• Title/Summary/Keyword: 산화작용

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Formation of Ceramic Thick Films by Applying EPD Method (EPD법을 적용한 세라믹계 분말재료의 후막 형성)

  • 소대화;전용우
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2004.05b
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    • pp.295-298
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    • 2004
  • 전기영동전착법은 도전성이 없는 산화물 또는 천연 분말을 알콜계 현탁용매와 전해질을 첨가시켜 전기이중층을 형성시킨 후 도전성을 갖는 모재에 미세 분말입자를 전착시킬 수 있는 기술이다. 본 논문은 이러한 전기영동법의 특성을 이용하여 세라믹계열의 분말을 모재에 전착시키는데 중요 요소인 기술적 제작 방법과 파라메터 등 복합적으로 작용되는 세라믹전착에 관한 내용을 연구하였다.

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Investigation on the Effect of Complexing Agents and Organic Additives in Trivalent Chromium Electroplating (3가크롬 도금에서 착화제 및 유기첨가제의 영향 연구)

  • Kim, Dong-Su;Lee, Ju-Yeol;Kim, Man;Gwon, Sik-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.81-82
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    • 2007
  • 3가크롬 도금액은 크롬원 (황화물계 또는 염화물계), 착화제, 완충제, 전도보조제, 산화방지제, 유기첨가제등으로 구성되어 있으며, 특히 착화제와 유기첨가제가 용액의 안정성 및 균일전착성에 미치는 영향이 크다고 보고되고 있다. 본 연구에서는 카르복시기의 작용기를 갖는 유기산을 착화제로 사용하고, 다양한 유/무기 첨가제의 조합 및 첨가량을 조절하여 크롬의 전착특성을 고찰하였다.

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Liquid-phase Microextraction Pretreatment Techniques for Analysis of Chemical Warfare Agents and Their Degradation Byproducts in Environmental Aqueous Samples (환경샘플 내 화학작용제 및 분해물질 분석을 위한 Liquid Phase Microextraction (LPME) 전처리 기법)

  • Kim, Dongwook;Chung, Wooyoung;Kye, Youngsik
    • Applied Chemistry for Engineering
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    • v.26 no.1
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    • pp.17-22
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    • 2015
  • International interests in chemical warfare agents (CWAs) have been increased recently because of the use of sarin (GB) in Syrian civil war which caused around 1,300 casualties in 2013. After exposing to natural environments, CWAs undergo hydrolysis or photodegrade to non-toxic degradation byproducts. Generally, CWAs and their degradation byproducts are present at very low concentration (e.g. several ppb), thus pretreatment processes including separation, extraction and concentration are required prior to any analyses. Liquid-liquid extraction and solid-phase extraction (SPE) are common techniques to pretreat environmental samples. Recently, a novel pretreatment method, liquid phase miecoextraction (LPME), has been applied to CWAs analysis, which could reduce amounts of solvent used but promote analytical efficiencies. Fundamental backgrounds of LPME and its application to CWAs analysis were reviewed.

Hydrothermal Alteration and Mineralization in the Granodioritic Stock of the Barton Peninsula, King George Island, Antarctica (남극 킹죠지섬 바톤반도 화강섬록암의 열수변질과 광화작용)

  • Hwang, Jeong;Lee, Jong Ik
    • Economic and Environmental Geology
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    • v.31 no.3
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    • pp.171-183
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    • 1998
  • Early Tertiary volcanics, volcanoclastics and granodiorite occur in the Barton Peninsula, King George Island, Antarctica. In the granodioritic stock and volcanic rocks, propylitic alteration characterized by actinolite, epidote, chlorite and calcite is widespread, and disseminations and veinlets of sulfide minerals such as pyrite, chalcopyrite and bornite are ubiquitious. The study on the hydrothermal alteration near granodioritic stock can be summarized as follows; (1) granodiorite intrusion is a small, high level stock associated with calc-alkaline volcanism, and have high copper content, (2) high temperature type of propylitic alteration and common occurrence of copper sulfides in and around granodiorite intrusion, (3) low ${\delta}^{34}S$ values of pyrites by oxidational conditions of sulfide deposition, (4) low ${\delta}^{34}S$ values of quartz and feldspar in the granodiorite, and isotopic non-equilibrium by hydrothermal alteration. It suggest that hyrothermal alteration and mineralization near granodioritc stock should be genetically related to granodiorite intrusion in the Barton Peninsula.

