• Title/Summary/Keyword: 삼성분계

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Evolution of Phase Morphology During Compounding of Ternary Blends in a Twin Screw Extruder (이축 압출기를 이용한 혼련에서 삼성분계 블렌드의 상구조 형성과정)

  • Kim, Hyungsu;Lee, Shi-Choon;D .Y. Yu;C. G. Gogos
    • The Korean Journal of Rheology
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    • v.10 no.4
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    • pp.247-255
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    • 1998
  • The morphological changes during melt compounding of ternary blends containing various combinations of acrylonitrile-butadiene-styrene(ABS), methyl methacrylate-butadiene-ethyl acrylate(MBE), styrene-acrylonitrile(SAM) copolymers, and poly(methyl methacrylate)(PMMA) as dispersed components in a fixed matrix of polycarbonate(PC) have been investigated. Depending on the composition of the blend, MBE particles and PMMA phase appear to locate at the PC-SAN interface under the influence of interfacial tensions and motion induced coalescence. The interfacial viscosity is found to be a critical factor that affects the amount of coalescence.

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Chloride Penetration Resistance of Ternary Blended Concrete and Discussion for Durability (삼성분계 혼합콘크리트의 염화물 침투 저항성 및 내구성에 대한 고찰)

  • Song, Ha-Won;Lee, Chang-Hong;Lee, Kewn-Chu;Kim, Jae-Hwan;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.439-449
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    • 2008
  • Mineral admixtures are used to improve the quality of concrete and to develop sustainability of concrete structures. Supplementary cementitious materials (SCM), such as silica fume (SF), granulated blast furnace slag (GGBS) and pulverized fly ash (PFA), are gradually recognized as useful mineral admixture for producing high performance concrete. The study on ternary blended concrete utilizing mainly three major mineral admixtures is limited and the study on durability and chloride induced corrosion resistance of ternary blended concrete is very few. This study examines the durability characteristics of the ternary blended concrete composed of different amount of the SCM with ordinary Portland concrete and the study experimentally focuses on corrosion resistance evaluation of ternary blended concrete subjected to chloride attack. In this study, 50% replacement ratio of mineral admixture to OPC was used, while series of combination of $20{\sim}40%$ GGBS, $5{\sim}15%$ SF and $10{\sim}45%$ PFA binder were used for chloride corrosion resistance test. This study concerned the durability properties of the ternary blended concrete including the corrosion resistance, chloride binding, chloride transport and acid neutralization capacity. It was found that the ternary blended concrete utilizing the SCM densified the pore structures to lower the rate of chloride transport. Also, increased chloride binding and buffering to acid were observed for the ternary blended concrete with chlorides in cast.

Adsorption Characteristics of Three-components Volatile Organic Compounds on Activated Carbonaceous Adsorbents (탄소흡착제에 의한 삼성분계 휘발성 유기화합물의 흡착특성)

  • Son, Mi Sook;Kim, Sang Do;Woo, Kwang Jae;Park, Hee jae;Seo, Man cheol;Lee, Si hun;Ryu, Seung Kon
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.669-675
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    • 2006
  • Toluene of aromatic compounds, MEK of ketones and IPA of alcohols were extremely used as VOCs (Volatile Organic Compounds) on the getting into step with industrial process. The adsorption characteristics of three component solvent vapors (Toluene-MEK-IPA) on the activated carbonaceous adsorbents such as AC, ACF and AC+ACF were investigated in a stainless steel fixed bed adsorption experimental apparatus in order to identify those carbons for eliminating and recovering solvent vapors from industrial emission sources. The used activated carbonaceous adsorbents were pelletized commercial activated carbon and activated carbon fiber. The breakthrough curves and adsorption capacity have been obtained at atmospheric pressure in a adsorption fixed bed. It has been found that non-polar and larger molecules have been adsorbed better than polar and smaller molecules. Especially, alcohols and ketones were poorly adsorbed due to competitive adsorbability in ternary mixture system. However, it could be overcome by employment of activated carbonaceous adsorbent which have different porosity distribution appropriately.

