• The Korean Journal of Rheology
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• v.1 no.1
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• pp.54-62
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• 1989

준희박과 농축용액에서 약간의 유연성을 갖는 강성막대형 고분자의 회전확산계수와 zero shear rate 점도를 예측하기 위해 한정된 강성 사슬모델이 제시되었다. 본 연구에서는 이제시된 모델을 분자량 분포를 갖는 다분산계로 확장시켰다. 분자들의 분자량 분포 (MW/Mn) 와 분포 함수를 알수 없기 때문에 해당분자에 가장 적당한 분자량 분포와 함수를 취하였다. 만약 이것들을 알고 있다면 제시된 모델로 회전확산계수와 zero shear rate 점도 등과 같은 인자들을예측할수 있었다. 단분산계의 경우와 같이 다분산계에서도 회전확산계수 의 평균분자 윤곽길이 의존도는 L-7 에 비례하는 것으로 나타났다. Doi와 Edwards 의 튜브 모델에 의한 L-9 과 다른 이유는 분자들의 거동을 관찰하기 위해 임의로 선정된 하나의 막 대형 고분자운동을 제약하는 정도가 심하지 않았으며 따라서 제약 완화시간도 훨씬 짧았기 때문이다. 더구나 점도와 회전 확산계수와 단분산계에서는 정성적으로 일치한데 제약 완화 시간도 훨씬 짧았기 때문이다. 더구나 점도와 회전적인 일치를 나타내었다. 이 모델로 기준 으로 하여 분자들의 길이와 종류에 관계없이 하나의 master curve를 그릴수 있었다.

• Journal of the Korean Applied Science and Technology
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• v.17 no.2
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• pp.105-112
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• 2000

Surface tension as a function of concentration and temperature was measured for aquous solution of sodium N-acyl sarcosinate, $RCON(CH_{3})CH_{2}$ COONa, From the intersection points in the (${\gamma}-logC$) curves, the critical micelle concentration (cmc) was determined at 20, 30, 40, and $50^{\circ}C$. Structural effects on the cmc maximum and the minimum area per molecule at the aquous solution/air interface were discussed. The free energy, enthalpy, and entropy of micellization and adsorption of surfactant solution also were investigated. Numberous investigators have dealt with sodium N-acyl sarcosinates and their applications as wettings, flooding and reducing agents and as corrosion inhibitors.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.529-532
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• 2008

The durability of concrete and the water-tightness properties of cementitous material are closely relation. So, water-tightness materials as natural minerals, organic fatty acid, organic fatty salts inorganic materials use for improvement of concrete durability. But these materials are somehow different in water-tightness mechanism. In this study, we studied on hydration properties and water-tightness properties of cementitous materials with zinc-stearate, a kind of organic fatty acid salts.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.11 no.2
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• pp.49-54
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• 1978

The cold water mass appeared in offshore of the east coast of Korea in summer season was studied in aspect of chemical oceanography. Such a typical relationship between phosphate and dissolved oxygen as shown in the upwelling regions could not be found in the east coast except around the Kampo coast, southern part of the east coast. It is possible to isolate the North Korean Cold Water from tile proper water of tile Japan Sea by using $\sigma_t-O_2$ diagram. The origin of the cold water mass in offshore of the east coast of Korea in summer is not mainly due to the development of upwelling of the proper water of the Japan Sea but thesouthwardflolvingoftheNorthKoreanCold Water.

• Journal of the Korean Applied Science and Technology
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• v.18 no.1
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• pp.55-59
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• 2001

These N-acyl amino acid surfactants is normally produced by reaction of acid anhydride with sodium ${\ell}-glutamate$ hydrolysates under Schotten-Baumann condition i.e., in alkaline aqueous medium. To avoid using fatty acid chlorides, acylations were also carried out with the fatty acids themselves or with their methyl esters, but unfortunately these methods cannot be used in practice, dodecenyl succinic anhydride, was to be studied for their suitability as acylating agents the production if acylated glutamine hydrolysates. The surface activities including surface tension forming power, forming stability and emulsifying power were measured. The experimental results revealed that the products have a good emulsifying power. Thus, there derivatives will be expected to be used an emulsifying agent for O/W type cosmetic emulsion.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.315-315
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• 2019

