• Title/Summary/Keyword: 삼성분분석

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Physical Characteristic Analysis of Municipal Solid Waste for Estimation of Gasification Pretreatment Condition (가스화용 전처리 조건예측을 위한 생활폐기물의 물리적 특성 분석)

  • Yoon, Youngsik;Lim, Yongtaek;Park, Sunam;Gu, Jaehoi;Im, Nakjun;Han, Haengseok
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.171.1-171.1
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    • 2011
  • 폐기물의 처리방법은 중간처리와 최종처리로 구분되며, 중간처리의 방법으로는 고형화, 생물학적 처리(소화), 화학적 처리(중화/침전/추출), 자원화 및 재활용, 소각/열분해용융/가스화 등이 있다. 최종처리 방법으로는 매립, 해양투기 등이 있으며, 과거에는 폐기물의 처리 방법으로 최종처리가 많이 이용되었으나 현재에는 지속가능한발전의 이념아래 폐기물의 자원화, 청정에너지의 생산 등을 이유로 전처리 기술이 많이 보급되고 있는 추세이다. 남원시에서 발생되는 생활폐기물은 2010년 통계에 따르면 하루 평균 약 43돈에 이르고 있으며, 매립지의 사용연수를 연장하기 위한 중간처리 방법이 검토되고 있다. 생활폐기물의 가장 일반적인 중간처리 방법으로는 소각, 열분해용융, 가스화 등이 적용될 수 있으며, 이와 같은 열적처리는 폐기물의 감용 및 감량 효율이 높은 중간처리 방법에 속한다. 이러한 열적처리를 위해서는 폐기물의 물리적 특성에 대한 조사 및 검토가 가장 먼저 선행되어야 하며, 본 연구에서는 남원시에서 발생되는 생활폐기물의 성상분류, 삼성분분석, 원소분석, 발열량분석 결과를 통해 가스화에 적합한 전처리 조건을 예측하였다.

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A New Correction Method for Ship's Viscous Magnetization Effect on Shipboard Three-component Magnetic Data Using a Total Field Magnetometer (총자력계를 이용한 선상 삼성분 자기 데이터의 선박 점성 자화 효과에 대한 새로운 보정 방법 연구)

  • Hanjin Choe;Nobukazu Seama
    • Geophysics and Geophysical Exploration
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    • v.27 no.2
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    • pp.119-128
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    • 2024
  • Marine magnetic surveys provide a rapid and cost-effective method for pioneer geophysical survey for many purposes. Sea-surface magnetometers offer high accuracy but are limited to measuring the scalar total magnetic field and require dedicated cruise missions. Shipboard three-component magnetometers, on the other hand, can collect vector three components and applicable to any cruise missions. However, correcting for the ship's magnetic field, particularly viscous magnetization, still remains a challenge. This study proposes a new additional correction method for ship's viscous magnetization effect in vector data acquired by shipboard three-component magnetometer. This method utilizes magnetic data collected simultaneously with a sea-surface magnetometer providing total magnetic field measurements. Our method significantly reduces deviations between the two datasets, resulting in corrected vector anomalies with errors as low as 7-25 nT. These tiny errors are possibly caused by the vector magnetic anomaly and its related viscous magnetization. This method is expected to significantly improve the accuracy of shipborne magnetic surveys by providing corrected vector components. This will enhance magnetic interpretations and might be useful for understanding plate tectonics, geological structures, hydrothermal deposits, and more.

Phosphate Sorption on Boehmite with Eu(III): P K-edge EXAFS Fingerprinting (뵈마이트 표면의 인산염 및 Eu(III) 수착: 인(P) X-선 흡수분석(EXAFS)에 의한 연구)

  • Yoon, Soh-Joung;Bleam, William F.
    • Economic and Environmental Geology
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    • v.42 no.5
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    • pp.495-500
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    • 2009
  • Actinide sorption to the geological materials can reduce the mobility and bioavailability of radionuclides released to the environment through the development of nuclear weapons and nuclear energy. Under circumneutral pH conditions, actinide sorption can be enhanced by phosphate anions sorbed on oxide mineral surfaces as indicated by the sorption of trivalent lanthanide ions ($Ln^{3+}$), the chemical analog for trivalent actinide ions ($Ac^{3+}$). In this paper, we examined a ternary sorption system of trivalent europium ions ($Eu^{3+}$) sorbed onto boehmite (${\gamma}$-AlOOH) surfaces pre-sorbed with phosphate anions (${PO_4}^{3-}$), using extended X-ray absorption fine structure (EXAFS) spectroscopy. In the Eu-$PO_4$-boehmite ternary sorption system, $EuPO_4$ surface precipitates were formed as implicated by Eu $L_{III}$-edge EXAFS spectroscopy. Phosphorus K-edge EXAFS fingerprinting indicated a bidentate mononuclear surface complex formation of phosphate sorbed on boehmite surfaces as well as $EuPO_4$ surface precipitate formation.

