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Physical Properties and Flame Retardency of Polyhydroxyamides (PHAs) Having Pendant Groups in the Main Chain (주사슬에 곁사슬기를 갖는 폴리히드록시아미드의 물성 및 난연특성)

  • Yoon, Doo-Soo;Choi, Jae-Kon;Jo, Byung-Wook
    • Polymer(Korea)
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    • v.30 no.6
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    • pp.478-485
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    • 2006
  • Physical properties and flammability of polyhydroxyamides (PHAs) haying poly (ethylene-glycol) methyl ether (MPEG) and/or dimethylphenoxy pendants were studied by using DSC, TGA, FTIR, pyrolysis combustion flow calorimeter (PCFC), and X-ray diffractometer. The degradation temperatures of the polymers were recorded in the ranges of $276{\sim}396^{\circ}C$ in air. PCFC results showed that the heat release (HR) capacity and total heat release (total HR) values of the PHAs were increased with in-creasing molecular weight of MPEG. In case of M-PHA 2 annealed at $290^{\circ}C$, the values of HR capacity were siginificantly decreased from 253 to 42 J/gK, and 60% weight loss temperatures increased from 408 to $856^{\circ}C$ with an annealing temperature. The activation energy for the decomposition reaction of the PHAs showed in the range of $129.3{\sim}235.1kJ/mol$, which increased with increasing conversion. Tensile modulus of PHAs were decreased as increasing chain of MPEG, and showed an increase more than initial modulus after converted to PBOs.

An Experimental Study on Mortar to Apply Building Structure (건축물 구조체에 적용가능한 모르타르에 관한 실험적 연구)

  • Kwon, Mi-Ok;Yoon, Ki-Hyun;Jung, Kang-Sik;Kim, Gang-Ki;Paik, Min-Su;Jung, Sang-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.413-416
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    • 2008
  • The concrete used most in construction materials. There is an overcrowded iron dimensions use of the concrete at time of the other concrete theory on the reinforcing rod back which did congestion and compares it with this, and there are more few dimensions of the aggregate than concrete, and quantity of aggregate passage is superior in mortar than concrete. If a volume rate of the aggregate writes mortar than concrete against this, therefore, unit amount increases, and quantity of paste increases and quantity of dry shrinkage than increase concrete. However, I let I regulate lay priest distribution of the aggregate, and the results rates increase and reduce unit amount and decrease quantity of dry shrinkage, and separation resistance and the gap passage characteristics are judged because it can be it in a substitute document of very superior concrete. I came to carry out the study that I watched to let I was useful a little more and do the improvement repair of a become building wall body, a basement pillar and repair reinforcement of the assistant in the reinforcing rod back, the old age when I made congestion here. I regulated lay priest distribution of the aggregate in the study and regulated substitution rate of the aggregate (40%, 50%, 60%) and divided W/C 30%, 40% standards and produced mortar and I compared quantity of air by this, slump, compression robbery and showed it this time.

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Numerical Analysis of Infiltration in Permeable Pavement System considering Unsaturated Characteristics (불포화 특성을 고려한 투수성 포장 시스템의 침투성 수치해석)

  • Kim, Seungbae;Ahn, Jaehun;Teodosio, Bertrand;Shin, Hyunjun
    • Journal of the Society of Disaster Information
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    • v.11 no.3
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    • pp.318-328
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    • 2015
  • Effective urban flood reduction and restoration of natural water cycle at present include the application of permeable pavements. The application of permeable pavement addresses urban water cycle and disaster related events which gained attention internationally. However, few researches have been conducted to investigate unsaturated behavior and evaluate the water characteristics curves of these type of pavement materials most especially in the unsaturated state. In this study, first the saturated permeability and the soil-water characteristics curve of a pervious concrete are evaluated based on laboratory tests, and, based on experimental results, the infiltration of permeable pavement system is numerically modelled. In the soil-water characteristics curve of a pervious concrete, the volumetric water content drops very steeply after the air entry value with increasing matric suction. From the finite element analyses, the performance of the permeable pavement when compared to impermeable pavement, confirmed that the whole system effectively delayed and reduced runoff.

