• Title/Summary/Keyword: 산성 토양

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폐탄광 복원에 대향 조사, 평가 및 복구 설계

  • 최정찬
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.11a
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    • pp.3-21
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    • 2002
  • 국내의 휴ㆍ폐탄광 수는 2002년 현재 230여 개에 이르고 있다. 이에 따라 갱도, 폐석적치장 및 광산 시설물들은 방치상태로 남게 되며 광해의 주요인자가 되고 있다. 광해현상은 이들로부터 유출되는 산성광산배수(Acid Mine Drainage : AMD), 폐석 및 오염토양의 유실 및 하류부 퇴적, 채굴적 상부 및 인접지역의 지반침하 등이다. AMD는 pH가 6.0 미만이고 총산도(total acidity)가 총알카리도(total alkalinity)를 초과하는 물로서 노천광이 가행되었던 지역, 가행중이거나 휴광 또는 폐광된 광산에서 유출된다. 또한 도로사면 절개부나 지하철 터널에서도 황철석(pyrite)이나 백철석(marcasite)등을 함유하는 층이 공기 중에 노출되면 산성수가 침출되어 나오기도 한다. AMD에 의한 하천수의 오염이 매우 극심하여 때로는 미생물마저도 그 속에 살 수 없게 된다. AMD에 의해 오염된 하천수의 오염범위는 산성수의 양, 농도, 하천에 유입되는 산성수의 분포, 상류에서 흘러드는 오염되지 않은 물의 양, 지류에서 유입되는 물의 양에 따라 좌우된다. AMD 오염이 문제시되고 있는 나라는 미국을 포함하여 호주, 일본, 한국, 러시아, 남아연방 등이다. AMD를 처리하기 위해 여러 기술이 도입 적용되었으며 일부 기술들은 현재도 사용되고 있다. 각 기술마다 일장일단이 있으므로 경비의 과다, 유지 및 관리에 대한 지속성 여부, 공간의 확보 여부, 지역적 특수성에 맞춰 가장 적합한 방법을 채택하여야 하며 꾸준히 채택한 기술의 개량 및 새로운 기술의 첨가가 요구되고 있다. 따라서, AMD 오염지대에 대해 획일적으로 같은 처리방법을 채택하여 사용하는 것보다 각 지역 또는 AMD가 유출되어 나오는 광산폐기물의 특성 등을 고려하여 거기에 맞는 기술들을 복합적으로 또는 단독으로 사용하되 처리방법 채택 시 신중을 기할 것이 요망된다. 우리나라에서도 폐탄광을 복원하기 위하여 여러 시도가 있었으나 시간적, 경제적으로 충분히 고려하지 않아 시행착오을 범하고 있다. 따라서, 복원 대상광산에 대한 실제적인 조사, 평가 및 복구설계의 과정을 예로 들어 적절한 처리과정을 토의하고자 한다.

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Growth Inhibition of Cucumber by Absorbing Excess Al at Low Soil pH (강한 산성토양에서 Al의 과잉 흡수에 의한 오이 생육장해 양상)

  • Kim, Yoo-Hak;Kim, Myung Sook;Kang, Seong Soo;Lee, Hyeong Yong
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.925-927
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    • 2012
  • On-site diagnosis applied to soil having a symptom of yellowing and whitening in cucumber leaf and stem. Soil pH determined 4.2 by methods of on-site analysis and 4.5 by soil test analysis. High aluminum in soil solution extracted with water saturation was detected. Leaf and stem tissue were abundant in Al content but not in Ca. Also, N content of leaf and stem was low compared to normal N ranges. This symptom of cucumber assumed to be from the Al and nitrous acid gas toxicity by low soil pH and Eh. Conclusionally, symptom in leaf and stem of cucumber was alleviated and cucumber normally recovered during cultivation period by applying calcium hydroxide solution to correct soil pH up to 6.5. These results showed that low soil pH resulted in aluminum toxicity and N deficiency to plant growth in on-site farming.

