• Title/Summary/Keyword: 비소 및 중금속

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A Study on the Sanitation Condition for Products of Powdered Raw Grains and Vegetables (곡류 가공품 등의 위생실태에 관한 조사 연구)

  • Cho, Bae-Sick;Gang, Gyung-Lee;Lee, Hyang-Hee;Ha, Dong-Ryong;Kee, Hye-Young;Seo, Kye-Won;Kim, Eun-Sun;Park, Jong-Tae
    • Journal of Food Hygiene and Safety
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    • v.22 no.4
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    • pp.273-278
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    • 2007
  • Recently, the demand for the powdered products to process raw grains and vegetables has been expanded, and the growth possibility of their fields(markets) in the future will be highly valued with the westernization of living environment and the change of the dietary life. We have bought and analyzed the 111 products of raw grains and vegetables from the large-sized marts, markets and internet orders from March to October 2006. The rate of moisture content was $1.7{\sim}12.5%$. We also found out that the foods over 10% moisture content was 8 of those samples we bought or collected. Their ash rates were averagely $0.3{\sim}8.6%$. The number of those foods that the alien substances were detected was 2. The tar pigments, artificial sweeteners and sulfur dioxides of components that contained food additives were not detected. Each detection range of Cadmium, Lead and Arsenic of the injurious heavy metals was non-detectable $(nd){\sim}0.55,\;nd{\sim}4.52,\;nd{\sim}0.10mg/kg$, while the average detection content were 0.08, 0.48, 0.01 mg/kg. By investigating the contamination degree of the microflora, we discovered that the number of the aerobic plate count, B. cereus over 1,000 cfu/g and C. perfringens over 100 cfu/g was 36 (32.4%), 9 (8.1%) and zero, and that the whole sanitation condition of the products of powdered raw grains and vegetables circulated in the market was not so good.

Characteristics on Chemical Activation and VOCs Adsorption of Activated Carbon according to Mixing Ratio of Anthracite and Lignite (활성탄 제조시 유·무연탄 혼합에 따른 화학적 활성화 및 휘발성유기화합물 흡착 특성)

  • Cho, Joon-Hyung;Kang, Sung-Kyu;Kang, Min-Kyoung;Cho, Kuk;Oh, Kwang-Joong
    • Clean Technology
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    • v.23 no.4
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    • pp.364-377
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    • 2017
  • In this study, to improve the low surface area of domestic anthracite as raw materials of activated carbon, characteristics on chemical activation and VOCs adsorption of activated carbon according to mixing ratio of anthracite and lignite. For these, properties of raw materials, parameter characteristics of preparation processes for activated carbon, and VOCs adsorption characteristic of the prepared activated carbon are analyzed. The experimental results showed that, the domestic anthracite had disadvantages of high contents for ash and lead, arsenic, which were exceeded for the heavy metal limits, in the properties of raw materials. To improve these diadvantages, using the mixing ratio of anthracite and lignite, and the optimum conditions for pretreatment, activation, washing, and pellitization process, the activated carbon had a range of BET (Brunauer-Emmett-Teller) surface area of $1,154{\sim}1,420m^2g^{-1}$ with mesopore development and hydrophobic surface property. The carbons were satisfied with the quality standard for granular activated carbon, and had similar physicochemical properties with the commercial activated carbon. The minimum mixing condition for commercial VOCs activated carbon performance must have the caloric value of above $5,640kcal\;kg^{-1}$, and the carbon had higher adsorption capacity with order of xylene > toluene > benzene according to more higher molcular weight and hydrophobic property.

Effects of Distiller Solubles(Bekseju) Application on the Growth of Rice Plant(Oryza sativa L.) and Improvement of Soil Fertility (백세주 주정박이 벼의 생육과 토양비옥도 개선에 미치는 영향)

