• Title/Summary/Keyword: 산화성 첨가

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Accelerated Weathering Behavior of XLPE (가교폴리에틸렌의 촉진 내후성)

  • Lee, Chul Ho;Kim, Sang Wook
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.722-730
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    • 1994
  • The effects of antioxidant and carbon black on weatherability of crosslinked polythylene(XLPE) for electrical insulation were investigated. 16 compositions were prepared in other to determine the weathering resistance. Samples were exposed in xenon-arc lamp Weather-Ometer for 500, 1000, 1500, 2000 hours respectively. Tensile strength, elongation at break, dielectric strength and tan ${\delta}$ were measured to evaluate the weatherability of XLPE. The results indicated that the effect of carbon black was more prominent than antioxidant and synergistic effect, was observed when two additives were mixed.

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Effects of Metallaic Dialkyldithiophosphates on Lubricating Oil (금속 디알킬디티오인산염이 윤활유에 미치는 영향)

  • Moon Tak Jin;Kwon Oh Kwan
    • Journal of the Korean Chemical Society
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    • v.23 no.1
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    • pp.52-58
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    • 1979
  • Metallic dialkyldithiophosphates are widely used in lubricating oils as antioxidant and antiwear agents. Zinc DDTP are used most frequently in lubricating oil. Zinc, lead, tin and cobalt DDTP were prepared with primary and secondary alkyl groups. The effects of oxidation, thermal stability, metal corrosion and antiwear of each metallic DDTP prepared were studied. Based on the results, cobalt DDTP has a significant effect of antiwear on chrome alloy steel comparing with the other metallic DDTP. Also cobalt DDTP has a characteristic property of thermal sensitivity in its color, which was shown by the color change from brown to blue over a certain temperature. Another phenomenon obtained was that all metallic DDTP initiates the effect of antioxidation at the time of reaching to a certain effective acid concentration in lubricating oil.

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Effect of Garlic and Onion Juice Addition on the Lipid Oxidation, Total Plate Counts and Residual Nitrite Contents of Emulsified Sausage during Cold Storage (마늘즙 또는 양파즙 첨가가 유화형 소시지의 저장 중 지방 산화, 총 미생물수 및 아질산염잔존량에 미치는 영향)

  • Park, Woong-Yeoul;Kim, Young-Jik
    • Food Science of Animal Resources
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    • v.29 no.5
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    • pp.612-618
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    • 2009
  • The objective of this study was to determine the antioxidant and antimicrobial effects of garlic juice and onion juice in emulsified sausage during cold storage. The sausages were into five groups: control, 1% garlic juice (T1), 3% garlic juice (T2), 1% onion juice (T3), and 3% onion juice (T4). Each sausage type was tested in triplicate and assigned to one of four storage periods: 0, 7, 14 and 21 days. As storage time increased, the presence of garlic juice and onion juice resulted in decreased pH, residual nitrite value, and increased peroxide value, TBARS (thiobarbituric acid reactive substance) values, and total plate counts. The pH value, peroxide value, TBARS, residual nitrite and total plate counts were significantly decreased by the addition of garlic and onion juice relative to the control (p<0.05). Especially, T2 was significantly (p<0.05) more effective in delaying lipid oxidation compared to the other treatment groups. However, no significant difference (p<0.05) was found in total plate counts among all the formulations on day 0. Also, the use of garlic juice resulted in much better antioxidant and antimicrobial effects than the use of onion juice and the control. In conclusion, this study demonstrates that the addition of 3% garlic juice (T2) to emulsified sausages tended to improve antioxidative and antimicrobial effects during storage relative to the other treatment groups.

A Study on Productivity and Quality Characteristics of Wood Pellets by Larix Kaemferi Carr Sawdust with Adding Vegetable Oil and Ozonized Vegetable Oil (식물유 및 오존산화 식물유를 첨가한 낙엽송 목재펠릿의 생산성 및 품질특성에 관한 연구)

