• Title/Summary/Keyword: 비등수

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TGA열분석을 이용한 개질된 NR고무의 열화반응

  • An, Won-Sul;Park, Gi-Ho
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2008.11a
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    • pp.488-490
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    • 2008
  • 등온 및 비등온 TGA 열분석을 이용하여 TTSP를 이용하여 실험적으로 Shift factor(Acceleration factor) ${\alpha}_T$를 구하고 이로부터 마스터 커브 (master curve)를 도출할 수 있었고, 실험에 사용된 개질된 NR고무재료는 Arrhenius식을 잘 따르는 것이 확인되었으며, 이로부터 TTSP에 의한 촉진시험 결과의 신빙성을 확인할 수 있었다. 한편, 등온 TGA 실험으로부터 얻은 활성화에너지는 37.70 kJ/mol인 반면, 비등온 TGA로부터 Kissinger plot에 의해 얻은 활성화에너지는 166.20 kJ/mol이었는데, 이는 저온과 고온에서 서로 다른 분해기구에 의해 중량 감소가 일어나기 때문인 것으로 생각 되었다.

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Torque Curve Shapes of Simple Uniaxial Magnetic Materials (단순 일축 비등방성 자성체의 돌림힘 곡선의 개형)

  • Hur, Jeen;Shin, Sung-Chul
    • Journal of the Korean Magnetics Society
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    • v.8 no.1
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    • pp.34-41
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    • 1998
  • We have theoretically investigated torque curve shapes of simple uniaxial magnetic materials by considering conditions for round peaks to exist. These conditions are functions of an applied field, anisotropy field, ans lowest critical field $h_0$ for a domain wall to move or nucleate. The peak having a height of 2h appears when h is lower than h$_1$, the peak having a height of 1 appears when h is higher than h$_2$, ans two peaks having heights of 1 and -1 appear when h is higher than h$_3$. It was found that torque curves of simple uniaxial magnetic materials could be classified into 8 distinct types depending on the existence of hysteresis, the number of the round peaks, and the reversal mechanisms. Simple uniaxial magnetic materials also found to be classifed into the 5 groups depending on $h_0$.

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Undrained Analysis of Soft Clays Using an Anisotropic Hardening Constitutive Model: I. Constitutive Model (비등방경화 구성모델을 적용한 연약 지반의 비배수 거동 해석: I. 구성모델)

  • 오세붕
    • Journal of the Korean Geotechnical Society
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    • v.15 no.6
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    • pp.121-130
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    • 1999
  • The objective of this study is to perform finite element analyses(FEA) using the anisotropic hardening constitutive model on the basis of the total stress concept. An anisotropic hardening model was then developed to solve the problem and its mathematical formulations and experimental verifications were also described. In a companion paper, the constitutive equation will be formulated for accurate and efficient solutions of FEA, and coded into a nonlinear analysis program, and finally a field problem will be analyzed. The proposed model includes the failure criterion of a von Mises type and the anisotropic hardening rule based on the generalized isotropic hardening description, which can model the nonlinearity and the anisotropy of the stress-strain relationship. As a result this study could verty the experimental results for UU triaxial tests, CU triaxial tests for overconsolidated samples, and anisotropic loading tests with the rotation of principal stress axes for $K_0$consolidated samples.

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A Study on Caissons for Accelerating Consolidation Considering Anisotropic Permeability (비등방 투수성을 고려한 압밀촉진 케이슨 기초공법에 관한 연구)

  • 박정순;조남준
    • Journal of the Korean Geotechnical Society
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    • v.19 no.4
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    • pp.7-14
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    • 2003
  • This study has investigated the feasibility of caissons for accelerating consolidation (C.A.C.) constructed in clays with anisotropic permeability by improving the former study on C.A.C. in isotropic clays. Analytical solutions for excessive pore water pressures of two-dimensional consolidation equation and average degrees of consolidation with varying time factors have been provided by considering anisotropic permeability. With varying anisotropic permeability ratios of 5, 10, and 50, consolidation times required for reaching the average degree of consolidation of 90% for C.A.C. at the section of $\xi$=0.1 are shorter than those for conventional caissons by 8, 13, and 47 times, respectively. C.A.C. is more effective in reducing consolidation time as anisotropic permeability ratio increases. This study provides also plots for average degrees of consolidation versus the width to depth ratios of analyzed sections and permeability ratios, which will enable engineers to determine easily average consolidation settlements.

Temperature Distribution of Liquid Nitrogen Jet at Sub- and Supercritical States (아임계 및 초임계에서 액체 질소 분류의 온도 분포)

  • Lee, Hyunchang;Kim, Haisol;Cho, Seongho;Sung, Hong-Gye;Yoon, Youngbin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.1
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    • pp.1-6
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    • 2018
  • Temperatures of cryogenic nitrogen jet inside an injector and at three different downstream positions (0.9, 10.6, and 28.1d) were measured with thermocouples in sub- and supercritical states. The jet temperature decreased while cooling the supply line and injector. The jet experienced from flash boiling, boiling and then no boiling according to decreasing temperature. As an analogy to flash-boiling at the subcritical state, pseudo-flash boiling has been assumed considering the existence of pseudo-boiling at the supercritical state. By showing an area where the temperature did not increase downstream, the plausibility of pseudo-flash boiling is proposed.