  • Kim, In-Su;Ryu, Su-Jin;Choe, Yeong-Hwan;Park, Young-Gu;Kim, Gye-Won;Bae, Jung-Ho
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2009.12a
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    • pp.306-306
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    • 2009
  • 본 실험은 백세주 주정박이 벼의 생육과 토양 비옥도 개선에 미치는 영향을 조사하였다. 백세주 주정박은 압착된 주박을 재 발효시켜 단식증류기로 증류하여 알코올을 회수 후 발생된다. 실험 처리구는 무시용, 요소, 주정박 처리구로 하였고, 벼 질소비료 표준시비량 11kg N/10a를 기준으로 하여 전량 기비로 사용하였다. 백세주 주정박의 유효성분과 유해성분을 분석하였고, 토양에 주정박을 시용 전 후의 이화학적 분석을 하였다. 벼 실험 품종은 오대벼(Oryza sativa L.)이고, 벼의 생육과 수량 및 미질을 분석하였다. 백세주 주정박의 pH는 3.60, 유기물함량 90.12%, 염농도 0.72ds/cm, 수분함량 88%, 질소 0.21%, 인산 0.24%, 칼리 0.09%로 나타났다. 유해성분(중금속)분석결과 비소 0.03ppm, 크롬 0.09ppm, 구리0.91ppm, 납 0.05ppm, 니켈 0.05ppm, 아연 1.30ppm, 망간 3.28ppm, 철 34.86ppm로 나타났다. 토양이화학적 분석결과 주정박 시용처리구의 유기물함량과 질소 및 인산은 각각 23.0g/kg. 0.11%, 89mg/kg로 무시용과 요소처리구에 비해 유의한 차이를 보였다. 벼 이식 후 140일째 생육분석결과 초장 82.60cm, 옆폭 1.40cm, 옆장 37.70cm, 지상부건물중 59.21g로 다른 2개 처리구에 비해 유의한 차이를 보였다. 벼의 수량은 주정박 시용 처리구가 449.0kg/10a로 무시용 89.66kg/10a와 요소 401.66kg/10a에 비해 유의적인 차이를 보였다. 백세주 주정박 시용을 통해 토양 개량 효과를 기대할 수 있고, 공시 토양의 토양 개량 효과가 벼의 생육에 긍정적인 영향을 끼치는 것으로 나타남에 따라 백세주 주정박의 토양개량제로서의 활용 가능성을 확인하였다.

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A Study on Hygiene and Safety of Sanitary Wet Towel (물수건의 위생실태 및 안전성 연구)

  • Kim, Young-Sug;Kim, Yang-Hee;Kim, Young-Su;Kim, Dae-Hwan;Ryu, Kyong-Shin;Yoon, Mi-Hye
    • Journal of Food Hygiene and Safety
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    • v.31 no.4
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    • pp.258-263
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    • 2016
  • The risks of sanitary indicative bacteria, heavy metals and chlorinated derivatives in 94 cases of sanitary wet towels used in food services (39 from sanitary wet towel treatment business, 55 from food services) were assessed in the present study. Lead was detected in the range of N.D.~0.41 mg/kg (75 cases were not detected), N.D.~0.25 mg/kg of arsenic (93 cases were not detected), N.D.~0.01 mg/kg of cadmium (7 cases were lower than limit of quantitation; 87 cases were not detected), 0.003 mg/kg ~ 0.09 mg/kg of mercury. And chromium (VI) was not detected from all samples. The level of lead was the highest among the tested heavy metals, and the highest concentration of lead was 0.41 mg/kg. However, it was only 2.1% of legal limit (less than 20 mg/kg). The average moisture content of the samples was 61.9% (50.0% ~ 77.0%) and it showed no relevance to the detection of bacterial counts. Escherichia coli was not detected. Bacterial counts were detected 43 cases and among them, 24 cases were exceeded the legal limit. It was verified that the packaging conditions of sanitary wet towel (whether it is packed by a piece or not and sealed or not) are critical factors to cause the germ contamination and cross contamination in the wet towels. The chlorinated derivatives (chlorites and chlorates) were detected in 17 (19.3%) out of 88 cases. The results would be used as preliminary information to establish the programs of "Safety education for manufacturers and public policy of safety".

Functional Cosmetic Effect of Porcine Placeta (Porcine Placenta의 기능성 화장품소재 특성)