An Interface Reactions between Sintered Mn-Zn Ferrite and $SiO_2$-PbO-ZnO Bonding Glass (Mn-Zn 페라이트 소결체와 $SiO_2$-PbO-ZnO 삼성분계 봉착유리와의 계면반응)

  • 이대희;박명식;김정주;이병교;조상희
    • Journal of the Korean Ceramic Society
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    • v.37 no.12
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    • pp.1204-1211
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    • 2000
  • Mn-Zn 페라이트 소결체와 SiO$_2$-PbO-ZnO 삼성분계 유리와의 계면반응에서 페라이트와 유리에 각각 첨가된 ZnO가 계면반응에 미치는 영향을 조사하였다. SiO$_2$-PbO-ZnO 삼성분계 유리에 첨가된 ZnO 함량이 낮은 경우 페라이트와의 접합계면에서 생성되는 중간상은 Pb$_2$(Mn,Fe)$_2$Si$_2$O$_{9}$와 Pb$_{8}$(Mn,Fe)Si$_{6}$O$_{21}$의 고용체였으며, ZnO 농도가 증가함에 따라 중간상은 사라졌다. 유리속의 ZnO 성분이 증가함에 따라 페라이트 소결체 쪽의 계면부근에 Zn의 농도가 증가하는 특이한 분포가 나타났다. 이는 유리 속에 첨가된 Zn 이온의 높은 활동도로 인해 페라이트에 포함된 Zn 이온의 용해반응이 선택적으로 억제되어 나타난 것으로 생각된다. 페라이트에 첨가된 ZnO 함량이 낮은 경우 SiO$_2$-PbO 이성분계 유리와의 접합계면에서 페라이트의 용해에 따른 침식과 입계를 통한 유리의 침투가 심하게 일어났으며, ZnO 함량이 증가함에 따라 계면을 통한 상호확산과 반응이 억제되었다.

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Deep Sea Three Components Magnetometer Survey using ROV (ROV를 이용한 심해 삼성분자력탐사 방법연구)

  • Kim, Chang-Hwan;Park, Chan-Hong
    • Geophysics and Geophysical Exploration
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    • v.14 no.4
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    • pp.298-304
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    • 2011
  • We conducted magnetic survey using IBRV (Ice Breaker Research Vessel) ARAON of KORDI (Korea Ocean Research and Development Institute), ROV (Remotely Operated Vehicle) of Oceaneering Co. and three components vector magnetometer, at Apr., 2011 in the western slope of the caldera of TA25 seamount, the Lau Basin, the southwestern Pacific. The depth ranges of the survey area are from about 900 m to 1200 m, below sea level. For the deep sea magnetic survey, we made the nation's first small deep sea three components magnetometer of Korea. The magnetometer sensor and the data logger was attached with the upper part and lower part of ROV, respectively. ROV followed the planning tracks at 25 ~ 30 m above seafloor using the altimeter and USBL (Ultra Short Base Line) of ROV. The three components magnetometer measured the X (North), Y (East) and Z (Vertical) vector components of the magnetic field of the survey area. A motion sensor provided us the data of pitch, roll, yaw of ROV for the motion correction of the magnetic data. The data of the magnetometer sensor and the motion sensor were recorded on a notebook through the optical cable of ROV and the network of ARON. The precision positions of magnetic data were merged by the post-processing of USBL data of ROV. The obtained three components magnetic data are entirely utilized by finding possible hydrothermal vents of the survey area.

Flame Extinguishing Concentrations of Mixed Gaseous Agents (가스계 혼합소화약제의 불꽃소화농도)

  • 김재덕;임종성;이윤우;이윤용
    • Fire Science and Engineering
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    • v.15 no.1
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    • pp.34-40
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    • 2001
  • Fire extinguishing efficiency of mixed gaseous agents were investigated by the cup-burner test and predicting by the model of flame extinguishing concentration. The binary mixed agents that tested were carbon dioxide/HFC-23, carbon dioxide/HCFC-22, carbon dioxide/HFC-227ea, carbon dioxide/HFC-125, carbon dioxide/FIC-13I1, Hexafluoropropylene/HFC-23 and ternary mixed agents were carbon dioxide/HFC-23/HFC-l34a, carbon dioxide/HFC-23/HFC-227ea, carbon dioxide/HFC-23/HFC-125. A model which contains the flame extinguishing concentration and composition of pure components predicted the flame extinguishing concentration of mixture well. This model was superior when each component of the mixture exhibit physical fire extinguishing performance.