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The Role and Localization of Nitric Oxide Synthase in Neurogenic Inflammation of the Rat Airways (백서의 기도 선경성 염증에서 산화질소 합성효소(Nitric Oxide Synthase)의 역할과 분포)

  • Shim, Jae-Jeong;Lee, Sang-Yub;Lee, Sang-Hwa;Suh, Jung-Kyung;Kim, Chul-Hwan;Cho, Jae-Youn;In, Kwang-Ho;Yoo, Seo-Hwa;Kang, Kyung-Ho
    • Tuberculosis and Respiratory Diseases
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    • v.43 no.3
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    • pp.420-433
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    • 1996
  • Background : There have been many debates about the effects of nitric oxide on the neurogenic inflammation. The role of nitric oxide in the neurogenic inflammation of airways will be required a better understanding of the localization and types of nitirc oxide synthase(NOS) activity in the neurogenic inflammation of airways. Method : To investigate the role of nitric oxide in airway neurogenic inflammation, 1) the effects of neurokinin receptor antagonist (FK224) and nitric oxide synthase inhibitor, $N^{\omega}$-nitro-L-arginine (L-NNA) on plasma extravastion were evaluated in four groups of Sprague-Dawley rats ; sham operation group(sham NANC group), electrical vagal stimulation group(NANC2 group), intravenous pretreatment groups with FK224 (1mg/kg ; FK224 group), and L-NNA(1mg/kg ; L-NNA group) 15 minutes before vagal NANC stimulation. 2) NOS activity in trachea with neurogenic inflammation was localized by immunohistochemical stain. Immunohistochemical stain was performed by antibodies specific for inflammatory cells(iNOS), brain(bNOS), and endothelium (eNOS) on trachea obtained from sham NANC, NANC2, and FK224 groups. Results : The results are that plasma extravsation in neurogenic inflammation of rat airways was inhibited by FK224, but enhanced by L-NNA pretreatment(P<0.05). There was significantly increased infiltration of inflammatory cells in subepithelium of neurogenic inflammatory trachea, but the reduction of subepithelial infiltration of inflammatory cells was observed after pretreatment with FK224(P<0.05). Immunostaining with anti-iNOS antibody showed strong reactivity only in infiltrated inflammatory cells in neurogenic rat trachea, and these iNOS reactivity was reduced by pretreatment with FK224. bNOS immunoreactivity was significantly increased only in the nerves both of neurogenic inflammatory and FK224 pretreated trachea compared with sham NANC trachea(p<0.05). eNOS immunoreactivity was not significant change in endothelium in neurogenic inflammation of rat trachea. Conclusion : These results suggest that nitric oxide released from iNOS in infiltrated inflammatory cells has main role in neurogenic inflammation of rat trachea. The presence of bNOS immunoreactivity in the nerves indicates that nitric oxide may be released from the nerves in rat trachea with neurogenic inflammation.

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Effects of Inorganic-organic Additives on CO2 Adsorption of Activated Carbon (활성탄의 이산화탄소 흡착에 미치는 유무기계 첨가제의 영향)

  • Jo, Dong-Hyun;Cho, Ki-Sook;Park, Cheong-Gi;Kim, Sung-Hyun
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.885-889
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    • 2012
  • In this study, amine and metal oxide additives were investigated to improve $CO_2$ adsorption capacity of activated carbons (ACs). The characteristics of surface modified ACs were studied by X-ray photoelectron spectroscopy (XPS), $N_2$ adsorption, X-ray diffraction (XRD), and BET. Amine surface treatment decreased specific surface area and pore volume of ACs, but increased alkalinity by the incorporated nitrogen functional groups. Adsorption capacities of amine functionalized ACs was larger than original ACs, because basic group which can react with $CO_2$ was grafted on the ACs surface. Presence of copper oxides on ACs also enhances the carbon dioxide adsorption. The copper oxides could increase the adsorption rate of carbon dioxides due to the acid-base interaction (or electron acceptor-donor interaction). It was found that copper oxide loading was a promising method to improve the $CO_2$ adsorption capacity of ACs.

Effect of Egg Yolks from Laying Hens Intubated Astaxanthin on the Oxidation of Liver Microsome of Mouse (Astaxanthin처리 산란계로부터 생산된 난황이 Mouse Liver Microsome의 산화에 미치는 영향)

