• Title/Summary/Keyword: 사이클 분리

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Application of CV Cycling to the Activation of the Polymer Electrolyte Membrane Fuel Cell (고분자 전해질막 연료전지의 활성화를 위한 CV 활성화법)

  • Cho, Ki-Yun;Jung, Ho-Young
    • Applied Chemistry for Engineering
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    • v.23 no.5
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    • pp.445-449
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    • 2012
  • The activation process of the membrane-electrode assembly (MEA) is important for the mass production of the polymer electrolyte membrane fuel cell. The conventional activation process for the MEA requires excessive time and hydrogen gas and it might become the barrier for the commercialization of the fuel cell. The conventional activation process is based on hydrolysis of ion conducting membrane. In the study, we suggest the cyclic voltammetry (CV) technique as an on-line activation process and the CV activation process consists of two steps : 1) the humidification of the polymer electrolyte membrane and the electrode with 100% RH humidified nitrogen ($N_{2}$) gas, and 2) the removal step of the oxide layer on the surface of the Pt catalyst with CV cycling. The cycling reduces the activation time of the MEA by 2.5 h and use of hydrogen gas by 1/4.

Development of an Imaging Processing System for Automation of a Callus Inoculation (식물조직배양 자동화를 위한 영상처리장치 개발)

  • Chung, Suk-Hyun;No, Dae-Hyun;Song, Jae-Kwan
    • Journal of Bio-Environment Control
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    • v.18 no.2
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    • pp.95-100
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    • 2009
  • This study was conducted to develop an imaging processing system of inoculation processing of a lily callus. The image processing system was composed of a camera, a image processing board, and etc. And the illuminance always decided by setting up 55W/3 wavelength lamp respectively on all aspects and the side was maintained by the lighting part. The image characteristic was examined according to each frame of RGB,therefore the culture vessel was able to be separated with B frame. The required time was 2.2 seconds in one cycle from the image acquisition to obtaining the result. The recognition rate of the container was 100%, and the result of image processing showed that the recognition success rate of lily callus was 93%.

Highly Efficient Mechanical Separation Process for the Recycling of Waste Jelly-Filled Communication Cables (고효율 기계적 박리기술을 이용한 폐 젤리충진 통신케이블 재활용 연구)

  • Lee, Sooyoung;Uhm, Sunghyun;Seo, Minhye;Lee, Minseok;Cho, Sungsu
    • Resources Recycling
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    • v.25 no.3
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    • pp.37-42
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    • 2016
  • Highly efficient and environmentally friendly mechanical process was developed for the higher recovery rate and productivity in the recycling of waste jelly-filled communication cables. Only the simplest mechanical method was designed and built for a continuous process, further proved experimentally along with the addition of several parts such as brush-type rollers and scrappers. In this process, the recovery rate and productivity were 98% and 55 Kg/hr respectively. This process is thought to be simple but highly advanced method for the commercialization of green process.

Hydrolysis Stability of Sulfonated Phthalic and Naphthalenic Polyimide with Ester Bond (에스테르기를 도입한 술폰화 프탈계 폴리이미드와 나프탈렌계 폴리이미드의 수화안정성에 관한 연구)

  • 이영무;이창현;손준용;박호범
    • Membrane Journal
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    • v.13 no.2
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    • pp.110-117
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    • 2003
  • Sulfonated polyimides had been utilized and studied widely as available materials in chloro-alkali electrolysis, cationic exchange resins, and so on. However, a slow decrease in performance during experiments had been reported, which could be attributed to a loss of ionic conductivity related to either a continuous dehydration or polymer degradation. One of main reasons to account for the degradation of sulfonated polymers is the hydrolysis leading to polymer chain scission and decrement of molecular weight. Therefore, the objective of our study was to investigate possible imide cycle and additional ester bond cleavage connected with $SO_3$H presence under hydrated condition. In order to confirm and obtain as clear information as possible about breakages of bonds via $^1H\; and \;^{13}C$ NMR and IR spectroscopic analyses, our study was performed by model compound. Consequently, model compounds with both phthalic and naphthalenic imide ring and ester bonds were synthesized to evaluate the hydrolysis stability of sulfonated polyimide. The experiments were performed for prepared model compounds before and after aging in deionized water at $80^{\circ}C$ and were terminated by lyophilization technique. The aging products were finally analyzed by NMR and IR spectroscopy.

