• Title/Summary/Keyword: 삼성분계 가스

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Flame Extinguishing Concentrations of Mixed Gaseous Agents (가스계 혼합소화약제의 불꽃소화농도)

  • 김재덕;임종성;이윤우;이윤용
    • Fire Science and Engineering
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    • v.15 no.1
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    • pp.34-40
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    • 2001
  • Fire extinguishing efficiency of mixed gaseous agents were investigated by the cup-burner test and predicting by the model of flame extinguishing concentration. The binary mixed agents that tested were carbon dioxide/HFC-23, carbon dioxide/HCFC-22, carbon dioxide/HFC-227ea, carbon dioxide/HFC-125, carbon dioxide/FIC-13I1, Hexafluoropropylene/HFC-23 and ternary mixed agents were carbon dioxide/HFC-23/HFC-l34a, carbon dioxide/HFC-23/HFC-227ea, carbon dioxide/HFC-23/HFC-125. A model which contains the flame extinguishing concentration and composition of pure components predicted the flame extinguishing concentration of mixture well. This model was superior when each component of the mixture exhibit physical fire extinguishing performance.

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Measurement of Lower Flash Point for Ternary Mixture, n-Nonane+n-Decane+n-Dodecane System (삼성분계 혼합물인 n-Nonane+n-Decane+n-Dodecane 계의 하부인화점 측정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.31-36
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    • 2016
  • The flash point is one of the most important indicators of the flammability of liquid solutions. The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. In this study the flash points of ternary liquid solutions, n-nonane+n-decane+n-dodecane system, were measured using Seta flash closed cup tester. The measured values were compared with the calculated values using Raoult's law and empirical equation. The calculated data by empirical equation described the measured values more effectively than those calculated by Raoult's law.

Dry Etching of Flexible Polycarbonate and PMMA in O2/SF6/CH4 Discharges (O2/SF6/CH4 플라즈마를 이용한 플렉시블 Polycarbonate와 PMMA의 건식 식각)

  • Joo, Y.W.;Park, Y.H.;Noh, H.S.;Kim, J.K.;Lee, J.W.
    • Journal of the Korean Vacuum Society
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    • v.18 no.2
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    • pp.85-91
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    • 2009
  • There has been a rapid progress for flexible polymer-based MEMS(Microelectromechanical Systems) technology. Polycarbonate (PC) and Poly Methyl Methacrylate (PMMA), so-called acrylic, have many advantages for optical, non-toxic and micro-device application. We studied dry etching of PC and PMMA as a function of % gas ratio in the $O_2/SF_6/CH_4$ temary plasma. A photoresist pattern was defined on the polymer samples with a mask using a conventional lithography. Plasma etching was done at 100 W RIE chuck power and 10 sccm total gas flow rate. The etch rates of PMMA were typically 2 times higher than those of PC in the whole experimental range. The result would be related to higher melting point of PC compared to that of PMMA. The highest etch rates of PMMA and PC were found in the $O_2/SF_6$ discharges among $O_2/SF_6$, $O_2/CH_4$ and $SF_6/CH_4$ and $O_2/SF_6/CH_4$ plasma composition (PC: ${\sim}350\;nm/min$ at 5 sccm $O_2/5$ sccm $SF_6$, PMMA: ${\sim}570\;nm/min$ at 2.5 sccm $O_2/7.5$ sccm $SF_6$). PC has smoother surface morphology than PMMA after etching in the $O_2/SF_6/CH_4$ discharges. The surface roughness of PC was in the range of 1.9$\sim$3.88 nm. However, that of PMMA was 17.3$\sim$26.1 nm.

The Calculation of Flash Point for n-Nonane+n-Decane+n-Tridecane System by Raoult's Law and Multiple Regression Analysis (라울의 법칙과 다중회귀분석법에 의한 n-Nonane+n-Decane+n-Tridecane 계의 인화점 계산)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.22 no.2
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    • pp.52-58
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    • 2018
  • The flash point is one of the most important properties to characterize fire and explosion hazard of flammable liquid mixture. In this paper, the flash points of ternary liquid mixture, n-nonane+n-decane+n-tridecane system, were measured using Seta flash closed cup tester. The measured values were compared with the calculated values using Raoult's law and multiple regression analysis. The absolute average errors(AAE) of the results calculated by Raoult's law is $0.6^{\circ}C$. The absolute average errors of the results calculated by multiple regression analysis is $0.4^{\circ}C$. As can be seen from AAE, the calculated values based on multiple regresstion analysis were found to be better than those based on Raoult's law.

Characterizations of Cellulose Blend Films: Morphology, Mechanical Property, and Gas Permeability (셀룰로오스 블렌드 필름의 특성연구 : 모폴로지, 기계적 성질, 및 가스 투과도)

  • Jang, Seo-Won;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.63-69
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    • 2008
  • The mechanical properties and morphologies of cellulose blends with two different additives were compared. Poly (vinyl alcohol) (PVA) of ethylene glycol (EG) were used as additives in the formation of cellulose blends through the solution blending. The properties of blends were varied with the additive content in the polymer matrix. The ultimate tensile strength and initial modulus of the cellulose blends were highest for a blend PVA content of 30 wt% and for a blend EG content of 10 wt%, respectively. Ternary blended systems of composition of cellulose/PVA (70/30=w/w)/EG were also prepared by the solution blending method with different EG contents. The mechanical properties of these systems were found to be optimal for EG contents of up to 40 wt%. The mechanical properties of the cellulose ternary blend films were superior to those of the cellulose binary blend films. The oxygen permeability transmission rate ($O_2TR$) monotonically decreased with increasing EG content in the ternary blend films. Overall, the mechanical properties of the cellulose blend films were found to be better than those of pure cellulose films.

A study on permeation of $CO_2-N_2-O_2$ mixed gases through a NaY zeolite membrane under permeate evacuation mode (진공모드에서 NaY 제올라이트 막의 $CO_2-N_2-O_2$ 혼합기체의 투과거동 연구)

  • Jeong, Su Jung;Yeo, Jeong-Gu;Han, Moon Hee;Cho, Churl Hee
    • Membrane Journal
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    • v.23 no.5
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    • pp.352-359
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    • 2013
  • In the present study, $CO_2$ permeation through a hydrophilic NaY zeolite membrane was studied under permeate evacuation mode for $CO_2$ single gas, $CO_2-N_2$ and $CO_2-O_2$ binary mixtures, and $CO_2-N_2-O_2$ ternary mixture. It was reconfirmed that the $CO_2$ permeation was governed by surface diffusion and the $CO_2$ selectivity was induced from blocking effect of adsorbed $CO_2$ molecules. The $CO_2$ permeance measured in permeate evacuation mode was much lower than that done in He sweeping mode, but was comparable to that obtained under feed pressurization mode. The NaY zeolite membrane showed a considerable $CO_2$ separation for $14%CO_2-80%N_2-6%O_2$ mixture : $CO_2$ permeance was about $1{\times}10^{-7}mol/m^2secPa$ and $CO_2$ selectivity was more than 10. Therefore, it was concluded that NaY zeolite membrane was one of promising membranes for post-combustion CCS process.