  • Kim, Bo Young;Kim, Tagon;Kang, Whan Yul;Baek, Hyun;Cheon, Hae Young;Kim, Donguk
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.327-331
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    • 2010
  • Porcine placenta was treated with alkali, acid and enzyme treatment to obtain extracts. Heavy metal contents such as Pb, As, and Hg were low enough to satisfy cosmetic agent standard. As a result of safety test(MTT assay), porcine placenta extracts showed over 80% of cell viability at $50{\mu}g/ml$, and cell toxicity was relatively lower. From antioxidation test using DPPH free radical scavenging assay, antioxidation effect was highest as 63% at $50{\mu}g/ml$ when porcine placenta was treated with alkali in pH 9. From whitening effect test using tyrosinase inhibition assay, tyrosinase inhibition effect was 30% at $50{\mu}g/ml$ concentration in alkali treated procine placenta, however, the efficiency was lower compared with arbutin or vitamin C. In anti-wrinkle effect test from elastase inhibition assay, elastase inhibition effects were 20~30% at $50{\mu}g/ml$ for 5 kinds of porcine placenta treatments, which was superior to standard, and especially, protease treated extracts showed best results. Skin formulation including 1% porcine placenta was made and the formulation was very stable for temperature and storage period. From this research, porcine placenta extract showed high potential for anti-wrinkle functional cosmetic agent.

Study on the Chemical Compositions of Sun-dried, Refined, and Processed Salt Produced in Chonbuk Area (전라북도내 천일염, 재제 및 가공염의 성분 조사에 관한 연구)

  • 조은자;신동화
    • Journal of Food Hygiene and Safety
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    • v.13 no.4
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    • pp.360-364
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    • 1998
  • The sun-dried, refined, and processed salt (roasted and bamboo salt) manufactured in Chonbuk province were analyzed their chemical compositions and minerals including heavy metals for safety evaluation. Average content of each eomponent as the lowest and the highest were as follows-pH; 6.80 (refined) to 10.35 (bamboo), water content; 0.13% (bamboo) to 10.7% (sun-dried), sodium chloride; 96.6% (roasted) to 84.3% (sun-dried), 804; 0.59% (bamboo) to 3.0% (sun-dried), water insoluble matters; 0.001% (refined) to 1.98% (bamboo), acid inoluble matters; <0.001% (refined) to 0.21% (bamboo), calcium; 0.038% (refined) to 0.213% (sun-dried), magnesium; 0.111% (refmed) to 1.078% (sun-dried), lead; 0.45 ppm (refmed) to 1.15 ppm (bamboo). Cadminium, arsenic and mercury were not detected in all salt. As the analytical results, all salts were differtent in their chemical compositions and safe in view of heavy metals.

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Mechanical and Germination Characteristics of Stabilized Dredged Soil (고화준설토의 역학적 특성과 식생 발아 특성)

  • Lee, Miji;Mun, Kyoungju;Yoon, Gillim;Eum, Hyunmi;Kim, Yuntae
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.3
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    • pp.33-40
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    • 2014
  • In this paper, mechanical and germination characteristics of stabilized dredged soils were investigated to recycle dredged soil in eco-friendly manner such as waterfront construction. Non sintering binder (NSB), which was developed by using interchemical reactions between slag, high-calcium fly ash, alkali activator on the dredged marine clay, was added to dredged soil. Ordinary portland cement was also used for the comparison of two binders. Experimental tests such as flow test and unconfined compressive test were carried out to evaluate characteristics of stabilized dredged soil. Leaching test, pH measure, vegetation germination test were also conducted to consider environmental applicability. The unconfined compressive tests shows that unconfined compressive strength (UCS) also increases with the increase of curing time and mixed ratio. UCS of NSB mixtures were higher than those of OPC mixtures. Germination tests showed that germination and sprouting date are better in NSB mixture than OPC mixture. It can be explained that germination decreased as pH and 7-day strength increased.

Stabilization of Two Mine Drainage Treated Sludges for the As and Heavy Metal Contaminated Soils (오염토양 특성별 광산배수처리슬러지의 비소 및 중금속 안정화)