증산과 증발의 합으로 나타내지는 증발산은 지구내에서의 수문 순환에 영향을 미치는 중요한 인자로써, 지표와 대기의 에너지 교환을 담당하고 있다. 정확한 관측을 위해서 오래전부터 증발산에 대해서 관측하기 위하여 직접관측 방법들인 증발산계를 이용한 관측방법, 에디 공분산 방법을 이용한 플럭스타워 관측 방법 등을 사용하였으며, 물리 및 경험적인 방법인 Penman (1948), Monteith (1965) 방법, PT (Priestley and Taylor, 1972) 방법 등을 이용함으로써 증발산과 관계를 가진 수문기상인자를 이용함으로써 증발산에 대해서 추정하여 왔다. 대부분 지상 관측에 의존하기 때문에 시공간적인 값의 표현이 어렵다는 문제를 가지고 있으며, 관측 장비의 관리 및 유지비용이 증대로 인하여 조밀한 관측망을 구축하기 어렵다. 이러한 단점을 개선하고자 인공위성 및 재분석 자료를 활용하여 여러 경험식을 통해서 증발산 자료가 제공되고 있다. 그러나 이러한 자료들의 문제점은 각기 다른 경험식 및 다른 입력자료를 제공하고 있을 뿐만 아니라, 자료별 지역별 정확성이 차이가 발생한다. 따라서, 최근 연구에서는 지점자료와 인공위성 자료 및 재분석 자료를 모두 사용함으로써 수문기상인자를 개선하고자 하는 연구가 진행되어왔으며, 정확성 또한 개선된 것을 확인 할 수 있다. 그러나, 이러한 방법들의 가장 큰 문제점은 관측 자료가 필수적으로 필요하다는 것에 있다. 대부분의 나라나 지역에서는 조밀한 구축망을 구축하기 어렵기 때문에 실질적으로 적용하기가 어렵다는데 있다. 따라서 본 연구에서는 이러한 문제를 해결하기 위하여 지점자료가 필요없는 융합방법을 triple collocation 방법을 이용함으로써 제안하고자 한다.

• Journal of the Korean Applied Science and Technology
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• v.36 no.4
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• pp.1443-1459
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• 2019

Polyglycerol fatty acid ester nonionic surfactants have been used for a long time in foods and have been suggested as an alternative to the safety problems of PEG based nonionic surfactants. The polyglycerol fatty acid ester surfactants are synthesized by combining a hydrophilic polyglycerin and a lipophilic fatty acid. The hydrophilic polyglycerin is polymerized using glycerin, glycidol, epichlorohydrin, etc. The main issues of the polyglycerol polymerization reaction are to increase the content of the polyglycerol in the form of linear rather than branched or cyclic forms and to narrow the distribution of the degree of polymerization. The method of binding a lipophilic fatty acid group to a hydrophilic polyglycerin includes chemical synthesis such as esterification reaction and enzyme synthesis using lipase enzyme. The main issues of polyglycerin fatty acid ester synthesis are to increase the yield and to control the degree of esterification while reducing side reactions.

• Polymer(Korea)
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• v.34 no.1
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• pp.52-57
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• 2010

The low viscous epoxy resin(bisphenol F) with carboxylic acid as the reductants was introduced for high performance and reliability in the ACA with a low melting point alloy filler system. The curing characteristics of the epoxy resin and temperature dependant viscosity characteristic of epoxy resin at the melting temperature of LMPA were investigated by dynamic mode of differential scanning calorimetry (DSC) and rheometer, respectively. Based on these thermo-rheological characteristics of epoxy resin and LMPA, the optimum process system was designed. In order to remove the oxide layer on the surface of LMPA particle, three different types of carboxyl acid-based reductant were added to the epoxy resin. The wetting angles were about $18^{\circ}$ for carboxypropyldisilioxane, and $20.3^{\circ}$ for the carboxy-2-methylethylsiloxane, respectively.

• Journal of the Korea Institute of Building Construction
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• v.9 no.6
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• pp.175-181
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• 2009

In this research, experiments were conducted to find out whether polycarboxylate could be used as a crude steel admixture for practical work, depending on the change in the replacement level of the compound mixed into polycarboxylate. Its fluidity was satisfactory, its airspace was a bit smaller than the KS standard, and its unit volume weight was proven to meet the standard. The amount of bleeding was smallest in B2, and in terms of the solidification time, the first and the last solidification was faster in A1, B1, and C1. With regard to the compressive strength in early days as acharacteristic of hardened concrete, all addition rates of 7-day C2 displayed the highest strength value, among which the addition rate of 1.3% had the biggest strength performance tendency. The seal strength also showed the strength performance rate which was about one tenth as big as that of the compressive strength. The length change rate resulting from dryness and contraction was proven to be good, and once the appropriate AE air entraining agent is used, it is evaluated to be a very useful and practical compound out in the field.

• Applied Chemistry for Engineering
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• v.1 no.2
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• pp.249-255
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• 1990

The conditions for separation and identification of anionic and nonionic surfactants by thin layer chromatography were investigated. Polyoxy alkylene-type nonionic surfactants were identified by the distribution of alkyl chain and alkylene oxide. Various polyoxyethylenated nonyl phenols were easily distinguished by densitometer. Some anionic surfactants were identified by $R_f$ and color, and the mixtures of anionic and nonionic surfactants were separated. Polyoxyethylenated fatty acid was separated into three parts of diester, monoester and polyethylene glycol, respectively, and the mixed ratio was determined by densitomer. All the experiments were carried out in 13-20 minutes, and the length of run was 80mm.