  • Lee, Eung-Su;Kang, Chan-Young;Seo, Jun-Won;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.4
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    • pp.359-369
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    • 2011
  • The study was carried out to investigate the quality characteristics of pellets manufactured with adding soybean oil, waste soybean oil, ozonized soybean oil and ozonized waste soybean oil to Larix kaemferi Carr sawdust. The characteristics of pellet included moisture contents, heating value, ash contents, apparent densities, durabilities, absorption ratio and elementary analysis. Moisture contents were shown 7.66~9.48% which satisfied the first grade (less than 10%) of quality standard of wood pellets announced by Korea Forest Research Institute. The heating value of the manufactured wood pellets in this study exceeded the first grade of quality standard (more than 4,300 kcal/kg) and it appeared that the pellets manufactured with adding oils and ozonized oils had more heating value than the control pellets. Ash contents 0.34~0.42% also passed the first grade (less than 0.7%) of quality standard and apparent densities were adequate for the first grade (640 kg/$m^3$) on the quality standard. Durabilities of the pellets manufactured with adding soybean oil and ozonized waste soybean oil were shown over the first grade (97.5 kg/$m^3$) of quality standard. In the general results of durabilities, the pellets manufactured with additives had better values than the control pellets. After 24 hours absorption ratio experiment, absorption ratio of pellets manufactured with additives also appeared much lower moisture absorption than the control pellets and they still had the same results after 5days absorption ratio experiment. Elementary analysis of the sulfur content was satisfied the first grade (less than 0.05%) of quality standard of wood pellets and the nitrogen content was also adequate for the first grade (less than 0.3%) of quality standard of wood pellets.

Effect of graphene oxide on mechanical characteristics of polyurethane foam (산화그래핀이 폴리우레탄 폼 기계적 강도에 미치는 영향)

  • Kim, Jong-Min;Kim, Jeong-Hyeon;Choe, Young-Rak;Park, Sung Kyun;Park, Kang Hyun;Lee, Jae-Myung
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.6
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    • pp.493-498
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    • 2016
  • In the present study, graphene oxide based polyurethane foams were manufactured as a part of the development process of mechanically strengthened polyurethane foam insulation material. This material is used in a liquefied natural gas carrier cargo containment system. The temperature of the containment system is $-163^{\circ}C$. First, graphene oxide was synthesized using the Hummers' method, and it was supplemented into polyol-isocyanate reagent by considering a different amount of graphene oxide weight percent. Then, a bulk form of graphene-oxide-polyurethane foam was manufactured. In order to investigate the cell stability of the graphene-oxide-polyurethane foam, its microstructural morphology was observed, and the effect of graphene oxide on microstructure of the polyurethane foam was investigated. In addition, the compressive strength of graphene-oxide-polyurethane foam was measured at ambient and cryogenic temperatures. The cryogenic tests were conducted in a cryogenic chamber equipped with universal testing machine to investigate mechanical and failure characteristics of the graphene-oxide-polyurethane foam. The results revealed that the additions of graphene oxide enhanced the mechanical characteristics of polyurethane foam. However, cell stability and mechanical strength of graphene-oxide-polyurethane foam decreased as the weight percent of graphene oxide was increased.

Effects of Light and Water Soluble Proteins on the Lipid Oxidation of Meat Emulsion Model System during Refrigerated Storage (광 조사 및 차단 조건에서의 고기모형 유화물의 지방산화에 미치는 수용성 단백질의 효과)

  • Park, Hyung-Il;Chung, Myung-Sub;Lee, M.
    • Korean Journal of Food Science and Technology
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    • v.29 no.3
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    • pp.395-399
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    • 1997
  • Meat model emulsions ware prepared with salt-soluble protein and soybean oil. Effects of water-soluble protein (WSP) on the meat model emulsion treated with/without BHT during 8 day storage $5^{\circ}C$ under both dark and light illumination were studied by measuring POV and TBA. An emulsion without BHA and WSP was used as a control. Under light storage, there was no significant difference in peroxide values between the control and the sample treated with BHA except the 2nd day of storage. However, TBA values of the sample treated with BHA were significantly (p<0.05) lower than those of control except the 4th day of storage. TBA and POV of the samples treated with WSP and WSP + BHA were higher than control after 4th day of storage under light. That is, water soluble protein, which was composed mainly of myoglobin, increased lipid oxidation under light storage. The similar trends were also shown in the samples stored under dark. These results suggested that acceleration of lipid oxidation of the meat model emulsions by water soluble protein (WSP) under both light and dark might not be due to the singlet oxygen formation, but due to superoxide anion formed.