Physicochemical Properties of Organic Sludge Discharged from an Industrial Complex in Ulsan (울산지역 산업단지에서 배출되는 유기성슬러지의 물리.화학적 특성)

  • Lee, Gang-Woo;Kim, Min-Choul;Lee, Jae-Jeong;Lee, Man-Sig;Kim, Ji-Won;Park, Hung-Suck;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1760-1767
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    • 2008
  • In this study, we analyzed the physical and chemical properties such as proximate analysis, ultimate analysis, heating values, and thermogravimetric analysis for the organic sludges discharged from an industrial complex in Ulsan. The average water, combustible, and ash content of organic sludges were 72.9, 18.5, and 8.6%, respectively. And according to the ultimate analysis of organic sludges, the C, O, H, N, and S compositions were 33.9, 26.4, 4.4, 4.4, and 0.6%, respectively. According to the results of investigating the lower heating values, 6 sludges were on the range of $1,500{\sim}2,000\;kcal/kg$ and 4 sludges were on the range of over 2,000 kcal/kg. Therefore, these 10 sludges could be directly applied to industries which try to use the energy by direct incineration.

A Study on the Application of GOCI to Analyzing Phytoplankton Community Distribution in the East Sea (동해에서 식물플랑크톤 군집 분포 분석을 위한 GOCI 활용 연구)

  • Choi, Jong-kuk;Noh, Jae Hoon;Brewin, Robert J.W.;Sun, Xuerong;Lee, Charity M.
    • Korean Journal of Remote Sensing
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    • v.36 no.6_1
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    • pp.1339-1348
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    • 2020
  • Phytoplankton controls marine ecosystems in terms of nutrients, photosynthetic rate, carbon cycle, etc. and the degree of its influence on the marine environment depends on their physical size. Many studies have been attempted to identify marine phytoplankton size classes using the remote sensing techniques. One of successful approach was the three-component model which estimates the chlorophyll concentrations of three phytoplankton size classes (micro-phytoplankton; >20 ㎛, nano-; 2-20 ㎛ and pico-; <2 ㎛) as a function of total chlorophyll. Here, we examined the applicability of Geostationary Ocean Colour Imager (GOCI) to the mapping of the phytoplankton size class distribution in the East Sea. A fit of the three-component model to a biomarker pigment dataset collected in the study area for some years including a large harmful algal bloom period has been carried out to derive size-fractioned chlorophyll concentration (CHL). The tuned three-component model was applied to the hourly GOCI images to identify the fractions of each phytoplankton size class for the entire CHL. Then, we investigated the distribution of phytoplankton community in terms of the size structure in the East Sea during the harmful Cochlodinium polykrikoides blooms in the summer of 2013.

The study of the Composition and Physico-chemcal Characteristics of MSW in urban and gangwon area (수도권 및 강원지역 도시고형폐기물의 조성과 물리·화학적 특성연구)

  • Lee, Keon-Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.3
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    • pp.65-74
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    • 2008
  • In this study, the composition and physico-chemical characteristics of municipal solid waste (MWS) which was treated in four different area were investigated. It is necessary to measure the characteristics of MSW to build a waste treatment and Refuse Derived Fuel (RDF) facility, the data-base and total managing of the landfill. It was found that the average density of solid wastes is in the range of $78.15-199.8kg/m^3$. This MSW was composed of 8.87% of food wastes, 38.8% of papers, 34.12% of plastics & vinyls, 7.16% of textiles, 0.96% of wood, 1.3% of rubber & leathers and others, respectively. Most of MSW are composed of food, paper and plastic waste and more than 94% was combustible waste. For three components, moisture is 17.38%, combustible component is 69.03% and ash is 6.24%. The chemical element has the high order of carbon, oxygen, hydrogen on the dry basis of wastes. And the low heating value of the MSW which is measured by calorimeter is calculated as 2973.8 kcal/kg and high heating value of the MSW is calculated as 5209.94 kcal/kg.