Minimum Film Boiling Temperatures for Spheres in Dilute Aqueous Polymer Solutions and Implications for the Suppression of Vapor Explosions (폴리머 수용액에서 구형체의 최소막비등온도와 증기폭발 억제 효과)

  • Bang, Kwang-Hyun;Jeun, Gyoo-Dong
    • Nuclear Engineering and Technology
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    • v.27 no.4
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    • pp.544-554
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    • 1995
  • Pool boiling of dilute aqueous solutions of polyethylene oxide polymer has been experimentally investigated for the purpose of understanding the physical mechanisms of the suppression of vapor explosions in this polymer solution. Tn solid spheres of 22.2mm and 9.5mm-diameter ore heat-ed and quenched in the polymer solutions of various concentrations at 3$0^{\circ}C$. The results showed that minimum film boiling temperature($\Delta$ $T_{MFB}$) in this highly-subcooled liquid rapidly decreased from over $700^{\circ}C$ for pure water to about 15$0^{\circ}C$ as the polymer concentration was increased up to 300ppm for 22.2mm sphere, and it decreased to 35$0^{\circ}C$ for 9.5mm sphere. This large decrease of minimum film boiling temperature in this aqueous polymer solution may explain its ability to suppress spontaneous vapor explosions. Also, tests with applying a pressure wave showed that the vapor film behaved more stable against an external disturbance at higher polymer concentrations. These observations together with the experimental evidences of vapor explosion suppression in dilute polymer solutions suggest that the application of polymeric additives such as polyethylene oxide as low as 300ppm to reactor emergency coolant be considered to prevent or mitigate energetic fuel-coolant interactions during severe reactor accidents.s.

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A Study on the Analysis of Anisotropic Thin and Thick Shells (비등방성 얇은 쉘 및 두꺼운 쉘의 해석연구)

  • Park Weon-Tae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.6
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    • pp.525-530
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    • 2005
  • In this study, it is presented analysis results of bending problems in the anisotropic thick shell and the anisotropic thin shell bending problems. In the numerical analysis of various mechanical problems involving complex partial differential equations, finite element method is used. Both Kirchoffs assumptions and Mindlin assumptions are used as the basic governing equations of bending problems in the anisotropic shells. The analysis results are compared between the anisotropic thick shells and the anisotropic thin shells for the various width-thickness ratios. The numerical method of this study will be contributed not only to analysis the bending behavior of anisotropic shells but also to design the anisotropic shells.

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Superexchange Interaction and Anisotropic Superexchange (Dzyaloshinskii-Moriya) Interaction (초교환 상호작용과 비등방성 초교환(Dzyaloshinskii-Moriya) 상호작용)

  • Yang, Il-Kyu;Bang, Kil-Hyun;Kim, Bum-Hyun;Min, Byung-Il
    • Journal of the Korean Magnetics Society
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    • v.17 no.5
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    • pp.215-220
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    • 2007
  • The superexchange interaction is introduced to explain antiferromagnetic ordering in transition metal compounds such as MnO and $MnF_2$. The anisotropic superexchange (Dzyaloshinskii-Moriya: DM) interaction can be derived by incorporating the spin-orbit interaction into the superexchange interaction. The anisotropic superexchange DM can account for the weak ferromagnetism observed in transition metal compounds such as ${\alpha}-Fe_2O_3$, $MnCO_3$, $CrF_3$.

Finite Difference Stability Analysis of Anisotropic Plates with Free Edge (자유경계를 갖는 비등방성 판의 유한차분 안정성 해석)

  • Yoo, Yong Min;Lee, Sang Youl;Chang, Suk Yoon
    • Journal of Korean Society of Steel Construction
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    • v.12 no.2 s.45
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    • pp.221-230
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    • 2000
  • Checking the stability of anisotropic plates with free edges, it is impossible that buckling loads and modes are found via existing classical methods about various loads and boundary conditions. For solving this problems. finite difference method(FDM) is used to analyze the buckling behaviors for arbitrary boundary conditions. Using FDM, it is difficult to treat the fictitious points on free edges. So, this paper analyzes buckling behaviors of analytic models with one edge free and the other edges clamped and with opposite two edges free and other two edges clamped. The various buckling loads and mode characteristics through numerical results are given for buckling behaviors of anisotropic plates on free edges.

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Buckling Analysis of Simple Supported Plate Stiffened with Laminated Composite Panel (복합적층 패널로 보강된 단순지지 판의 좌굴해석)

  • Park, Dae Yong;Chang, Suk Yoon
    • Journal of Korean Society of Steel Construction
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    • v.16 no.5 s.72
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    • pp.621-628
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    • 2004
  • This paper introduces a new theory, that in a stiffened plate, a steel stiffener could be substituted a composite material in order to prevent from buckling. Changing a steel stiffener into a composite material would not only preclude welding, but could also prevent damage to the material due to fatigue and corrosion.A composite material is assumed to adhere to a steel plate, and is never separated from the plate until the steel plate reaches buckling.Such plate has variable shapes, with different lengths and widths, and also shows an anisotropic material property. LUSAS, a commercial finite element analysis package, was used in the buckling analysis.This paper investigated buckling behavior in anisotropic composite plates with variable parameters.