Durability Evaluation of Gangway Ring for the Articulated Bogie of High speed Railway Vehicle (고속철도차량 관절대차 갱웨이 링의 내구성 평가)

  • Kang, Gil-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.5
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    • pp.66-72
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    • 2019
  • To improve ride quality and running stability of high speed train(HST), it is important that connection between coaches adopts the articulated bogies by using a gangway ring, unlike the conventional independent bogies assembled with car bodies. Although the gangway ring should be ensured absolute safety against passenger movement between coaches during train operation, there is still a lack of quantitative durability criteria of that. Therefore, in order to improve the passenger safety of HST, it is important to study the test requirements on durability evaluation for the ring. In this study, seven mixed loading cases were derived from the triaxial loading(vertical/lateral/longitudinal) modes. The safety factor of each component is at least 2.4 or more from the results of the finite element analysis. In addition, fatigue safety was evaluated through durability analysis from the viewpoint of strain-life design. Durability tests for the gangway ring carried out a total of 10 million cycles in 4 phases load conditions. After the durability test, the defect of each component was investigated using nondestructive testing techniques.

Real Time Fault Diagnosis of UAV Engine Using IMM Filter and Generalized Likelihood Ratio Test (IMM 필터 및 GLRT를 이용한 무인기용 엔진의 실시간 결함 진단)

  • Han, Dong-Ju;Kim, Sang-Jo;Kim, Yu-Il;Lee, Soo-Chang
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.50 no.8
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    • pp.541-550
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    • 2022
  • An effective real time fault diagnosis approach for UAV engine is drawn from IMM filter and GLRT methods. For this purpose based on the linear diagnosis model derived from engine dynamic performance analysis the Kalman filter for residual estimation and each method are applied to the fault diagosis of the actuator for engine control sensors. From the process of the IMM filter application the effective FDI measure is obtained and the state responses due to actuator fault are estimated. Likewise from the GLRT method the fault magnitudes of actuator and sensors are estimated associated with some FDI functionings. The numerical simulations verify the effectiveness of the IMM filter for FDI and the GLRT in estimating the fault magnitudes of each fault mode.

A Study on the Recycling Improvement method of a Cosmetic Container in Korea (우리나라 화장품용기의 재활용 증진 전략)

  • Kim, Young-Gook;Lee, Hoon;Jung, Jae-Chun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.1
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    • pp.128-138
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    • 2002
  • Waste recyling is a very important concept with waste minimization in the waste managment. Especially, recycling waste from the point of environmental and economical view is useful. The recycling part of package waste needs to continuously grow. But, cosmetic container, which is continuosly increased as waste. The difficulty of waste treatment in cosmetic industy produces complicated environment problem. Cosmetic container is difficult to recycle because it mostly made of complex material. Also, cosmetic container is difficult to separate I source and thus usually are generated mixed waste. In this study we performed an analysis on the Recycling Improvement method of a Cosmetic Container The result of this study could be summarized as follows 1) As a part of law and a system improvement, must be achieved Improvement Cosmetic law, Deposit refund system. and charge system, Technology development for recycling of a cosmetic container, Extension of refill productions, Recovery system establishment of a cosmetic container and inducement of a maker's recycling paticipation. 2) As a part of a cosmetic container design improvement, must be achieved simplification and standardize of container's cuality, Cosmetic life cycle extension, Selection of recycling materials and Cosr reduction of a cosmetic container. In conclusion, To the recycling improvement of a cosmetic container, must be achived collective development of system improvement, participation of the government and company and a consumer's recycling consciousness. Most of all, A company need to try to recycling container development of a cosmetic container.