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Inhibitory Effects of Functional Sujeonggwa (Cinnamon Drink) on Lipid Peroxidation and DNA Damage in Diet-Induced Hypercholesterolemic ApoE Knockout Mice (고콜레스테롤혈증 ApoE Knockout 마우스에서 기능성 수정과의 지질과산화 및 산화적 DNA 손상 억제 효과)

  • Park, Eunju;Baek, Aran;Kim, Mijeong;Lee, Seon Woo;Lee, Eunji;Choi, Mi-Joo;Lee, Jeehyun;Song, Yeong Ok
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.11
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    • pp.1627-1634
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    • 2014
  • The recipe for sujeonggwa, a Korean traditional sweet drink containing cinnamon, ginger, sugar, or honey, was modified by replacing sugar with alternative sweeteners [stevia or short-chain frutooligosaccharide (scFOS)] in order to improve the health functionality of sujeonggwa. The aim of this study was to evaluate the effects of modified sujeonggwa on lipid peroxidation and oxidized DNA damage in diet-induced hypercholesterolemic ApoE knockout mice. Hypercholesterolemia was induced in 6-week-old male mice by administration of a high cholesterol diet (1.25% cholesterol, 0.5% cholic acid, and 10% coconut oil) for 4 weeks, after which mice were divided into five groups: sucrose solution-fed control group, sujeonggwa containing sucrose group, sucrose+stevia group, sucrose+stevia+scFOS group, and commercially available sujeonggwa group as a positive control. After 6 weeks, sujeonggwa supplementation resulted in reduced hepatic thiobarbituric acid reactive substances (TBARS), regardless of sweetener type. However, reduction of hepatic TBARS by commercially available sujeonggwa was insignificant. Both endogenous and $H_2O_2$-induced DNA damage in hepatocytes and splenocytes were significantly reduced only in the sujeonggwa containing stevia group compared to the sucrose-fed control group. There were no significant effects of sujeonggwa supplementation on total radical trapping potential, lipid peroxidation, or DNA damage in blood. These results suggest that sujeonggwa has protective effects against hepatic lipid peroxidation and DNA damage in hepatocytes or splenocytes from diet-induced hypercholesterolemic ApoE knockout mice, and the type of sweetener should be modified to improve the health benefits of sujeonggwa.

The Oxidation Stability of Soybean, Palm Fish oil and Lard affected by Crude Gingerol (대두유. 팜유, 돈지 및 어유의 산화 안정성에 미치는 Crude gingerol의 영향)

  • 백숙은
    • Korean journal of food and cookery science
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    • v.9 no.4
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    • pp.298-302
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    • 1993
  • The Crude ginerol from ginger was collected to investigate the possibility of application to food products as a natural antioxidant. The antioxidant activity of gingerols according to fatty acid composi-tion of several oils, were examined by measuring peroxide value(POV). The induction period(If) of fish oil, sdybean oil, lard and palm oil was 5.0, 17.0, 38.4 and 57.6 hours respectively by measuring POV during storge at $85^{\circ}C$. The relative antioxidant effectiveness(RAE) of gingerol group was lard ; 219, soybean oil; 176, fish oil; 160 and palm oil; 146%, while the RAE of'BHT group was lard; 238, palm oil; 158, soybfan oil; 132 and fish oil; 122%.

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Physicochemical properties and antioxidant activities of baked waffle added with cinnamon powder (베이킹 열처리로 제조된 계피 첨가 와플의 이화학적 특성과 산화방지활성)

  • Yeom, Juhee;Surh, Jeonghee
    • Korean Journal of Food Science and Technology
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    • v.49 no.5
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    • pp.494-501
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    • 2017
  • Waffles with cinnamon powder added in different proportions (0-12% of wheat flour) were baked to investigate the effects of baking on the physicochemical properties and antioxidant activity. Compared with the control without cinnamon, baking loss was lower in waffles with cinnamon, which led to a decrease in waffle hardness. This was attributable to the higher water-holding capacity of cinnamon than wheat flour. With the increase in the amount of cinnamon, the springiness, resilience, and cohesiveness of the waffle decreased, which was thought to result from the decrease in gluten formation by the proportional decrease of wheat flour. The total reducing capacity and DPPH radical scavenging activity of the waffle was significantly increased. This was substantially in agreement with the observations that cinnamon had an appreciable total reducing capacity and radical scavenging activity that were unchanged by heat treatment. This indicates that the antioxidant functionality of cinnamon could be effectively added to thermally processed food.