• Title/Summary/Keyword: 산소결핍

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Geological and Geochemical Studies on the Late Quaternary Sedimentary Environment of the Southwestern Ulleung Basin, East Sea. (울릉분지 남서부 해역의 제4기 후기 퇴적환경에 대한 지질${\cdot}$지화학적 연구)

  • 김일수;박명호;이영주;류병재;유강민
    • Economic and Environmental Geology
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    • v.36 no.1
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    • pp.9-15
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    • 2003
  • Two piston cores, obtained from the southwestern Ulleung Basin in East Sea, were analyzed to study the geochemical characteristics of the late Quaternary sediments and to detect any changes in sedimentary environment. The results show that the capacity of Total Organic Carbon is remarkably higher (average 1.8%) than that known from general open-sea. According to tephrochronology from known eruption ages, the sedimentation rates are high, ranging from 12.1 to 14.9 cm/kyr. The ratios of nitrogen and TOC (average 6.18-7.42) imply that the organic matter in the study area would be of oceanic origin. The correlation between sedimentation rates and sulfur contents suggests that the study area may be on the whole anoxic and somewhat high in primary productivity. During the Termination 1, inflows of organic matters were high. The sedimentary environments are characterized by rapid rates of sedimentation, and high anoxic values were compatible with accumulation of organic matters.

Variation of Electronic and Magnetic: Properties in Oxygen-deficient TiO2-δ Thin Films by Fe Doping (산소 결핍된 TiO2-δ 박막의 철 도핑에 의한 전기적, 자기적 특성 변화)

  • Park, Young-Ran;Kim, Kwang-Joo;Park, Jae-Yun;Ahn, Geun-Young;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.45-50
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    • 2006
  • Oxygen-deficient anatase and rutile titanium dioxide $(TiO_{2-\delta})$ thin films were prepared by a sol-gel method and their structural, electronic, and magnetic properties were investigated. Both anatase and rutile $TiO_{2-\delta}:Fe$ Fe films exhibited ferromagnetism at room temperature for a limited range of Fe doping. For the same amount of Fe doping, the anatase sample exhibited a higher magnetic moment than the rutile one. Result of conversion electron Mossbauer spectroscopy measurements indicates that $Fe^{3+}$ ions substituting the octahedral $Ti^{4+}$ sites mainly contribute to the room-temperature ferromagnetism. Some of the anatase $TiO_{2-\delta}:Fe$ films exhibited p-type character but the observed feromagnetism turns out to be independent of the hole concentration. The room-temperature ferromagnetism can be explained in terms of a direct ferromagnetic coupling between two neighboring $Fe^{3+}$ ions via an electron trapped in oxygen vacancy in $TiO_{2-\delta}:Fe$.

Photodegradation Characteristics of Oxygen Vacancy-fluorinated WO3 Photocatalysts Controlled by Plasma and Direct Vapor Fluorination (플라즈마 및 직접 기상 불소화에 의해 제어된 산소결핍 불소화 WO3 광촉매의 광분해 특성)

  • Lee, Hyeryeon;Lee, Raneun;Kim, Daesup;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.159-165
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    • 2022
  • To enhance the photocatalytic activities of WO3 photocatalysts, fluorine doping was performed to induce the oxygen vacancies. Both plasma and direct vaper fluorination were carried out for fluorine doping, and photocatalytic activities were examined by using methylene blue dye. Oxygen vacancies of the plasma and direct vaper fluorinated WO3 photocatalysts were measured to be 14.65 and 18.59%, which increased to about 23 and 56% at pristine WO3 photocatalysts. The degradation efficiency of methylene blue was also determined about 1.7 and 3.4 times higher than pristine WO3 photocatalysts, respectively, depending on oxygen vacancies increased. In addition, it was confirmed that the bandgap process energy decreased from 2.95 eV to 2.64 and 2.45 eV after fluorine doping. From this result, it is considered that the direct vaper fluorination has an advantage for increasing the photocatalytic activities of WO3 compared to that of the plasma fluorination.

Corrosion resistance of gallium-doped zinc oxide film depending on the hydrogen content (수소가스 함유량에 따른 Gallium-doped Zinc Oxide(GZO) 박막의 내식성 평가)

  • Jo, Su-Ho;Choe, In-Gyu;Kim, Sang-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.188-188
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    • 2016
  • GZO 박막은 상업적으로 사용되는 ITO를 경제적으로 대체할 수 있는 유망한 투명 전도 물질이며, 인체에 무해하고, 공급이 쉬우며, 화학적으로 안정하다. 특히, CIGS와 같은 광전변환 소자 전극에서는 부식 저항이 매우 중요한데, 습한 환경에서 견뎌낼 수 있다는 장점이 있다. GZO는 3가 갈륨이 2가 아연에 도핑된 n타입의 반도체 물질이다. 그리고 육각형의 황화아연 물질의 전기 전도도는 산소 결핍에 매우 의존한다. GZO의 수소는 산소 결핍 집중에 영향을 끼친다. 따라서 이 연구에서는 RF 마그네트론 스퍼터링 실험 동안 수소 함유량을 다양화 시키고, 면 저항, 광 투과도, 부식저항의 효과를 조사한다. 수소량이 증가할수록, 면 저항은 향상되어지고, 특정 지점을 넘으면 감소한다. 분극 실험에 의해 측정되어진 부식 저항은 박막의 미세조직과 결정립계의 특성에 더 의존되어진다. 훨씬 더 많은 수소를 함량한 비정질이 부식 저항성에 있어서 유효한 차이를 나타내지 못하는 동안 결정 내에서 많은 수소를 지닌 작은 결정의 결정립계는 낮은 분극저항, 즉 낮은 부식 저항성의 결과를 도출한다.

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High Density Cultivation of Methylobacillus sp. SK1 in Fed-Batch System (Methylobacillus sp. SK1의 고농도 유가배양)

  • 이형춘;이계호김시욱
    • KSBB Journal
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    • v.5 no.3
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    • pp.269-277
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    • 1990
  • Methylobacillus sp. SK1, an obligate methylotroph, was cultivated in a fed-batch culture using DO as a methanol feeding indicator with a micro computer-aided control system. While 2.07g/l of cell density was obtained after 13 hr in the batch culture (initial methanol concentration: 1.0%(v/v)),45.3g/l of cell density was obtained after 17 hr by feeding methanol and metal ions in the fed-batch culture with oxygen supply. The high-density biomass was obtained in short cultuivation time by fed-batch culture with feedback control, and consequently the biomass productivity was significantly increased. It was mainly due to extension of logarithmic growth period by methanol feeding without methanol inhibition and intensive aeration without DO limitation with microcomputer-aided control system.

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A Study on Application of Air-Ventilation System Depending on Oxygen-Density in a Vehicle (자동차 실내 산소농도에 따른 환기설정에 관한 연구)

  • 허성관;박동은;권택진;최종탁
    • Journal of Korea Society of Industrial Information Systems
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    • v.4 no.4
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    • pp.154-163
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    • 1999
  • This paper perform the experiment, under the various conditions, for the influence of the lack of O2 to the drivers This study was focus of studying the system of the automatic ventilating system The result of this study can implementation of improving the working environment where the working environment is closed space like vehicle. It is very close relation that the oxygen-density and there consumption between human body. And then assisting this study, recognizing the variable types of the oxygen consumption in a human body. In this system, examination and research the element and density of the oxygen related. And analize the time to take refreshment of drivers.

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