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The Study on Bunsen Reaction Process for Iodine-Sulfur Thermochemical Hydrogen Production (요오드-황 열화학 수소 제조를 위한 분젠 반응 공정 연구)

  • Kang, Young-Han;Ryu, Jae-Chun;Park, Chu-Sik;Hwang, Gab-Jin;Lee, Sang-Ho;Bae, Ki-Kwang;Kim, Young-Ho
    • Korean Chemical Engineering Research
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    • v.44 no.4
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    • pp.410-416
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    • 2006
  • For highly efficient operation of a Bunsen process section in an iodine-sulfur thermochemical hydrogen production cycle using nuclear heat, the process characteristics of $H_2SO_4-HI-H_2-O-I_2$ mixture system for separating into two liquid phases ($H_2SO_4$-rich phase and $HI_x$-rich phase) and the distribution of $H_2O$ to each phase were investigated.The experiments for process variables were carried out in the temperature range, from 298 to 353 K, and in the $H_2SO_4/HI/H_2O/I_2$ molar ratio of 1/2/14~20/0.5~8.0. As the results, for the $SO_2-I_2-H_2O$ Bunsen reaction system, the ranges between the starting point and the saturation point for two liquid phases separation were determined by calculation. The best result for the minimization of impurities (HI and $I_2$ in $H_2SO_4$ phase and $H_2SO_4$ in $HI_x$ phase) in each phase was obtained in an optimum condition with the highest temperature of 353 K and the highest $I_2$ molar composition. In this condition, the $HI/H_2SO_4$ molar ratio in the $H_2SO_4$-rich phase and the $H_2SO_4/HI_x$ molar ratio in the $HI_x$-rich phase were 0.024 and 0.028, respectively. For the distribution of $H_2O$ to each phase, it is appeared that the affinity between $HI_x$ and $H_2O$ was more superior to that between $H_2SO_4$ and $H_2O$. The affinity between $HI_x$ and $H_2O$ was decreased with increasing temperature but increased with increasing $I_2$ molar composition.

CO2 PSA Process using Double-Layered Adsorption Column (이단 적층 흡착탑을 이용한 CO2 PSA 공정)

  • Lee, Hwaung;Choi, Jae-Wook;Song, Hyung Keun;Na, Byung-Ki
    • Clean Technology
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    • v.7 no.1
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    • pp.51-63
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    • 2001
  • In this study, PSA, known as the most economic process, was used to recover $CO_2$ from the power-plant flue gas. Activated carbon and zeolite molecular sieve 13X were used as adsorbent. Activated carbon has been deemed inadequated adsorbent for separating $CO_2$ from the flue gas. However, highly concentrated $CO_2$ could be obtained as a product on the activated carbon adsorbent using the new operating cycle modifying the rinse step. Also, the recovery of $CO_2$ was improved using double-layered adsorption column packed with the activated carbon and the zeolite 13X simultaneously. Adsorption column was filled with the activated carbon in the feed-end side, and the zeolite 13X in the product-end side. The recovery of $CO_2$ increased about 40% with only 25% zeolite, and increased 67% with 50% zeolite at the experimental conditions of 13% $CO_2$ concentration, 10 SLPM flow rate and 2.2 atm adsorption pressure.

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Experimental Study on Optimization of Absorber Configuration in Compression/Absorption Heat Pump with NH3/H2O Mixture (NH3/H2O 혼합냉매를 사용한 압축/흡수식 히트펌프 시스템의 흡수기 최적화에 관한 실험적 연구)

  • Kim, Ji-Young;Kim, Min-Sung;Baik, Young-Jin;Park, Seong-Ryong;Chang, Ki-Chang;Ra, Ho-Sang;Kim, Yong-Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.3
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    • pp.229-235
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    • 2011
  • This research aims todevelopa compression/absorption hybrid heat pump system using an $NH_3/H_2O$ as working fluid.The heatpump cycle is based on a combination of compression and absorption cycles. The cycle consists of two-stage compressors, absorbers, a desorber, a desuperheater, solution heat exchangers, a solution pump, a rectifier, and a liquid/vapor separator. The compression/absorption hybrid heat pump was designed to produce hot water above $90^{\circ}C$ using high-temperature glide during a two-phase heat transfer. Distinct characteristics of the nonlinear temperature profile should be considered to maximize the performance of the absorber. In this study, the performance of the absorber was investigated depending on the capacity, shape, and arrangementof the plate heat exchangers with regard tothe concentration and distribution at the inlet of the absorber.