• Title/Summary/Keyword: 산처리법

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Physicochemical properties and sintering behavior of pottery stone as a raw material in porcelain products (국내 도석 광물의 물리화학적 물성 및 도자기 원료로서 소결 특성 평가)

  • Kim, Jong-Young;Kim, Ung-Soo;Hwang, Kwang-Taek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.5
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    • pp.192-202
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    • 2019
  • Physicochemical properties and sintering characteristics of pottery stone (Taebaek, Haenam, Aphae, Haengnam) were evaluated as a raw material for porcelain products. Due to acid leaching procedure, the concentration of iron oxide ($Fe_2O_3$) was decreased to < 1.0 wt%, which affects the whiteness of sintered samples. Mean particle size of acid leached samples is $5.7{\sim}10{\mu}m$ with narrow particle size distribution (PSD), which is lower than that of the pristine ($8{\sim}18{\mu}m$) with broad PSD. According to phase analysis by X-ray diffraction, most of pottery stones (PS) have Quartz phase as a main phase with Pyrophyllite as a second phase, however, Haenam PS shows halloysite phase. The absorption rate was in order of Taebaek (A, B, C)~Aphae (A, B) < Taebaek (Special A) < Haengnam < Haenam, and the samples sintered in reductive atmosphere showed lower absorption rate. This result might be due to the concentration of feldspar contained in PS, working as a flux in sintering process. Comparing the color of the sintered samples, the whiteness of refined PS (Taebaek special A, Haenam, Hangnam) is higher than acid leached PS (Taebaek A/B/C, Aphae A/B). The whiteness (L*) for refined PS is 95~97 %, which is higher than acid leached (82~96 %). This might be due to lower iron oxide concentration of the refined PS (0.11~0.58 %) than those of the acid leached PS (0.41~1.91 %) even though most of iron oxide was removed by acid leaching.

Characterization of Humic Acid in the Chemical Oxidation Technology(I) - Characteristics by Photocatalytic Oxidation Process - (화학적 산화법에 의한 부식산의 분해 처리기술에 관한 연구(I) - 광산화공정을 통한 부식산의 분해특성 분석 -)

  • Kim, Jong Boo;Rhee, Dong Seok
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.234-240
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    • 2000
  • The efficiency of Photocatalytic Oxidation Process were investigated for the treatment of Aquatic Humic Substances (AHS). In UV-only system, pH 7-9 was the optimum pH range for TOC removal, and alkali range was the optimum pH for absorbance decrease. In UV/$TiO_2$ system, the optimum $TiO_2$ dosage was 50ppm and over 50ppm of $TiO_2$ dosage was not effective for removal of AHS. In UV/$H_2O_2$ system, optimum $H_2O_2$ dosage was 20mM, when over 20mM dosage, removal of TOC (Total Organic Carbon) and absorbance was decreased. Radical scavenger affected on the photo-oxidation of AHS. Removal rate of TOC and absorbance was decreased by addition of carbonate ions and TOC removal was more effected than that of absorbance.

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Interblock Information from BIBD Mixed Effects (균형불완비블록설계의 혼합효과에서 블록간 정보)

  • Choi, Jaesung
    • The Korean Journal of Applied Statistics
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    • v.28 no.2
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    • pp.151-158
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    • 2015
  • This paper discusses how to use projections for the analysis of data from balanced incomplete block designs. A model is suggested as a matrix form for the interblock analysis. A second set of treatment effects can be found by projections from the suggested interblock model. The variance and covariance matrix of two estimated vectors of treatment effects is derived. The uncorrelation of two estimated vectors can be verified from their covaraince structure. The fitting constants method is employed for the calculation of block sum of squares adjusted for treatment effects.

수세법과 pH 조절법에 의한 닭가슴살 surimi의 품질 특성

  • Park, Gi-Hun;Kim, In-Jin;Ha, Ji-Hui;Gang, Seok-Mo;Kim, Il-Seok;Jin, Sang-Geun
    • Proceedings of the Korean Society for Food Science of Animal Resources Conference
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    • 2005.05a
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    • pp.155-158
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    • 2005
  • 닭가슴살을 이용해서 수리미 제조 시 4회 수세한 대조구, pH 3.0으로 산 처리한 T1, pH 11.0으로 알카리 처리한 T2로 하여 그 품질 특성을 비교한 결과 일반성분에서 수분, 조단백질과 염용성단백질 및 수율은 대조구에 비하여 pH 조절법으로 한 두 구가 높았으며, 조지방은 T2가 다른 두 구에 비하여 높았다. pH, 보수력, 파괴강도, 변형값은 처리 간에 유의적인 차이를 보이지 않았다. 전단가는 T2가 가장 높고, T1, 대조구 순이었다. $L{\ast}$값은 T2가 다른 두 구보다 낮았으며, $a{\ast}$값은 T1이 다른 두 구에 비하여 낮았다. $b{\ast}$값은 대조구가 가장 높고, T2가 가장 낮았다. 조직감에서 파쇄성 및 경도는 처리 간에 유의적인 차이를 보이지 않았으며, 응집성은 T1이 다른 두 구보다 낮았으며, 탄력성과 부착성은 대조구에 비하여 T1과 T2가 높았다. 검성은 대조구와 T1에 비하여 T2가 높았다. 조직감의 전 항목에서 T2 가 가장 높았다. 관능검사 결과 외관과 맛은 T1이 가장 높고, 대조구가 가장 낮았다. 색, 향, 다즙성, 연도 및 전체적인 기호도는 처리 간에 유의적인 차이가 없었다.