A Study on Visuospatial Cognitive Performance Following Oxygen Administration using fMRI (뇌기능 영상을 이용한 외부 산소 공급에 따른 공간 지각 능력 변화에 관한 연구)

  • 정순철;김익현;이봉수;이정미;손진훈;김승철
    • Journal of Biomedical Engineering Research
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    • v.24 no.4
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    • pp.267-273
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    • 2003
  • The present study attempted to observe what changes the supply of highly concentrated (30%) oxygen cause to people's ability of visuospatial cognition, compared to air of normal oxygen concentration (21%). This study sampled eight male university students (the average age : 23.5) as subjects for functional Magnetic Resonance Imaging (MRI) study It also developed equipment that supplies 21% and 30% oxygen) at a constant rate of 8L/min. Two questionnaires containing 20 questions were developed to measure the ability of visuospatial cognition, and accuracy was calculated from the result of task performance. The experiment paradigm consisted of the run conducting tasks at 30%'s concentration of oxygen and another run at 21%'s concentration of oxygen. Each run was composed of four blocks and each block included eight control tasks and five visuospatial taks. 3T MRI was used and fMRI was obtained through the single-shot EPI method. The activation in the occipital-associated area, bilateral superior parietal lobes, bilateral inferior parietal lobes. bilateral precuneus, bilateral postcentral gyri, bilateral middle frontal gyri, bilateral inferior frontal gyri, bilateral medial frontal gyri, bilateral superior frontal gyri, bilateral cingulate gyri was significantly increased at the 30%'s concentration of oxygen rather than 21%'s. Furthermore, the result of task performance showed the accuracy increased at 30%'s concentration of oxygen rather than 21%'s. From the result of this study, it is concluded that the supply of highly concentrated oxygen has a positive effect on the ability of visuospatial cognition.

An investigation on the insulation characteristics of $SF_6$ mixtures gas under uniform and non-uniform electric field (평등/불평등 전계에서의 $SF_6$혼합된 가스의 절연파괴특성 연구)

  • Lee, Sang-Hwa;Lee, Young-Jo;Ahn, Hee-Sung;Jeong, Seung-Young;Koo, Ja-Yoon
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1397-1398
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    • 2007
  • 본 연구는 $SF_6$와 Dry-air(건조공기), $N_2$, $CO_2$ 가스가 혼합된 절연매체의 절연 특성과 부분방전 특성 연구를 기초실험용 쳄버와 70kV급 GIS mock up을 이용하여 교류전압을 인가하여 실험이 수행되었다. 전자의 경우, Sphere gap 및 Needle/Plate 전극시스템을 이용하여 순수 $SF_6$가스와 Dry-air, $N_2$, $CO_2$ 가스들의 절연내력을 비교하고, 챔버의 압력을 5기압으로 유지한 상태에서 Dry-air, $N_2$, $CO_2$$SF_6$가스의 혼합비를 변화시키면서 절연내력이 측정되었다. 후자의 경우, 기초실험에서 도출된 $SF_6$가스와 Dry-air, $N_2$, $CO_2$의 최적의 혼합비율을 선택한 후, 방전 개시전압과 부분방전 양상을 순수 $SF_6$가스의 결과와 비교분석하기 위한 실험을 수행하였다. 이를 위하여 GIS 사고의 주요원인이 되는 결함들, 즉 Protrusion, Floating, Free moving particle 들을 인위적으로 모의하여 Mock up 내부에 설치하고 내부 압력을 5기압으로 유지한 상태에서 수행되었다. 전자의 경우, $0.5{\sim}5$ 기압 범위 내에서 Dry-air, $N_2$, $CO_2$ 압력을 변화시켰을 때 절연내력은 전극시스템에 무관하게 순수 $SF_6$가스의 결과치의 Dir-air $47{\sim}51%$, $N_2\;48{\sim}61%$, $CO_2\;47{\sim}60%$ 정도이다. 또한 챔버 압력이 5기압인 상태에서 Dry-air, $N_2$, $CO_2$가 80% 혼합된 절연매체는 순수 $SF_6$가스 절연내력의 80%이상의 절연내력을 가지고 있다. 후자의 경우, 인가전압을 고정 시켰을 때, 부분방전 패턴과 방전크기는, 순수 $SF_6$가스와 Dry-air 가 80% 혼합된 절연매체는 동일한 패턴과 방전크기를 나타내고 있다. 이러한 결과를 근거로, 가스 압력이 5기압에서 운전되는 전력기기의 절연매체로서 혼합가스를 사용할 경우, $SF_6$가스와 Dry-air, $CO_2$, $N_2$ 가스들의 혼합비는 2:8정도가 적절한 것으로 제안한다.

