• Title/Summary/Keyword: 비이오 연료

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Extraction of Intracellular Lipids from Recombinant E. coli for Improving Long-chain Fatty Acid Production (긴 사슬 지방산 생산을 위해 재조합된 E. coli로부터의 세포 내 지질 추출)

  • Ham, Su Mi;Yoo, In Sang;Park, Sang Joon;Kim, Ji Hyeon
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.482-486
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    • 2013
  • Recently, biohydrocarbons are gathering an interest as a new bioenergy due to the versatile applicability. In the present work, a process is proposed for the recovery of lipids from Recombinant E. coli MG1655 which provides longer chain fatty acids. After the growth of the recombinant E. coli, the cells were disrupted by high pressure homogenizer for obtaining intracellular lipids and the resulting solutions were centrifuged and extracted. For the efficient cell disruption with high pressure homogenizer, the pressure higher than 5,000 psi was required. In addition, under the conditions of applied pressure 5,000 to 20,000 psi, 1~3 pass homogenizing was enough for the more than 90% cell disruption. As organic solvents for extraction of lipid, hexane/isopropyl alcohol and ethyl acetate/ethanol systems showed excellent extracting power. With these solvent systems, the 60% lipid could be recovered. Moreover it was found that the extracted lipids contained long-chain fatty acids such as $C_{12}$, $C_{14}$, $C_{16}$ and $C_{18}$.

Synthesis of Mesoporous Pt-Au Alloy Electrode by Electrodeposition Method for Direct Methanol Fuel Cell (전기화학적 증착법에 의한 직접 메탄올 연료전지(DMFC)용 메조포러스 백금-금 합금전극제조)

  • Park, Eun-Kyung;Ahn, Jae-Hoon;Kim, Young-Soo;Kim, Kyung-Hwa;Baeck, Sung-Hyeon
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.727-731
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    • 2008
  • Mesoporous Pt-Au alloy films were successfully fabricated on ITO-coated glass by electrodeposition method using tri-blockcopolymer (P123) as a templating agent. The electrolyte consisted of 10 mM hydrogen hexachloroplatinate ($H_2PtCl_6$), 10 mM hydrogen tetrachloroaurate ($HAuCl_4$), and proper amount of P123. For comparison, control samples were electrodeposited without $HAuCl_4$ and P123. Film composition was determined by EDS(Energy Dispersive X-ray Spectroscopy), and the mesoporous structure was confirmed by TEM(Transmission Electron Microscopy). SEM(Scanning Electron Microscopy) was utilized to examine surface morphology, and it was observed that the addition of P123 affected the particle growth, resulting in the significant change of surface morphology. Methanol oxidation and CO oxidation were carried out to investigate electrocatalytic activities of synthesized samples. It was observed that the catalytic activity was strongly dependent on the film compositions. Compared with nonporous electrode prepared without P123 templating, mesoporous films prepared with P123 templating showed much higher catalytic activities and stability for both methanol oxidation and CO oxidation. These enhanced electrocatalytic activities were due to the high surface area and facilitated charge transfer of mesoporous films.

Effects of Lettuce Cultivation Using Optical Fiber in Closed Plant Factory (폐쇄형 식물공장내 태양광 파이버를 이용한 상추 재배효과)

  • Lee, Sanggyu;Lee, Jaesu;Won, Jinho
    • Journal of Bio-Environment Control
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    • v.29 no.2
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    • pp.105-109
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    • 2020
  • This study was conducted to the improvement of solar light-based artificial light supply system and effect of lettuce cultivation. The artificial light supply system was consisted of units such as light source, power, system measurement and controller. The light source supply was composed of a solar transmitter and an LED lamp. The power supply consisted of an leakage breaker, SMPS, LED controller and relay. The solar transmitter was made of a quartz optical fiber with optimal light transmission. Artificial light used white lamp among LEDs. System measurement and control consisted of touch screen, Zigbee communication module and light quantity sensor. The results of test confirmed that the LED light is automatically activated when the intensity measured by the light intensity sensor is 200 μmolm-2s-1 or less. Moreover, the leaf length, root length, chlorophyll content and root fresh weight of optical fiber treatment was hight than LED lamp treatment. Therefore, it can be inferred that the energy-saving solar light collector device can be effective in the indoor lettuce production. However, the use of LED lamp is also recommended to assure the availability of sufficient sunlight in cloudy and rainy days.

