• Title/Summary/Keyword: 비방사능

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Determination of % Contents of Uranium and Thorium in Natural Radioactive Ores by ${\gamma}$-ray Spectrometry (${\gamma}$-선 분광법을 이용한 한국산 방사성 원광내의 Uranium Thorium 함유량 측정)

  • 조성원;정문규;유건중;홍치유
    • Nuclear Engineering and Technology
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    • v.2 no.4
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    • pp.273-278
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    • 1970
  • The Contents of uranium and thorium in radioactive ores produced in Korea were determined by gamma-ray spectrometry utilizing Ge (Li) diode detector. Both methods, namely, gamma-ray spectrometries of activated samples and non-activated samples, were tested and compared for their accuracies and rapidness in determination of contents. Also the useful-ness of application of Ge(Li) diode detector to the determination of uranium and thorium contents in ores was discussed in detail.

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Synthesis and Evaluation of $2-[^{18}F]Fluoro-A85380$, a Radioligand for ${\alpha}_4{\beta}_2$ Nicotinic Acetylcholine Receptor Imaging (${\alpha}_4{\beta}_2$ 니코틴성 아세틸콜린 수용체 영상 방사성리간드 $2-[^{18}F]fluoro-A85380$의 합성 및 평가)

  • Ryu, Eun-Kyoung;Choe, Yearn-Seong;Kim, Sang-Eun;Hwang, Sae-Hwan;Paik, Jin-Young;Choi, Yong;Lee, Kyung-Han;Kim, Byung-Tae
    • The Korean Journal of Nuclear Medicine
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    • v.36 no.4
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    • pp.261-270
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    • 2002
  • Purpose: Nicotinic acetylcholine receptors (nAChRs), which mediate excitatory neurotransmission, are known to participate in various neurophysiological functions. Severe losses of nAChRs have been noted in Alzheimer's and Parkinson's diseases. Therefore, noninvasive and quantitative imaging of nAChRs would offer a better understanding on the function of these receptors. In this study, $2-[^{18}F]fluoro-A85380\;([^{18}F]1)$, an ${\alpha}_4{\beta}_2$ nAChRs radioligand, was prepared using one HPLC purification and evaluated in mouse brain, and the results were compared with those in the literature. Materials and Methods: $[^{18}F]1$ was prepared by $[^{18}F]$fluorination of the iodo precursor followed by acidic deprotection and then purified by HPLC. Tissue distribution studies were performed in mouse brain at the indicated time points and the result was expressed as %ID/g. Inhibition studies were also carried out with pretreatment of various ligands. Results: One HPLC purification method gave the desired product in 15-20% radiochemical yield and with high specific activity ($38-55GBq/{\mu}mol$). Tissue distribution studies showed that $[^{18}F]1$ specifically labeled nAChRs in mouse brain with a high thalamus to cerebellum uptake ratio (13.8 at 90 min). Inhibition studios demonstrated selective binding of $[^{18}F]1$ to nAChRs, blocking the uptake of the $[^{18}F]1$ in nAChR-rich legions by selective ligands such as cytisine and nicotine which are well-known nAChRs agonists. Conclusion: This study demonstrated that the $[^{18}F]1$ produced by the method using one HPLC purification gave the results similar to those reported in the literature. Therefore, this synthetic method can be readily applied to the routine preparation of $[^{18}F]1$, a PET radioligand for ${\alpha}_4{\beta}_2$ nAChRs imaging.

Natural radioactivity of surface sediments by source regions of the asian dust (황사지역 발원지에 따른 표층퇴적물의 자연방사능 특성)

  • Lee, Kil Yong;Yoon, Yoon Yeol;Cho, Soo Young;Koh, Kyung Seok;Kim, Yongje
    • Analytical Science and Technology
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    • v.21 no.6
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    • pp.474-479
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    • 2008
  • Radioactivity of naturally occurring radioactive nuclides (NORN) such as $^{226}Ra$, $^{228}Ac$ and $^{40}K$ were investigated for surface sediments collected from Ordos, Alashan, Taklimakan deserts and Loess plateau regions in China. By a Gamma-ray spectrometry, specific activity (SA) and SA ratio (SAR) of the NORN were determined for each source region of Asian dust. Characterization of the source regions of Asian dust was performed with the SA and SAR values. SA of $^{226}Ra$ in the three desert regions have almost same values in the range of mean value 17.9~21.9 Bq/kg, however, the SA in Loess Plateau has much higher values in the mean value of 35 Bq/Kg. SA of $^{228}Ac$ in the Ordos and Alashan desert regions have almost same values in the range of mean value 27.1~27.2 Bq/kg, and those in Taklimakan desert and Loess Plateau were 31.7 and 49.0 Bq/kg, respectively. In case of 40K, the SA in all regions have similar values in the range of 636~943 Bq/kg. The mean SAR value of $^{226}Ra/^{228}Ac$ in four source regions was almost same in the range of 0.708-0.721. It is shown that relationship between $^{226}Ra$ and $^{228}Ac$ is clearly presented in the source regions. The mean SAR values of $^{226}Ra/^{40}K$, $^{228}Ac/^{40}K$ are 0.0209-0.056, 0.0287-0.0773, respectively.