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Water-Soluble Conjugated Polymer and Graphene Oxide Composite Used as an Efficient Hole-Transporting Layer for Organic Solar Cells (수용성 공액고분자/그래핀 옥사이드 복합체를 이용한 유기태양전지의 정공수송층에 대한 연구)

  • Kim, Kyu-Ri;Oh, Seung-Hwan;Kim, Hyun Bin;Jeun, Joon-Pyo;Kang, Phil-Huyn
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.38-42
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    • 2014
  • The poly[(9,9-bis((6'-(N,N,N-trimethylammonium)hexyl)-2,7-fluorene)-alt-(9,9-bis(2-(2-(2-methoxyethoxy)ethoxy)ethyl)-9-fluorene)) dibromide (WPF-6-oxy-F)] and graphene oxide (GO) was blended and irradiated with gamma ray under ambient condition. This WPF-6-oxy-F-GO composite was investigated as a hole-transporting layer (HTL) in organic solar cells (OSCs). Compared with the pristine GO, the sheet resistance ($R_{sheet}$) of irradiated WPF-6-oxy-F-GO was decreased about 2 orders of magnitude. The reason for the decrease of $R_{sheet}$ is the effect of efficient ${\pi}-{\pi}$ packing resulted from the formation of C-N bond between WPF6-oxy-F and GO. As a result, the efficiency of OSCs was dramatically enhanced ~ 6.10% by introducing irradiated WPF-6-oxy-F-GO as a HTL. WPF-6-oxy-F-GO is a sufficient candidate for HTL to facilitate the low-cost and high efficiency OSCs.

A Simplified Closed Static Chamber Method for Measuring Methane Flux in Paddy Soils (논토양(土壤)의 메탄 배출(排出) 측정(測定)을 위한 간역폐쇄정태(簡易閉鎖靜態) Chamber법(法))

  • Shin, Yong-Kwang;Lee, Yang-Soo;Yun, Seong-Ho;Park, Moo-Eon
    • Korean Journal of Soil Science and Fertilizer
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    • v.28 no.2
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    • pp.183-190
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    • 1995
  • Various factors such as sampling height in the chamber, sampling interval, sampling time at daytime and the effects of pedoturbation on methane emission during chamber installation were evaluated using a simplified closed static chamber method to measure methane flux in paddy soils. Sampling height of the chamber for representative samples was 65cm. An additional DC fan was required to attain an even methane gradient in the chamber. Considering the change of methane concentration and air temperature in the chamber, sampling is recommended to finish within 30 minutes after starting sampling. The aim of setting DC fan in the chamber was to get the thermal equilibrium in the chamber as well as the representative samples. Suitable time to collect the gas samples representing the day's methane flux was 0900~1200 hours. Gas sampling was possible even after installation of small chambers if the elapsed time was more than 6 hours and supporting stand would be to be added to minimize pedoturbation.