  • 김홍출;박숙자;김정곤;박철우;조용운;조현종;하영래
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.1
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    • pp.155-159
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    • 2002
  • Effect of the egg yolky from laying hens intubated, p.o., astaxanthin (designated AEY) on the oxidation of mouse liver microtome was investigated using female ICR mouse (6~7 weeks of age). Mice were adapted in a temperature- and humidity-controlled house for one week and randomly divided into 7 treatment groups (10 mice/cage/treatment). Mice were intubated p.o., AEY (50, 100 and 150 mg) or control egg yolk (CEY, 150 mg) every week for 3 weeks. BHT (5 mg) and e -tocopherol (50 mg) were fed to mice as positive control. At week 4, the liver microsome was prepared from sacrificed mice. Protein content of mouse liver microsome with AEY treatment was relatively higher than that with CEY treatment. AEY treatment remarkably lowered the content of unsaturated fatty acids including oleic acid and linoleic acid, but raised that of the saturated fatty acids including stearic acid. AEY group showed relatively higher antioxidative activity than CEY, when used Asc/F $e^{+2}$ or NADPH/F $e^{+2}$ as oxidant. Antioxidative activity of AEY was more effective than $\alpha$-tocopherol, but less effective than BHT.

Thrombin Detection with Tetrabromophenolphthalein Ethyl Ester Adsorbed on Aptamer-attached Conductive Polymer (전기전도성 고분자 위에 고정된 압타머에 흡착된 테트라브롬페놀프탈레인 에틸 에스테르를 이용한 트롬빈 검출)

  • Chung, Saeromi;Noh, Hui-Bog;Shim, Yoon-Bo
    • Journal of the Korean Electrochemical Society
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    • v.19 no.4
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    • pp.134-140
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    • 2016
  • An aptamer-based biosensor using a new redox indicator has been examined for the electrochemical detection of thrombin. The aptamer modified primary aliphatic amine was covalently immobilized onto poly-(5,2':5',2"-terthiophene-3'-carboxylic acid) (polyTTCA) layer. Tetrabromophenolphthalein ethyl ester (KTBPE) was interacted to aptamer and used as an electrochemical indicator. Prior to the detection, the oxidation reaction of KTBPE onto aptamer modified layer was also investigated using differential pulse voltammetry. The characterization of the final sensor (KTBPE/aptamer -polyTTCA) was performed by voltammetry, QCM, and ESCA. After binding of thrombin onto KTBPE/aptamer based sensor, the peak signal of KTBPE was gradually decreased. The sensor exhibited a dynamic range between 10.0 and 100.0 nM with the detection limit of $1.0{\pm}0.2nM$.

Geochemical Behavior and Occurrence of Surface Oxidized Materials on the Stone Cultural Heritage: Iksan Mireuksaji Stone Pagoda (석조문화재 표면 산화물의 산출상태와 지구화학적 거동: 익산 미륵사지 석탑)

  • Lee, Dong-Sik;Lee, Chan-Hee;Yang, Hee-Jae;Choi, Ki-Young
    • Economic and Environmental Geology
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    • v.40 no.4
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    • pp.375-387
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    • 2007
  • The Iksan Mireuksaji stone pagoda, designated as national treasure No. 11 in Korea, has been in the process of disassembling for reconstruction as part of the cultural heritage conservation program. The pagoda is mainly consisting of granite, which is relatively resistant to weathering. However, it has lost its original rock color due to various contaminants deposited at the surface since it exposed to the atmospheric environment long time. In this research, we categorized the secondary inorganic contaminants into the genetic type, and also quantitatively examined occurrences and types of pollutants in the oxidation area of the pagoda surface in which the area is clearly distinguished by naked eyes. Geochemical behavior of soluble pollutants through reaction experiments are demonstrated, and effective methods of cleaning for the conservation and scientific applicability of the surface cleaner are also studied.

Dispersion Stability of Pigments in Aqueous Solution of Anionic Oligo-Type Surfactants(Parts 2) - Dispersion of Red Iron Oxide or Titanium Dioxide - (올리고머형 음이온성 계면활성제 수용액에서 안료의 분산안정성(제2보) - 산화철이나 산화티티늄의 분산 -)

  • Lee, Hyang Woo;Lee, Jin Hee;Park, Heung Joe;Nam, Ki Dae
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.1-5
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    • 1999
  • The dispersing performance of oligomer-type anionic surfactants ($C_mD-Na$), cooligomers of diethylester maleate and alkylvinylether of different alkyl chain lengths or polymerization degree were studied on the aqueous suspension of iron dxide or titanium dioxide particles which are hydrophilic pigments. The dispersion behavior of oligomer-type surfactants for these dispersoids, although anion charges on the surface of pigments particles showed different dispersing properties, was dependent upon the side alkyl chain length. Oligomer-type surfactants having more than $C_8$ side alkyl chain exhibited large dispersing action for relatively hydrophobic ${\alpha}-Fe_2O_3$ and Anatase $TiO_2$ in the concentration range of more than 0.1% oligomer-type surfactant solutions.

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