Comparison of Control Strategies for Military Series-Type HEVs in Terms of Fuel Economy Based on Vehicle Simulation (시뮬레이션을 이용한 군용 직렬형 HEV 의 주행 전략에 따른 연비 성능 비교에 관한 연구)

  • Jung, Dae-Bong;Kim, Hyung-Jun;Kang, Hyung-Mook;Park, Jae-Man;Min, Kyoung-Doug;Seo, Jung-Il
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.1
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    • pp.31-36
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    • 2012
  • Military vehicles, compared to conventional vehicles, require higher driving performance, quieter operation, and longer driving distances with minimal fuel supplies. The series hybrid electric vehicle can be driven with no noise and has high initial startup performance, because it uses only a traction motor that has a high startup torque to drive the vehicle. Moreover, the fuel economy can be improved if the vehicle is hybridized. In series hybrid electric vehicles, the electric generation system, which consists of an engine and a generator, supplies electric energy to a battery or traction motor depending on the vehicle driving state and battery state of charge (SOC). The control strategy determines the operation of the generation system. Thus, the fuel economy of the series hybrid electric vehicle relies on the control strategy. In this study, thermostat, power-follower, and combined strategies were compared, and a 37% improvement in the fuel economy was implemented using the combined control strategy suggested in this study.

Analysis of Cost Saving Effect on Stakeholders according to Performance Improvement of Harbor Cranes - The Yeosu Bulk Terminal (항만 양하 크레인의 성능 개선에 따른 이해관계자들의 비용 절감 효과 분석 - 여수 벌크 터미널 중심으로 -)

  • Park, Sang-Kook
    • Journal of Korea Port Economic Association
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    • v.33 no.2
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    • pp.97-109
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    • 2017
  • The Terminal Operating Company (TOC) decides to replace the harbor cranes in order to increase revenue and profit through the improvement of unloading efficiency. To achieve this goal, substantial costs and efforts are necessary. However, the conative participation of harbor stakeholders is needed, because they will certainly be passionate enough when expected effects are obvious. The purpose of this study is to analyze the effect on stakeholders on direct and indirect cost saving when the cargo handling equipment is replaced. According to the analysis, a total cost saving of 6,561.8 million won will arise including a vessel chartering fee of 3,649.6 million won, a port facility fee of 1,528.8 million won, and fuel costs of 1,383.4 million won as direct effects. As indirect cost effects, a total cost saving of 3,107.0 million won will emerge including an environmental pollution cost of 2,134.8 million won and a freight inventory cost of 972.2 million won. Consequently, the replacement of harbor cranes in the TOC has positive effects on shipping companies, shippers, and the government in terms of costs and other aspects. The results of this study can be utilized as a basis to draw a conative cooperation of stakeholders on TOC's promotion of the harbor cranes replacement.

Synthesis and Characterization of a Series of PtRu/C Catalysts for the Electrooxidation of CO (일산화탄소 산화를 위한 PtRu/C 시리즈 촉매의 합성 및 특성 연구)

  • Lee, Seonhwa;Choi, Sung Mook;Kim, Won Bae
    • Clean Technology
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    • v.18 no.4
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    • pp.432-439
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    • 2012
  • The electrocatalytic oxidation of CO was studied using carbon-supported 20 wt% PtRu (PtRu/C) catalysts, which were prepared with different Pt : Ru atomic ratios from 7 : 3 to 3 : 7 using a colloidal method combined with a freeze-drying procedure. The bimetallic PtRu/C catalysts were characterized by various physicochemical analyses, including X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). CO stripping voltammetry measurements indicated that the addition of Ru with a Pt catalyst significantly improved the electrocatalytic activity for CO electrooxidation. Among the tested catalysts, the $Pt_5Ru_5/C$ catalyst had the lowest onset potential (vs.Ag/AgCl) and the largest CO EAS. Structural modification via lattice parameter change and electronic modification in the unfilled d band states for Pt atoms may facilitate the electrooxidation of CO.

A Study on the boiler efficiency with selecting the uppermost burners in the 870MW opposite wall fired boiler (870MW 대향류 보일러에서 최상부층 버너 선택운전에 따른 보일러 효율변화 고찰)

  • Woo, Gwang-Yoon;Kim, Soo-Seok;Park, In-Chan;Ham, Young-Jun;Lee, Eung-Yoon
    • Plant Journal
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    • v.13 no.2
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    • pp.46-51
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    • 2017
  • In this study, the boiler efficiency and the change of boiler combustion state with the burner operation of the uppermost layer of 870MW opposite fired coal boiler were measured. Test results showed that the boiler efficiency was high in the order of the uppermost layer simultaneous operation of the front and rear burners, the front burner, and the rear burner operation. When the front and rear burners were operated simultaneously, the heat absorption rate of water walls in the boiler furnace was uniform at four side, and the temperature deviation of the left and right steam on the convection front surface decreased. As the heat absorption rate of the boiler improved, the loss of boiler exhaust gas decreased and the coal supply amount decreased by 8 tons/hour compared to the operation of the rear burner. This will contribute not only to the reduction of fuel cost but also to the reduction of greenhouse gas emissions.