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Preparation and Characterization of Planar-type Artificial Calamine Powder with a High Aspect Ratio for the Application to Ultraviolet and Blue Band Protection Cosmetics (자외선 및 블루영역 차단 화장품 응용을 위한 박막 판형 인공 칼라민 소재의 합성 및 특성 평가 연구)

  • Lee, Jung-Hwan;Lee, Gun-Sub;Jo, Dong-Hyeon;Hong, Da-Hee;Yu, Jae-Hoon;Gwack, Ji-Yoo;Lee, Hee-Chul
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.47 no.3
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    • pp.227-235
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    • 2021
  • In this study, we have prepared pure planar-type ZnO and calamine powder containing both ZnO and Fe2O3 components as a raw material for cosmetics with UV and blue band blocking functions. The planar-type ZnO ceramic powder having a high aspect ratio in the range of 20:1 to 50:1 was synthesized by precipitation method in a zinc acetate and sodium citrate mixed solution with the electrolyte obtained by power generation with a zinc-air battery. The content of Fe2O3 in the artificial calamine ceramic powder could be increased by increasing the amount of iron chloride solution added, and in this case, some of the blue region of visible light and ultraviolet light were remarkably absorbed. When potassium acetate was added, the decomposition of the Zn(OH)42- anion in the solution was promoted to facilitate the growth of ZnO crystal in the form of a barrier wall in the vertical direction on the (0001) plane, which could increase UV absorption by providing more opportunities. By controlling the amount of iron chloride solution and potassium acetate solution added, the composition and shape of the thin film plate-shaped artificial calamine ceramic powder can be optimized, and when applied to cosmetic formulations, the light transmittance of the blue region can be greatly reduced.

Study on Bearing Capacity of Ultra High Strengh End Extended PHC Pile by Loading Test (재하시험을 통한 초고강도 선단확장 PHC말뚝의 적용성 연구)

  • Hwang, Ui-Seong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.3
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    • pp.269-275
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    • 2019
  • As the national industry is developing gradually due to the expansion of the economic scale, the construction of large and super high-rise structures for building social infrastructure has been increasing, and studies have been conducted actively to transmit the large loads at the upper portion to the lower bedrock. In this study, the PHC was extended to an ultra-high strength PHC, which increased the concrete compressive strength of the PHC from the conventional 80 MPa to 110 MPa, and the PHC, which extended the tip of the pile. After construction with the driving method and injected pile method, the tendency of the bearing capacity was tested through a load test. Measurements of the bearing capacity of the extended PHC using the pile driving method revealed the main surface friction force to be smaller than that of the general PHC, and the stet-up effect was also insignificant. On the other hand, the effect of the friction force on the ground surface when the injected pile method was applied is expected to increase the bearing capacity when the gap between the main surface and the ground is wide and the cement paste is filled tightly. In addition, the ultrahigh strength PHC showed higher bearing capacity than the conventional PHC, and the permissible pile stress was less than 60%. Therefore, it is possible to reduce the number of piles and reduce the construction cost and effect of shortening the length of the pile by designing the tip of the pile on the ground with the intensity of soft rock as a method for utilizing the increased strength of the ultra-high strength PHC.

A Study on the Synthesis and Electrochemical Characteristics of Carbonized Coffee Powder for Use as a Lithium-Ion Battery Anode (리튬 이온 이차전지 음극 활물질용 탄화 커피 분말 제조 및 전기화학적인 특성연구)

  • Kim, Tae Gyun;Cho, Jin Hyuk;Pham-Cong, De;Jeon, Injun;Hwang, Jin Hyun;Kim, Kyoung Hwa;Cho, Chae Ryong
    • New Physics: Sae Mulli
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    • v.68 no.12
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    • pp.1315-1323
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    • 2018
  • We studied the carbonization due to the annealing condition of waste coffee powder for application as an active anode material for lithium-ion batteries (LIBs). The coffee powder used as an active anode material for LIBs was obtained from coffee beans, not from a coffee shells. The waste coffee powder was dried in air and heat-treated in an $Ar/H_2$ atmosphere to obtain a pore-forming activated carbon powder. The specific capacity of the sample annealed at $700^{\circ}C$ was still 303 mAh/g after 1000 cycles at a current density of 1000 mA/g and with a coulombic efficiency of over 99.5%. The number of pores and the pore size of the waste coffee powder were increased due to chemical treatment with KOH, which had the some effect as an increased specific surface area. The waste coffee powder is considered to be a very promising active anode material because of both its excellent electrochemical properties due to enhanced carrier conduction and its being a cost effective resource for use in LIBs.