• Title/Summary/Keyword: 산성폐수

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A Study on the Assessment of the Contamination by Acid Mine Drainage in Abandoned Coal Mines (국내폐탄광의 산성폐수 오염도 평가에 관한 연구)

  • 최우진
    • Journal of Korea Soil Environment Society
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    • v.2 no.3
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    • pp.31-38
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    • 1997
  • Temporal and spatial comparisons of acid mine drainage contaminated waters are difficult because of the complex physico-chemical nature of the pollutant. In the present study, an acid mine drainage index has been developed and evaluated for the assessment of surface waters. AMD index is calculated using a modified arithmetic weighted index using seven parameters which are most indicative of AMD contamination, i. e. pH value, sulphate, iron, zinc, aluminum, copper and manganese. Weighting is used to express the relative indicator value of each parameter. The proposed AMD index is used to quantify contamination from acid mine drainage over ten different old mine sites and assess the degree of impact on surface on surface waters. As a result of AMD evaluation, the Sukbong Mine located near the Moonkyung province showed lowest AMD value indicating the worst acid mine drainage quality. In overall, Youngdong mine sites showed higher contaimination compared to the other mine sites including Youngsuh, Choongbu, Suhbu and Nambu area.

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Neutralization Processes of Acid Mine Drainage (AMD) from the Abandoned Donghae Coal Mine (동해 폐탄광 일대 산성 광산폐수의 중화처리)

  • 김정엽;전효택;오대균
    • Journal of the Korean Society of Groundwater Environment
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    • v.2 no.1
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    • pp.38-47
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    • 1995
  • This study was carried out in order to provide basic information on neutralization processes of acid mine drainage (AMD) from the abandoned Donghae coal mine in the Samchuk coalfield. The contents of potentially toxic elements in stream water increase and the level of pH decreases during dry season. Hydrated lime is turned out to be the best neutralizer of the acid mine water from a technical and economic viewpoint. From the results of equilibrium calculation, Fe and Al could be precipitated as FeOOH, and Al(OH)$_3$, respectively, in the neutralization process. The sites of holding basins necessary to equalize quantity and quality of AMD are recommended by GIS analysis, and the capacities of holding basins are determined by hydrological calculation.

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Study on Organic Material Used in Bioreactor for the Treatment of Acid Mine Drainage (산성 광산 폐수 처리용 생물반응기에 사용되는 유기물의 연구)

  • 김경호;나현준;이성택
    • Journal of Korea Soil Environment Society
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    • v.2 no.1
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    • pp.45-50
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    • 1997
  • The change of industrial structure has brought the sharp declination of mine products, and has made many mines closed, which results in environmental pollution by untreated acid mine drainage(AMD). AMD with low pH and high concentration of heavy metals could severely destroy the ecosystem. Many researches have been carried out for the treatment of AMD. In this study, we have treated AMD with oak compost, mushroom compost, sludge cake and cow manure which usually used in AMD treatment systems, and compared the capability of each organic matter. Cow manure and oak compost have been most effective among 4 organic materials. Oak compost removed the heavy metals by ion exchange between Ca-rich particles and soluble heavy metal ions. It also captured the heavy metals using bound functional groups like -OH and -COO-. Sulfate reducing bacteria existing in the cow manure removed effectively heavy metals by producing metal sulfide compound. Therefore, it is effective to use both organic materials in mixture on the treatment of AMD.

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산성광산배수 평가 및 처리기술 분석

  • 최정찬
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.02a
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    • pp.29-48
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    • 2001
  • 일반적인 폐수처리 시 여러 광물들이 사용되는 데 예를 들면, 수산화칼슘 및 탄산나트륨은 중화제, 점토는 응집제, 알룸(alum) 및 염화철은 인 제거제로 사용되고 있다. 산성광산배수인 경우에는 알칼리성의 중화제로 석회 (CaO), 석회석 (CaCO$_3$), 가성소다 (NaOH), 탄산나트륨 (NaCO$_3$) 등이 사용된다. 그러나, 설비비 및 유지비가 많이 들어 몇 십년 동안 계속해서 침출되는 산성광산배수를 처리하기에는 문제가 있다. 산성광산배수 (Acid Mine Drainage, AMD)는 pH가 6.0 미만이고 총산도 (totalacidity)가 총알카리도 (total alkalinity)를 초과하는 물로서 노천광이 가행되었던 지역, 가행중이거나 휴광 또는 폐광된 광산에서 유출된다. 또한 도로사면 절개부나 지하철 터널에서도 황철석(pyrite)이나 백철석 (marcasite)을 함유하는 층이 공기 중에 노출되면 산성수가 침출되어 나오기도 한다. 산성광산배수에 의한 하천수의 오염이 매우 극심하여 때로는 미생물마저도 그 속에 살 수 없게 된다. 산성광산배수에 의해 오염된 하천수의 오염범위는 산성수의 양, 농도, 하천에 유입되는 산성수의 분포, 상류에서 흘러드는 오염되지 않은 물의 양, 지류에서 유입되는 물의 양에 따라 좌우된다. 산성광산배수 오염이 문제시되고 있는 나라는 미국을 포함하여 호주, 일본, 한국, 러시아, 남아연방 등이다. 산성광산배수는 환원환경에서 생성된 석탄층 및 접촉교대 또는 열수에 의해 생성된 금속광이 공기 및 물에 노출되어 생성되는 자연적인 현상이다. 그러나 국지적인 지역에서 인간이 이 광상들을 환경영향을 고려하지 않고 대규모로 개발할 때 인간 생활에 심각한 영향을 미치는 것이다. 광산산성배수를 처리하기 위해 상기와 같이 여러 기술이 도입 적용되었으며 일부 기술들은 현재도 사용되고 있다. 각 기술마다 일장일단이 있으므로 경비의 과다, 유지 및 관리에 대한 지속성 여부, 공간의 확보 여부, 지역적 특수성에 맞춰 가장 적합한 방법을 채택하여야 하며 꾸준히 채택한 기술의 개량 및 새로운 기술의 첨가가 요구되고 있다. 따라서, 산성광산배수 오염지대에 대해 획일적으로 같은 처리방법을 채택하여 사용하는 것보다 각 지역 또는 광산산성폐수가 유출되어 나오는 광산폐기물의 특성 등을 고려하여 거기에 맞는 기술들을 복합적으로 또는 단독으로 사용하되 처리방법 채택 시 신중을 기할 것이 요망된다.