  • Tak, Hyunji;Jeon, Soyoung;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.27 no.4
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    • pp.10-21
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    • 2022
  • In the South Korea, 47% of abandoned mines are suffering from the mining hazards such as the mine drainage (MD), the mine tailings and the waste rocks. Among them the mine drainage which has a low pH and the high concentration of heavy metals can directly contaminate rivers or soil and cause serious damages to human health. The natural/artificial treatment facilities by using neutralizers and coagulants for the mine drainage have been operated in domestic and most of heavy metals in mind drainage are precipitated and removed in the form of metal hydroxide, alumino-silicate or carbonate, generating a large amount of mine drainage treated sludge ('MDS' hereafter) by-product. The MDS has a large surface area and many functional groups, showing high efficiency on the fixation of heavy metals. The purpose of this study is to develop a ingenious heavy metal stabilizer that can effectively stabilize arsenic (As) and heavy metals in soil by recycling the MDS (two types of MDS: the acid mine drainage treated sludge (MMDS) and the coal mine drainage treated sludge (CMDS)). Various analyses, toxicity evaluations, and leaching reduction batch experiments were performed to identify the characteristics of MDS as the stabilizer for soils contaminated with As and heavy metals. As a result of batch experiments, the Pb stabilization efficiency of both of MDSs for soil A was higher than 90% and their Zn stabilization efficiencies were higher than 70%. In the case of soil B and C, which were contaminated with As, their As stabilization efficiencies were higher than 80%. Experimental results suggested that both of MDSs could be successfully applied for the As and heavy metal contaminated soil as the soil stabilizer, because of their low unit price and high stabilization efficiency for As and hevry metals.

Evaluation of Characteristics of Sludge generated from Active Treatment System of Mine Drainage (광산배수의 적극적 처리시설에서 발생하는 슬러지 특성 평가)

  • Jung-Eun Kim;Won Hyun Ji
    • Economic and Environmental Geology
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    • v.56 no.4
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    • pp.409-419
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    • 2023
  • Acid mine drainage(AMD) treatment is classified as both passive and active treatment. During the treatment, about 5,000 tons of neutralization sludge is generated as a by-product per year in Korea. This study was conducted to evaluate the characteristics of sludge generated from physico·chemical treatment processes as an active treatment from 5 different sources (D, H, S, T, Y) and the possibility of the sludges being recycled. The sludges have a pH range of 5.86 ~ pH 7.89, and a water content range of 51% ~ 82%. Most of particle sizes were less than 25 ㎛. In analysis of inorganic elements, the concentration of Al, Fe, and Mn were between 1,189 mg/kg ~ 129,344 mg/kg, 106,132 mg/kg ~ 338,011 mg/kg, and 3,472 mg/kg ~ 11,743 mg/kg, respectively. The concentration of As and Zn in sludge-T, Cd in sludge-D, Ni in sludge-H, Zn in sludge-S, and Cd in sludge-Y exceeded the soil contamination standards of Korea. The results from 2 separate kinds of leaching test, the Korea Standard Leaching Test(KSLT) and Toxicity Characteristic Leaching Procedure(TCLP), showed that all the sludges met the Korea groundwater standards. From the XRD and SEM-EDS analysis, the peaks of calcite and quartz were found in the sludges. The sludge also had a high proportion of Fe and O, and the majority of the composition was amorphous iron hydroxide.

Improving the Nutritional Value of Tenebrio molitor Larvae by Feeding Them a Soymilk Residue-added Food Source (두유박 첨가 먹이원 급이에 따른 갈색거저리 유충의 영양성 증진 효과)

  • So-Yun Kim;Min Ji Park;Jeong-Hun Song;Sangmin Ji;Gyu-Dong Chang;Sun Young Kim
    • Journal of Life Science
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    • v.34 no.3
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    • pp.191-198
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    • 2024
  • To verify the nutritional value and safety of larvae fed with a soymilk residue-added food source, we compared and analyzed the nutritional components of and harmful substances in Tenebrio molitor larvae reared on wheat bran. Crude protein content based on dry weight was 1.2 times higher in the 10% soymilk residue-fed group (SR) (54.0%) than in the wheat bran-fed group (WB) (43.5%). Dietary fiber also tended to be 1.9 times more in the SR (4.9%) than the WB (2.5%). Among unsaturated fatty acids, the linoleic acid content was found to be 1.1-fold higher in the SR (32.9%) than in the WB (29.0%). Potassium, which was the most abundant among the macro minerals, was 1.1-fold more abundant in the WB (1,074.5 mg/100 g) than in the SR (1,014.0 mg/100 g). Among the micro minerals, zinc content was 1.2-fold higher in the SR (14.5 mg/100 g) than in the WB (11.9 mg/100 g). The results of the analysis of hazardous substances in the WB and SR revealed that the amount of heavy metals met the standards for heavy metals in edible insects, and food poisoning-inducing bacteria such as Escherichia coli and Salmonella spp. were not detected in all groups. These results indicate that mealworm larvae fed with 10% soymilk residue have abundant nutrients and are safe for intake. Thus, food sources with added soymilk residue has the potential to be used as feed ingredients.