Comparison of the Ion-exchange Method and Evaporation Method for the Detection of Radioactivity in Water (수중 방사능 측정시 이온교환농축법과 증발건조법의 비교)

  • Ji, Pyung-Gook;Park, Chong-Mook;Ro, Seung-Gy
    • Journal of Radiation Protection and Research
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    • v.13 no.2
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    • pp.52-56
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    • 1988
  • An ion-exchange method for the detection of radioactivity in water using ion-exchange resin in concentrating radioactive nuclides was compared with an evaporation method. The loss of the radioactive materials in the sample treated by the ion-exchange method was less by about 20% than that by the evaporation method. In addition, the evaporation method needed about 20 hours for evaporating one liter of the sample at $70^{\circ}C$, while the ion-exchange method spent 6 hours to adsorb and adsorb the same amount of the sample on the resin. Consequently, the ion-exchange method is more effective than the evaporation method for the treatment of the radioactively contaminated water and is especially suitable for detecting the low-level radioactivity in water.

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밀봉선원폐기물 처분을 위한 분류방안 도출

  • 이지훈;이태범;박주완;김창락
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.235-235
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    • 2004
  • 밀봉선원 폐기물은 크기가 작지만 특별한 관리 및 처분을 요하는 방사성폐기물이다. 특히 수거된 폐라듐선원의 경우 장기간의 관리가 필요하며, 음식물 보존이나 살균에 사용된 대형 밀봉선원 폐기물의 경우도 처분보다는 재활용도 고려하여야 한다. 이러한 밀봉선원의 특징은 작은 크기와 고건전성물질로 되어 있고 높은 비방사능을 갖는다는 것이며 따라서 처분시 보통의 방사성폐기물과는 달리 비균질폐기물의 특성을 고려한 안전성 평가가 필요하다.(중략)

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선택성 이온교환수지에 의한 Cs 함유 토양 제염폐액 정화

  • 원휘준;김계남;오원진;정종헌
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.131-132
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    • 2004
  • 원자력연구소에 보관 중인 오염 토양폐기물을 토양 세척법으로 제염하여 비 방사성폐기물화 한다면 그 부피를 10% 이하로 저감시킬 수 있으며 연구소의 고체 방사성폐기물 저장 용량을 크게 늘릴 수 있다. 1988년 발견 당시 오염 토양 폐기물의 주요 방사성 핵종은 Co-60 이었는데 시간경과에 따라 Cs-134, 137 이 주요 방사성 핵종이 되었다. 오염토양 폐기물의 60 % 이상은 방사능 농도가 극히 낮아 물리적으로 입도를 분리하거나 수 세척에 의해 비 방사성폐기물화 할 수 있음을 파악하였다.(중략)

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Oxidation Experiment of U-Ti Chip for the Treatment of Depleted Uranium Waste (감손우라늄 폐기물 처리를 위한 U-Ti 칩의 산화실험)

  • 강권호;정경환;문제선;김길정
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.103-106
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    • 1999
  • 감손우라늄(depleted uranium, DU)은 천연 우라늄에서 핵분열 물질인 U-235를 농축하는 과정에서 발생한다. U-235의 농도가 0.45%인 감손우라늄의 비방사능은 천연우라늄의 약70.8%에 분과하나 감손우라늄은 밀도가 19g/㎤으로 높고 천연우라늄에 비해 U-235의 농도가 상대적으로 낮기 때문에 외국의 경우는 방사선의 차폐체, 비행기나 헬리콥터 및 미사일의 무게중심제(counter-weight)로 사용되며 또한 플라이 휠 등 큰 내부에너지 저장을 위한 장치 등에 널리 이용되고 있다.(중략)

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Quenching Curves for VOCs in the Analysis of Groundwater $^{14}C$ using Liquid Scintillation Counter (액체섬광계수기를 이용한 지하수의 $^{14}C$ 측정에서 휘발성유기화합물(VOC)에 대한 소광곡선)