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장풍 폐광산의 산성광산폐수에 의한 침출수 유동에 대한 지구물리 및 지화학탐사자료의 상관해석

  • Kim, Ji-Su;Han, Su-Hyeong;Choe, Sang-Hun;Lee, Gyeong-Ju;Lee, In-Gyeong;Lee, Pyeong-Gu
    • Journal of the Korean Geophysical Society
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    • v.5 no.1
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    • pp.19-27
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    • 2002
  • Geophysical surveys(self-potential, electromagnetic, electrical resistivity, and seismic refraction methods) were performed to delineate the flow channel of leachate from a AMD (acid mine drainage) by correlating the anomalies to geochemical characteristics at an abandoned mine (Jangpoong mine). The geophysical responses attempted to be correlated with water sample analysis data(pH, EC, heavy metals, ${SO_4}^{-2}$). Electrical dipole-dipole resistivity sections represent the low-resistivity zone trending northwest, which indicates the leachate flow by AMD along the contact of the mine waste rock dump and the bedrock. From the overall points of geophysical and geochemical anomalies, it is summarized that the flow channel of leachate by AMD can be successfully imaged with composite interpretations on the geophysical and geochemical studies.

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Emission Patterns and Formation Mechanism of PCDDs/PCDFs in Bleaching Wastewater(I) - Inlet and Outlet of the Chlorine Bleaching Stage(Acidic Wastewater) - (제지폐수중의 다이옥신 배출 패턴 및 형성 메카니즘(I) - 염소표백공정(산성폐수) 전.후단을 중심으로 -)

  • Chung, Y.H.;Shin, S.K.;Jang, S.K.
    • Analytical Science and Technology
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    • v.14 no.3
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    • pp.266-273
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    • 2001
  • One pulp manufacture facility was selected as surveying facilities to examine the discharged rate and generation mechanism of dioxin in bleaching stag wastewater. The analytical method was established in the wastewater and the sample was collected and analyzed. The outlet concentration of bleaching stage was increased 5 times for 2,3,7,8-TCDF and 7 times for OCDD, and the discharged ratio between PCDFs and PCDDs was surveyed about 2:3. The 2,3,7,8-TCDF and 2,3,7,8-TCDD were mainly detected in acid wastewater of bleaching stage that is known as the typical discharged patterns of chlorine bleaching stage.

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Estimation of Acidic Wastewater Toxicity on the Activated Sludge (활성슬러지에 미치는 산폐수의 독성도 예측)

  • Choi, Kwang-Soo;Ko, Joo-Hyung;Jang, Won-Ho;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2175-2185
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    • 2000
  • Respiration rate should be a reasonable state variable for the activated sludge and could be used to simulate the performance of the activated sludge process. Toxic materials are classified into three groups, competitive, noncompetitive and uncompetitive. They increase/decrease the half saturation coefficient or specific growth rate. that means decreasing of the substrate removal capacity. In this research, a pilot-scale activated sludge process was operated under extended aeration method, and a representative noncompetitive inhibitor, acidic wastewater was applied to establish a respirometry-based toxicity model. Using this model. the correlation coefficient between measured and calculated respiration rate was 0.96 when acidic wastewater(pH 3.9~5.5) was introduced continuously to the aeration tank. Even though respiration rate was decreased by toxic effect of acidic wastewater, effluent substrate concentration represented to COD was deteriorated just a little bit. It might be caused by the low ratio of readily biodegradable substrate in the input substrate. Reduction of respiration rate by decreasing of input substrate concentration was much lower than that by acidic wastewater, and hence it was estimated that the possibility of false toxic alarm caused by decreasing of substrate concentration should be low.

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Removal Characteristics of Heavy Metals by Continuous Neutralization of Plating Wastewater with Waste-Oyster Shells (폐굴껍질에 의한 산성도금폐수의 연속 중화시 중금속제거 특성)

  • 김형석;송동근;성낙창
    • Resources Recycling
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    • v.7 no.3
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    • pp.36-41
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    • 1998
  • Objective of the research is to deteonine the praeLic따 running parameters for neutralization and removal of heavy metals from plating wastewater with waste-oyster shells by the Bohart$.$Adams equation. Waste-oyster shells discharged from the d domestic oyster cultnring fields cause a serious ocean environmental pollution. However, it is expected that those are able to b be recycled for removal of heavy metals through neutralization of plating wastewater because the shells contain approximate 93% $CaCO_3$, and have multi-pore voids. By applying the results of the continuous experiments to Bohart-Adams equation, s service time decreases in the order of Cr>Fe>Cu while removal efficiencies of metals become less in the order of Fe>Cr>Cu.

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