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Bias-corrected imputation method for non-ignorable nonresponse with heteroscedasticity in super-population model (초모집단 모형의 오차가 이분산일 때 무시할 수 없는 무응답에서 편향수정 무응답 대체)

  • Yujin Lee;Key-Il Shin
    • The Korean Journal of Applied Statistics
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    • v.37 no.3
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    • pp.283-295
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    • 2024
  • Many studies have been conducted to properly handle nonresponse. Recently, many nonresponse imputation methods have been developed and practically used. Most imputation methods assume MCAR (missing completely at random) or MAR (missing at random). On the contrary, there are relatively few studies on imputation under the assumption of MNAR (missing not at random) or NN (nonignorable nonresponse) that are affected by the study variable. The MNAR causes Bias and reduces the accuracy of imputation whenever response probability is not properly estimated. Lee and Shin (2022) proposed a nonresponse imputation method that can be applied to nonignorable nonresponse assuming homoscedasticity in super-population model. In this paper we propose an generalized version of the imputation method proposed by Lee and Shin (2022) to improve the accuracy of estimation by removing the Bias caused by MNAR under heteroscedasticity. In addition, the superiority of the proposed method is confirmed through simulation studies.

Effects of Various Pretreatment Methods on Physicochemical and Nutritional Properties of Carrot (다양한 전처리 방법에 따른 당근의 이화학 및 영양학적 특성 분석)

  • Kim, Kwang-Il;Hwang, In-Guk;Yoo, Seon-Mi;Min, Sang-Gi;Choi, Mi-Jung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.12
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    • pp.1881-1888
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    • 2014
  • Pre-thermal treatment is important to minimize quality changes during main cooking or storage. In this study, to optimize pre-thermal treatment of carrots, three types of pre-thermal treatments were applied to carrots and quality changes such as physicochemical, nutritional, or sensory properties were observed. Washed and sliced carrots were thermally treated by hot-water immersion ($100^{\circ}C$, 1~10 min), steaming ($100^{\circ}C$, 1~10 min), and stir-frying with oil (10~80 sec). Carrot tissue was maintained until 2 min hot-water immersion or steaming, and they were damaged by just 30 sec of stir-frying. Color and hardness were significantly affected by treatment time and temperature. Color was completely changed after 5 min and 7 min by hot-water and steam treatments, respectively. Hardness decreased to 44% compared with fresh carrot (4,500 g) after 1 min, 3 min, and 20 sec of hot-water, steam, and stir-frying, respectively. For nutritional changes, ascorbic acid, organic acid, and peroxide activity were reduced by all treatments compared with fresh carrot. Especially, succinic acid was dramatically reduced by hot-water treatment. Otherwise, free sugar contents were increased with greater treatment time in all samples. In this study, pre-thermal treatment of carrot was optimal at 2 min steaming treatment.

A study on hyperspectral image processing for geographical origin discrimination of domestic and chinese rice (국내산과 중국산 쌀의 원산지 판별을 위한 초분광 영상 처리에 관한 연구)

  • Mo, Changyeun;Lim, Jongguk;Kim, Giyoung;Kwon, Sung Won;Lim, Dong Kyu;Min, Hyun Jung;Kwon, Kyungdo
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.147-147
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    • 2017
  • 우리나라에서는 수입 개방화 추세에 따라 공정한 유통질서 확립하고 국내 생산자와 소비자를 보호하기 위하여 원산지 표시제가 시행되고 있다. 그러나 수입 농산물과 국산 농산물의 큰 가격차이로 인하여 원산지를 허위 표시하는 경우가 증가하고 있다. 특히 쌀 관세화 전환 의무에 따른 수입산 쌀 증가하고 있으며 단립종과 중립종 수입산 쌀은 국내산 쌀과 외관이 유사하여 육안식별이 어려워 국내산 쌀로 둔갑할 우려가 있다. 이에 신속하고 비파괴적으로 쌀의 원산지를 판별할 수 있는 기술 개발이 요구되고 있다. 따라서 본 연구에서는 국내산 쌀과 중국산 쌀의 원산지를 신속하게 판별가능한 영상 처리기술을 개발하였다. 쌀은 국내에서 생산된 중립종 50점과 중국에서 생산된 단립종 및 중립종 51점이 수집되어 사용되었다. 쌀의 분광 영상은 초분광 가시광 및 근적외선 영상 시스템을 이용하여 측정하였다. 이 시스템은 할로겐-텅스텐 라인광, 시료 이송부, 초분광 영상 획득부로 구성되어 있다. 텅스텐-할로겐 라인광은 $15^{\circ}$ 각도로 대칭으로 시료에 조사되고 400 ~ 1000 nm 파장 영역의 반사광 영상 스펙트럼이 측정되었다. 초분광 영상 데이터는 광에 노출되지 않은 암실에서의 파장별 영상과 반사율이 99% 이상인 기준판의 파장별 영상을 이용하여 교정되었다. 부분최소제곱회귀법을 이용하여 쌀 원산지 판별모델 식을 개발하였고, 이 판별 모델식을 교정된 초분광 영상에 적용하여 영상처리 판별 모델을 개발하였다. 그 결과, 원산지 판별정확도가 97.4% 이상으로 나타났으며, 국내산과 중국산 쌀의 원산지 판별이 가능하였다.