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Isobaric vapor-liquid equilibria for ternary and each corresponding binaries of the system n.Dodecane-1.Decanol-1.Dodecanol at 15 mbar (n.Dodecane-1.Decanol-1.Dodecanol 삼성분계 및 각 이성분계의 15 mbar 정합 기액평형)

  • 박소진;이태종
    • Journal of Energy Engineering
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    • v.2 no.3
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    • pp.308-314
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    • 1993
  • Both Vapor-liquid equilibrium data and boiling temperature have been measured for ternary and each corresponding binaries of n.dodecane-1.decanol-1.dodecanol mixture under constant pressure of 15 mbar. Measured vapor-liquid equilibrium data were correlated with the conventional g$\^$E/ model ; Margules, van Laar, Wilson, NRTL and UNIQUAC equations. Binary equilibrium data were thermodynamically tested by Redlich-Kister integral method and ternary data were also qualitatively checked by two point consistency test, suggested by McDermott-Ellis. Among the binary VLE data, only the system n.dodecane-1.decanol has minimum boiling azeotrope.

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The Fundamental Properties of High Fluidity Mortar with Activated Ternary Blended Slag Cement (활성화된 삼성분계 고유동 모르타르의 기초특성)

  • Bae, Ju-Ryong;Kim, Tae-Wan;Kim, In-Tae;Kim, Hyoung-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.74-82
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    • 2017
  • This research presents the results of the strength and drying shrinkage properties to study the effect of ground granulated blast furnace slag(GGBFS), fly ash(FA) and calcium sulfoaluminate(CSA) for activated ternary blended slag cement. The activated ternary blended cement(ATBC) mortar were prepared having a constant water-cementitious materials ratios of 0.4. The GGBFS contents ratios of 100%, 80%, 70% and 60%, FA replacement ratios of 10%, 20%, 30% and 40%, CSA ratios of 0%, 10%, 20% and 30% were designed. The superplasticizer of polycarboxylate type were used. The activator was used of 10% sodium hydroxide(NaOH) + 10% sodium silicate($Na_2SiO_3$) by weight of binder. Test were conducted for mini slump, setting time, V-funnel, water absorption, compressive strength and drying shrinkage. According to the experimental results, the contents of superplasticizer, V-funnel and compressive strength increases with an increase in CSA contents for all mixtures. Moreover, the setting time, water absorption ratios and drying shrinkage ratio decrease with and increase in CSA. One of the major reason for the increase of strength and decrease of drying shrinkage is the accelerated reactivity of GGBFS with alkali activator and CSA. The CSA contents is the main parameter to explain the strength development and decreased drying shrinkage in the ATBC.

Variation of Morphology and Its Effect on Physical Properties in Thermoplastic Ternary Blends (열가소성 삼성분계 블렌드의 구조 조절 및 구조 조절이 물성에 미치는 효과)

  • 차국헌
    • The Korean Journal of Rheology
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    • v.5 no.2
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    • pp.170-179
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    • 1993
  • 결정성 고분자/비결정성 고분자/충격보강재의 조합으로 이루어진 열가소성 삼성분계 블렌드의 미세구조 조절이 기계적 및 열적 거시물성에 미치는 영향을 살펴보았다. 결정성 고분자로는 나일론6를 비결정성 고분자로는 변성폴리페닐린 옥사이드(PPO)를 충격 보강재 로는 스티렌-에틸렌부틸렌-스티렌(SEBS) 삼중블록 공중합체를 사용하였고 비상용인 나일 론6와 변성 PPO 사이의 상용화를 위해 반능 상용화(reactive compatibilization)방법을 사용 하였다. 반응 사용화에 사용된 반응기로는 나일론의 말단기에 있는 친핵성기인 아민기와 반 응성이 높은 친전자성기인 무수말레인산(MAH)을 충격보강 고부 SEBS에 그라프트시켜 충 격보강 고무내의 SEBS-MAH의 함량을 증가시킴에 따라 처음에 PPO 분산상에 있던 고무 가 나일론 연속상으로 이동하는 현상을 관찰하였다. 이러한 충격보강 고부의 SEBS-MAH 함량 증가에 의한 PPO 분산상에서 나일론상으로의 이동이 내충격성의 향상 및 내열성의 저 하와 밀접한 관계가 있다는 것을 알았다.

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