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The Study of Physico-chemcal Characteristics of Municipal Solid Waste (MSW) in Gangwon Area (강원지역 도시폐기물의 물리·화학적 특성 연구)

  • Lee, Keon-Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.2
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    • pp.101-111
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    • 2009
  • In this study, the physico-chemical characteristics of municipal solid waste (MWS) which was treated in gangwon area were investigated. It is necessary to measure the characteristics of municipal solid waste for build a waste treatment and RDF facility and for data-base and total managing of the landfill. It was found that the average density of solid wastes is in the range of $101.8{\sim}199.8kg/m^3$. This MSW was composed of 30.7% of food wastes, 36.3% of papers, 15.8% of plastics & vinyls, 1.9% of textiles, 3.2% of wood and 1.5% of rubber & leathers respectively. Most of MSW are composed of food, paper and plastic waste and the combustible waste is more than 90%. For three components, moisture is 44.6%, combustible component is 47.7% and ash is 7.7% respectively. The chemical elements are carbon, oxygen, and hydrogen on the dry basis of wastes. The low heating value of the MSW measured by calorimeter was obtained as 2,631 kcal/kg, and the high heating value of the MSW was obtained as 3,310 kcal/kg.

Study on the Spectrophotometric Determination of Rare Earth by Ternary Complex Using Xylenol Orange and Surfactant (Xylenol Orange와 계면활성제의 삼성분 착물에 의한 희토류원소의 분광광도법 정량에 관한 연구)

  • Cha, Ki-Won;Park, Chan-Il;Kang, Sun-Hee;Chang, Byung-Du
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.277-284
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    • 1994
  • The spectrophotometric determination of rare earth elements with XO was investigated in the presence of cetylpyridium chloride(CPC), dodecyltrimethylammonium bromide(DTMAB), cetyltrimetylammonium bromide (CTMAB), Triton X-100 at pH 6.2. The complex between XO and rare earth elements in the presence of cationic surfactants was very stable and more sensitive than in the absence of surfactants. The largest absorbance increase was provided by CTMAB, which was therefore chosen for determination of rare earth elements. REE-XO-CTMAB complex has absorption maxima at 618nm and obeys the Beer's law in the range of 0~0.5 ppm. Molar absorptivity was $1.5{\times}10^5mol^{-1}cm^{-1}l$.

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Spectrophotometric Determination of Scandium(III) with Eriochrome Cyanine R in the Presence of Cetyltrimethylammonium bromide (Cetyltrimethylammonium bromide에서 Eriochrome Cyanine R에 의한 스칸듐(III)의 분광광도법 정량)

  • Cha, Ki-Won;Park, Chan-Il;Kim, Jong-Whon
    • Analytical Science and Technology
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    • v.9 no.2
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    • pp.139-144
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    • 1996
  • The spectrophotometric determination method of scandium with eriochrome cyanine R(ECR) and the composition ratio of the complex were investigated in the presence of surfactants. The absorbance increase and red shift of maximum adsorption wavelength of Sc(III)-ECR complex were observed in cetyltrimethylammonium bromide (CTMAB), but those changes were not observed in the sodium dodecyl sulfate(SDS) and Triton X-100. A volume of 5ml of $1{\times}10^{-3}M$ ECR and 10ml of $2{\times}10^{-4}M$ CTMAB are necessary for the determination of $1{\times}10^{-7}{\sim}3.0{\times}10^{-6}M$ Sc(III) at pH 6.5. The apparent molar absorption coefficient of the Sc(III)-ECR-CTMAB, temary complex at 610nm is $5.6{\times}10^5mol^{-1}cm^{-1}L$ and its detection limit is $1.0{\times}10^{-7}M$. The binary complex composition of Sc(III)-ECR is 1:2 and the ternary complex composition of Sc(III)-ECR-CTMAB is 1:3:1.

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Separation of Functionalized Heterocyclic Compounds by High Performance Liquid Chromatography(I) (고성능 액체 크로마토그래피에 의한 기능성 헤테로고리화합물의 분리(I))

  • Lee, Kwang-PilI;Cho, Yun Jin;Lee, Young Cheol
    • Analytical Science and Technology
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    • v.10 no.6
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    • pp.408-417
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    • 1997
  • Normal phase or reversed phase liquid chromatographic separation of some structural isomers of functionalized heterocyclic compounds has been carried out by using several different columns and various mobile phases. The optimal experimental conditions for separation of structural isomers were found on a ternary solvent system including alcohol as a modifier. This polar modifier is preferentially adsorbed onto strong adsorption site, leaving a more uniform population of weaker site that then serve to retain the sample. This 'deactivation' of the adsorbent leads to a number of improvements in subsequent separations. The optimal mobile phase system of separation were found on normal phase on structural isomers. Retention mechanism of normal phase system was also studied depending on adsorption strength between solute and stationary phase of column. However, retention factors of reversed phase system were found on hydrophobic interaction with solvophobic effect.

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