Multi-solute Adsorption of Oranic Compounds in Soil (유기화합물들이 혼합상태에서 토양에 흡착하는 성질에 관한 연구)

  • 윤춘경
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.37 no.2
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    • pp.41-52
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    • 1995
  • 혼합상태에서 유기화합물들이 토양에 흡착하는 성질에 관해서 5개의 유기화합물(페놀,2,4-디크로로페놀, 2,4,6-트리크로로페놀, 부루신, 따이오유리아)과 2종류의 토양을 이용하여 연구하였다. 일반적으로 따이오유리아를 제외하고는 한가지 물질이 혼합상태에 있는 다른물질이에 의 흡착력이에 제약을 받아서 단독으로 있을때 보다 흡착율이 낮았다. 따이오유리아는 단독인 경우보다 혼합상태일 때 더 많은 흡착을 보였는데 이는 혼합상태에서 오히려 흡착이 증가할수도 있음을 나타낸다. 혼합이 흡착에 비치는 영향은 페놀의 혼합상태와 단독상태에서의 흡착상태를 여러가지 형태로 비교하여 검토하였는데 산성이고 유기물질이 많은 토양보다 혼합으로 인한 흡착의 억제 효과가 뚜렷하였다.

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Buffer Capacities of Forest Soils by the Treatment of Simulated Acid Rain (인공산성우 처리에 대한 삼림토양의 완충능)

  • 진현오;이계성;정동준
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.4 no.1
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    • pp.49-57
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    • 2002
  • This study was conducted to find out buffer capacities of forest soils by the treatment of simulated acid rain(SAR) of four forests(Q. spp., P. rigida, P. koraiensis, L. leptolepis) in Kyunghee university's practice forest. All soils of each forest stand were treated by simulated acid rain at the level of pH 3.0, 4.0, 5.0 respectively. The result obtained from this study can be summarized as follows: Soil pH was measured by soil depth of each forest stand. The deeper soil depth was, the higher soil pH was. Also it was appeared that base saturation of sample soils was the highest as 17.42% in P. rigida stand and cation exchange capacity(C.E.C) was the highest as 29.87 me/100 g in Q. spp. stand. for responses of soil leachates to acidification treatment with pH 3.0 simulated acid rain(SAR), as simulated acid rain(SAR)-input was increased, pH value of soil leachates appeared high temporarily, but soon pH value of soil leachates had been low gradually. At the rest of pH 4.0, pH 5.0 treatment, pH value of soil leachates was high proportionably. The amounts of TBC of primary stage had a difference as pH level of simulated acid rain and forest stands. But as simulated acid rain(SAR)-input was increased. Amount of TBC was diminished. Also the amounts of TBC of primary stage in acidification treatment with pH 3.0, 4.0 simulated acid rain(SAR) was higher that of acidification treatment with pH 5.0 simulated acid rain(SAR). These trend showed obvious difference at low soil acidity and high TBC. The amounts of activity Al of primary stage appeared high as increasing the input acidity of simulated acid rain(SAR). Also, by soil depth, the amounts of Activity Al was different between A layer(0-15 cm) and AB layer(0-30 cm). There was considerable the correlation between simulated acid rain-input and activity Al change. But this was oppositional trend in soil leachates of pH 4.0, 5.0 treatment and total base cations(TBC).

Effects of Artificial Acid Precipitation on Forest Soil Buffer Capacities (인공산성우(人工酸性雨)가 삼림토양(森林土壤)의 완충능(緩衝能)에 미치는 영향(影響))

  • Min, Ell Sik;Lee, Soo Wook
    • Journal of Korean Society of Forest Science
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    • v.79 no.4
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    • pp.376-387
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    • 1990
  • A research effort has been made to determine soil buffer capacity in forest soils nearby urban and industrialized regions. Buffer capacities of soils from four regions were measured by different pH levels of artificial acid precipitation. The following conclusions have been drawn in response to the overall research objectives. Soil Suffer capacity was the highest in Kangwondo followed by Uisan, Yeochon and Seoul when simulated acid precipitation were treated at the level of pH 3.0-5.7. With the acid precipitation treatment below pH 2.0 level, however, the capacity dropped seriously with no significant differences between the regions. In Kangwondo region soils weathered from granite and limestone showed significant differences in the buffer capacities. Soil collected in Seoul and Ulsean revealed that the capacities tended to increase with the distance from the pollution sources when treated at pH 3.0, 4.5 and 5.7 level of acid precipitation. The major mechanism of soil buffer observed during simulated acid precipitation experiment was canon exchange for Kangwondo forest soils. In Seoul region canon exchange also played an important role in soil buffering under artificial acid precipitation between 3.0 and 5.7 pH levels, yet under pH 2.0 level aluminum and silicate hydrolysis. In Ulsan canon exchange was a msjor determinant for the buffer capacity above pH 4.5 level, between pH 3.0-4.5 aluminum hydrolysis and below pH 3.0 aluminum and silicate hydrolysis. In Yeochon silicate hydrolysis led buffer capacity above pH 4.5 and below pH 4.5 aluminum hydrolysis.

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