• Korean Journal of Soil Science and Fertilizer
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• v.14 no.3
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• pp.157-162
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• 1981

The studies we re carried out to examine the effect of soil improvement agents, such as lime, wollastonite and phosphate, in reducing the damage caused by hydrogen fluoride gas to the vegetative growth of rice. The yield loss, damage rate of the plant leaves, the fluoride of the plants were measured. The results obtained are summarized as follows : 1. The best results were obtained a treatment of lime and wollastonite. 2. The rice yield was not significantly increased by the soil improvement agents. 3. The fluoride content of the plants was positively correlated with yield loss and damage rate during vegetative growth.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1997.04a
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• pp.73-74
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• 1997

• Journal of the Korean Society of Urban Environment
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• v.18 no.4
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• pp.495-502
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• 2018

In this study, the AERMOD air diffusing model was used to estimate the range of influence of Hazardous chemicals (hydrogen fluoride) in case of small accidents in Jeju area. The impact scope were in the order of Seogwipo Fire Station, Dongbu Fire Station, Jeju Fire Station, and Seobu Fire Station. Seasonal orders were summer, spring, autumn and winter. The correlation between the meteorological factors shows a strong positive correlation with the wind speed of 0.998 and has a negative correlation with the temperature of -0.463. Through the linear regression analysis, we could estimate the equation of Impact scope = 13.922WS (Wind Speed) - 5.195 and the reliability ($R^2$) was as high as 0.995.

• Journal of the Korean Institute of Gas
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• v.22 no.4
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• pp.32-38
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• 2018

The purpose of this study is to assess quantitatively the amount of leaks and the extent of dispersion in case of a leak at a hydrogen fluoride tank container unloading station, and to suggest a safety improvement plan to prevent recurrence of similar accidents. In 2012, Company H leaks 8 tonnes of tank containers with a maximum storage capacity of 18 Ton, causing it to become a social issue. As a result of calculation using Gaussian plume model, the concentration was estimated to be more than 20ppm from the leak point to 1,321 m radius. The leakage of hydrogen fluoride from the company R in 2014 was estimated to be 11.02 kg, of which 2.9 kg was treated by the scrubber. As a result of calculation using Gaussian plum model, the damage range with a concentration of 20ppm or more from the leak source was estimated to be 69 m in radius. As a result of comparing the above two accidents, it was found that the leakage amount was about 987 times different and the damaged site was more than 19 times different. Therefore, it was concluded that it was necessary to control the wearing of the protective equipment, the enclosure of the unloading site, the installation of the scrubber, and the emergency training to avoid the accidental leakage of a hydrogen fluoride from the unloading site.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1998.11a
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• pp.92-92
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• 1998

반도체 기술의 경이적인 발전에 힘입이 최근 휴대용 이동통신기기, 노트북 컴퓨터 등 무선전자제품의 폭발적인 수요와 함께 이들의 소형화, 경량화가 요구되어 전원인 2차전지의 경량화, 고용량화, 장수명화의 필요성이 절실해졌다. Ni-MH 전지는 Ni-Cd전지에 비해 에너지밀도가 1.5~2배에 이르고 충방전 cycle이 길며 오염물질이 없어 환경 친화적이라는 장점이 었다. Ni-MH 전지의 성능은 음극재료인 수소저장합금에 의해 좌우되므로 수소저장능력이 크고 내식 성이 우수한 합금개발이 중요하다. $CaNi_5$는 수소저장능력이 크고 매장량이 많아 값이 싸다는 장점이 있지만 KOH 용액에서 내구성이 떨어진다는 단점이 있어 주로 Heat Pump 재료에만 사용이 제한되어왔다. 본 실험에서는 결정 구조의 nanocrystalline 및 amorphous화함으로써 해리압의 변화, 방전용량의 변화 등 새로운 전극 특성을 나타낸다고 보고되고 있는 MG (Mechanical Grinding)방법을 통해 CaNis 합금의 전극특성의 변화를 살펴보았고, 아울러 고상-기상반응에서 표면에 형성된 산화피막을 제거하여 안정한 불화물을 표면에 형성시킴으로써 불순물 가스에 대한 내구성을 높이고 활성화특성을 향상 시킨다고 보고되고있는 불화처리 방법을 이용하여 불화처리 시간을 달리하면서 용액 속에서의 pH의 변화, ICP분석, 전극의 성능 및 표면 특성변화를 충방전 test, SEM 등을 통해 고찰하였다.

• Bulletin of Korea Environmental Preservation Association
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• v.7 no.8
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• pp.26-30
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• 1985

• Bulletin of Korea Environmental Preservation Association
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• v.7 no.9
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• pp.36-40
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• 1985

• Applied Chemistry for Engineering
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• v.7 no.5
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• pp.925-937
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• 1996

Three types of mordenites treated by steaming($SM_{6.5}$), HF solution for $SM_{6.5}(FM_a)$ and HF solutlon+steaming for $SM_{6.5}(FM_b)$ were prepared and used as cracking catalysts of vacuum gas oil. These samples were analysed by XRF and XPS for average and surface Si/Al atomic ratio, XRD for unit cell constants, nitrogen adsorption/desorption for porosity, pyridine-IR for acidic properties. In comparison with three type samples, $SM_{6.5}$ had a lot of acid amount and showed micropore volume mostly(>85% to total volume). Dealuminated $FM_a$, compared with $SM_{6.5}$, was decreased a little in acid amount and improved for porosity. Also, $FM_b$ was decreased further in acid amount and developed in mesopore dramatically. The catalytic activity and the yield of gasoline, kerosine+diesel and branched aromatic over the modified mordenites which have developed mesopore were improved. This is due to limited access of diffusion of large molecules within pore of the modified mordenites.

• The Safety technology
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• no.198
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• pp.26-28
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• 2014

2년 전인 지난 2012년 9월 27일 경북 구미4공단에 소재한 휴브글로벌에서 불화수소가 누출되는 사고가 발생했다. 이 사고로 근로자 5명이 사망하고 23명이 부상을 당했다. 사고 후 불화수소가 공기를 통해 대량 퍼지면서 인근 지역도 막대한 피해를 입었다. 사고는 안전관리측면에서 많은 허점을 드러냈다. 사업장은 물론 관할 소방서, 구미시 모두에서 화학사고에 대한 대응 매뉴얼과 협조체계가 제대로 구축되지 않아 피해의 확산을 막지 못했다. 너무나 허술한 화학사고 대응체계의 현실에 구미시민은 물론 전 국민이 분노했다. 이에 정부는 화학물질관리 및 사고대응 시스템 전면에 대한 대대적인 개선에 돌입했다. 그리고 그 결과물이 지난해 12월 초 모습을 드러냈다. 관계부처, 지자체, 소방당국, 안전보건공단까지 한데 모여 효과적인 화학사고 예방과 대응을 전담하는 화학재난 합동방재센터가 전국에서 처음으로 구미에 문을 연 것이다. 그로부터 반년이 흐른 지금 구미에는 어떤 변화가 생겼을까. 달라진 화학재난 안전관리체계를 확인해보고자 구미119화학구조센터를 찾아가봤다.

• Journal of Environmental Health Sciences
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• v.38 no.5
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• pp.448-449
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• 2012