  • Lee, Kil-Yong;Cho, Soo-Young;Yoon, Yoon-Yeol;Ko, Kyung-Seok;Kim, Yong-Je
    • Journal of Soil and Groundwater Environment
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    • v.12 no.6
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    • pp.53-59
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    • 2007
  • Optimal quenching curves have been studied for the accurate analysis of $^{14}C$ in groundwater polluted by reducing efficiency of volatile organic compounds (VOCs) in liquid scintillation counter (LSC). The quenching parameters (SQP(E)) were measured for ten VOCs such as benzene, toluene, ethylbenzene, o-(m-,p-)xylene, trichloroethylene (TCE), tetrachloroethylene(PCE), carbon tetrachloride and chloroform. The quenching curves were plotted using $^{14}C$ standard solution and chloroform as a quenching agent. Optimal plotting conditions were determined for standard solution, LSC measuring time and the concentration of chloroform. The quenching effects of chlorinated organic compounds such as TCE, PCE, carbon tetrachloride and chloroform were greater than those of BTEX (benzene, toluene, ethylbenzene and xylene). Optimum measuring time was 100 minutes far 7,000 dpm/mL standard solution. A few mL of chloroform should be added for good quenching curves. These quenching curves have good correlation coefficients (> 0.99) and the curves could be applied to accurate analysis of $^{14}C$ in groundwater and tap water.

Degradation of [$^{14}C$]Carbofuran in Soils and Characterization of its Nonextractable Residues (토양중 [$^{14}C$Carbofuran의 분해 및 비추출성 잔류분의 특성)

  • Park, Chang-Kyu;Lee, Young-Deuk
    • Applied Biological Chemistry
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    • v.38 no.3
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    • pp.263-268
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    • 1995
  • A study was undertaken to compare degradation patterns of carbofuran in soils between submerged and upland moisture conditions [$3-^{14}C$]Carbofuran was treated in each soils at the rate of 1.0 mg/kg (87.8 kBq $^{14}C/50g$ soil) and the time-course analysis for distribution of radioactivity and degradation products were conducted. Differences in the pathway and rate of carbofuran degradation in soils were observed between submerged and upland moisture conditiona major degradation being hydrolysis at 7-C position and oxidation at 3-C position, respectively. Carbofuran showed less persistence in soils of higher moisture contents A significant portion, $24{\sim}39%$ of the total radioactivity, resided in soils as nonextractable residues at 60 days after treatment The nonextractable radioactivity was mainly located in soil organic matter, fulvic acid, humic acid and humin factions Gel filtration chromatography confirmed the incorporation of carbofuran and its degradation products into the organic matter.

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Cooling Time Determination of Spent Nuclear Fuel by Detection of Activity Ratio $^{l44}Ce /^{l37}Cs$ (방사능비 $^{l44}Ce /^{l37}Cs$ 검출에 의한 사용후핵연료 냉각기간 결정)

  • Lee, Young-Gil;Eom, Sung-Ho;Ro, Seung-Gy
    • Nuclear Engineering and Technology
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    • v.25 no.2
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    • pp.237-247
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    • 1993
  • Activity ratio of two radioactive primary fission products which had sufficiently different half-lives was expressed as functions of cooling time and irradiation histories in which average burnup, irradiation time, cycle interval time and the dominant fissile material of the spent fuel were included. The gamma-ray spectra of 36 samples from 6 spent PWR fuel assemblies irradiated in Kori unit-1 reactor were obtained by a spectrometric system equipped with a high purity germanium gamma-ray detector. Activity ratio $^{l44}$Ce $^{l37}$Cs, analyzed from each spectrum, was used for the calculation of cooling time. The results show that the radioactive fission products $^{l44}$Ce and $^{l37}$Cs are considered as useful monitors for cooling time determination because the estimated cooling time by detection of activity ratio $^{l44}$Ce $^{l37}$Cs agreed well with the operator declared cooling time within relative difference of $\pm$5 % despite the low counting rate of the gamma-ray of $^{l44}$Ce (about 10$^{-3}$ count per second). For the samples with several different irradiation histories, the determined cooling time by modeled irradiation history showed good agreement with that by known irradiation history within time difference of $\pm$0.5 year. From this result, it would be expected to be possible to estimate reliably the cooling time of spent nuclear fuel without the exact information about irradiation history. The feasibility study on identification of and/or sorting out spent nuclear fuel by applying the technique for cooling time determination was also performed and the result shows that the detection of activity ratio $^{l44}$Ce $^{l37}$Cs by gamma-ray spectrometry would be usefully applicable to certify spent nuclear fuel for the purpose of safeguards and management in a facility in which the samples dismantled or cut from spent fuel assemblies are treated, such as the post irradiation examination facility.mination facility.

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