conductivity than YSZ in the temperature range of $300∼^{Circ}C$ and better long term stability than other sc-$ZrO_2$ based electrolyte that showed the possibility as a strong candidate electrolyte material for intermediate-or low-temperature SOFC.