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Effect of Branching-agent Content on the Electrochemical Properties of Partially Fluorinated Poly(Arylene Ether Sulfone) Block Ionomer Membranes (부분불소계 Poly(Arylene Ether Sulfone) 블록이오노머막의 전기화학적 특성에 대한 분지체 함량의 효과)

  • Jeon, Seong-Hoon;Chang, Bong-Jun;Kang, Ho-Cheol;Kim, Jeong-Hoon;Joo, Hyeok-Jong
    • Membrane Journal
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    • v.21 no.1
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    • pp.1-12
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    • 2011
  • Partially fluorinated poly(arylene ether sulfone) block ionomer membranes with different branch degree for fuel cell applications were investigated. A sulfonable monomer, a non-sulfonable monomer and a trifunctional branching agent were synthesized and the sulfonable monomer was oligomerized to obtain block structures. The oligomer was then further polymerized with the non-sulfonable monomer and the branching agent. The mole ratio of oligomer : non-sulfonable monomer was fixed at 4:6 and the content of the branching agent was varied from 0 to 2 mol% (BBC-40Bx). Post-sulfonation of BBC-40Bx was carried out using chlorosulfonic acid (CSA) (SBBC-40Bx). All the synthesized compounds were characterized by $^1H$-NMR, $^{19}F$-NMR and FT-IR. It was confirmed that the ion exchange capacity (IEC), water uptake and ion conductivity of SBBC-40Bx increased with the increment of branching agent content.

A Study on the Climate Change and the Policy of Natural Gas Exploitation on the Arctic Region (기후변화와 북극 유·가스전 개발에 관한 연구)

  • Kim, Boyoung;Ryu, Siho;Park, Yonhe
    • Environmental and Resource Economics Review
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    • v.18 no.4
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    • pp.787-813
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    • 2009
  • Because of global warming, the thawing of the Arctic ice cap is slowly accelerating. That is the hot issue nowadays. According to the each country's climate change policy, it is boom in the world to lessen the consuming of the fossil fuel those are oil, coal and natural gas. But on the contrary the thawing of the Arctic ice cap is the chance to make the natural gas producing unit cost lower. The purpose of this paper is to search the Arctic policy of each country under the contradictory relationship between promoting the climate change policy and exploiting the natural gas on the Arctic. Specially, there are huge natural gas reserves in Russia on the Arctic region, Russia's exploiting the natural gas on the Arctic will affect on the natural gas supply-demand balance of world natural gas market strongly in the future. Therefore it needs to prepare the future energy alternative policy for Korea's energy security. Russia has Yamal Peninsular where is abundant on natural gas reserver, and she can supply natural gas by LNG ship all over the world via the Arctic route. This means that the structure of world natural gas market be changed gradually. It will be possible in 2030~2040. And such a change is very important because new natural gas trading type can do it through not only overcoming the geological restriction but also shifting the main trading type from PNG(Pipeline Natural Gas) to LNG(Liquified Natural Gas). Therefore it is necessary that we should let this be a good lesson to ourselves through the government action of other countries (China, Japan) those also have no sovereignty over the Arctic as Korea.

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Investigation of Tar/soot Yield of Bituminous and Low Rank Coal Blends (발전용 역청탄과 저열량탄 혼소시 Tar/Soot의 배출 특성 연구)

  • Lee, Byung Hwa;Kim, Jin Ho;Kim, Gyu Bo;Kim, Seng Mo;Jeon, Chung Hwan
    • Journal of Energy Engineering
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    • v.23 no.2
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    • pp.42-48
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    • 2014
  • Soot and tar which were derived from combustion or pyrolysis processes in Puverized Coal(PC) furnace or boiler have been significantly dealing in a radiative heat transfer and an additional source of NOx. Furthermore, the increasing for the use of a coal with low caloric value gives rise to a lot of tar-soot yield and LOI in a recycled ash for using cement materials. So, the ash with higher tar-soot yield and LOI can not recycle due to decreased strength of concrete. In this study, tar-soot yields and flame structures were investigated using the LFR for a blending combustion with bituminous coal and sub-bituminous coal. Also, The investigation were conducted as each single coals and blending ratio. The coals are used in a doestic power plant. In the experimental results, sub-bituminous coal with high volatile contents shows longer soot cloud length than bituminous coal, but overall flame length was shorter than bituminous coal. Tar-soot yields of sub-bituminous coal is lower than those of bituminous coal. Combustion characteristics are different between single coal and blended coal. Therefore, finding an optimal coal blending ratio according to coal rank effects on tar-soot yields.