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Biotreatment Technologies for Air Pollution Control (생물학적 처리기술을 이용한 대기오염 제어)

  • Won, Yang-Soo
    • Clean Technology
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    • v.13 no.1 s.36
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    • pp.1-15
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    • 2007
  • Biological treatment is a relatively recent air pollution control technology in which off-gases containing biodegradable odors and volatile organic compounds(VOCs) are vented through microbes. It is a promising alternative to conventional air pollution control methods. Bioreactors for air pollution control have found most of their success in the treatment of dilute and high flow waste air streams containing VOCs and odor compounds. They offer several advantages over traditional technologies such as incineration or adsorption. These include lower treatment costs, absence of formation of secondary pollutants, no spent chemicals, low energy demand and low temperature treatment. The three most widely used technologies are described, namely biofiltration, biotrickling filtration, bioscrubbing. The most widely used bioreactor for air pollution control is biofilter, but it has several limitations. In the past years major progress has been accomplished in the development of vapor phase bioreaction systems, for solving problems of biofilter. Biotrickling filters are more complex than biofilters, but are usually more effective, especially for the treatment of compounds which are difficult to degrade or compounds that generate acidic by-products. This, paper reviews fundamental and theoretical/practical aspect of air pollution control in biofilter, biotrickling filter and bioscrubber, focusing more extensively on biotrickling filtration. Special emphasis is given to the operating parameters and the factors influencing performance for air pollution control, and cost estimation in biotreatment technologies.

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RF-Plasma를 이용한 Ru-Cr 금속합금 분말 제조 및 특성

  • Ho, Jong-Hwan;Im, Seong-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.211-211
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    • 2013
  • Ru-Cr은 차세대 반도체 메모리(RAM, MRAM, FeRAM), 헤드(MR, TMR), 캐피시터의 웨이퍼 등에 전극층이나 시드층 형성을 위해 스퍼터링 타겟으로 제조되며, IT산업이 발달함에 따라 수요가 증가하고 있다. 기존의 스퍼터링 타겟은 산처리와 주조와 같은 습식법이 주를 이루었으나, 긴 제조시간과 강산사용의 위험성화 강산폐유의 처리가 문제되고 있다. 최근에는 습식공정을 보완하기 위한 건식법의 연구가 진행 중이며, 합금소재에 대한 건식법의 연구가 필요하다. 본 연구에서는 폐 Ru-Cr 금속합금 스퍼터링 타겟을 Hammer-mill, jet-mill 등 건식으로 분쇄하고 RF-Plasma를 이용하여 소결에 용이한 구형, 고순도 Ru-Cr금속합금분말을 제조하였다.

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Fatty Acid Composition Analysis of Major Oil Crops by One-Step Extraction/Methylation Method (일단계 추출 및 메칠화법에 의한 유료작물의 지방산 분석)

  • 김진경;김남희;방진기;이병규;박충범;이봉호
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.45 no.3
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    • pp.211-215
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    • 2000
  • Lipid extraction preceding fatty acid methyl esters preparation for gas-liquid chromatography is time-consuming and cumbersome. We performed one-step extraction/methylation method with a mixture of methanol-heptane-benzene-DMP-H$_2$SO$_4$ without prior fat extraction. The simultaneous digestion and lipid transmethylation takes place at 8$0^{\circ}C$ in a single phase. After cooling till room temperature, two phases are formed. The upper one of the phases contains the fatty acid methyl esters ready for GLC. The fatty acid composition of major industrial crops obtained by the one step extraction/methylation method (method 1 and 2) was almost identical with the fatty acid composition of the pure fats extracted with hexane by the Soxtec instrument (method 3). Due to its simplicity, speed, and reduced organic solvent the one-step extraction/methylation method (method 1 and 2) should be useful to determine overall fatty acid composition, especially in situations where many samples have to be analyzed.

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