• Title/Summary/Keyword: 분해 법칙

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In Newton's proof of the inverse square law, geometric limit analysis and Educational discussion (Newton의 역제곱 법칙 증명에서 기하학적 극한 분석 및 교육적 시사점)

  • Kang, Jeong Gi
    • Journal of the Korean School Mathematics Society
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    • v.24 no.2
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    • pp.173-190
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    • 2021
  • This study analyzed the proof of the inverse square law, which is said to be the core of Newton's , in relation to the geometric limit. Newton, conscious of the debate over infinitely small, solved the dynamics problem with the traditional Euclid geometry. Newton reduced mechanics to a problem of geometry by expressing force, time, and the degree of inertia orbital deviation as a geometric line segment. Newton was able to take Euclid's geometry to a new level encompassing dynamics, especially by introducing geometric limits such as parabolic approximation, polygon approximation, and the limit of the ratio of the line segments. Based on this analysis, we proposed to use Newton's geometric limit as a tool to show the usefulness of mathematics, and to use it as a means to break the conventional notion that the area of the curve can only be obtained using the definite integral. In addition, to help the desirable use of geometric limits in school mathematics, we suggested the following efforts are required. It is necessary to emphasize the expansion of equivalence in the micro-world, use some questions that lead to use as heuristics, and help to recognize that the approach of ratio is useful for grasping the equivalence of line segments in the micro-world.

Kinetics of Base Hydrolysis of Some Chromen-2-one Indicator Dyes in Different Solvents at Different Temperatures (여러 온도 및 용매 하에서 수행된 chromen-2-one 지시약 염료들의 염기성 가수분해 반응에 대한 속도론적 연구)

  • Abu-Gharib, Ezz A.;EL-Khatib, Rafat M.;Nassr, Lobna A.E.;Abu-Dief, Ahmed M.
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.346-353
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    • 2011
  • Base hydrolysis of 7-hydroxy-2H-chromen-2-one (HC) and 7-hydroxy-2H-chromen-2-one-4-acetic acid (HCA) in aqueous-methanol and aqueous-acetone mixtures were studied kinetically at temperature range from 283 to 313 K. The activation parameters of the reactions were evaluated and discussed. Moreover, the change in the activation energy barrier of the investigated compounds from water to water-methanol and water-acetone mixtures was estimated from the kinetic data. It is observed that the change in activation barriers is more or less the same for the hydrolysis of HC and HCA. Base hydrolysis of HC and HCA follows a rate law with $k_{obs}=k_2[OH^-]$. The decrease in the rate constants of HC and HCA as the proportion of methanol or acetone increases is due to the destabilization of $OH^-$ ion. The high negative values of entropy of activation support the proposal mechanism, i.e. the investigated reaction takes place via the formation of an intermediate complex. Moreover, these values refer to the rigidity and stability of the intermediate complex. Thus, the ring opening of the intermediate complex would be the rate controlling step.

On the Distensibility of the External Carotid Artery of the Rabbit (가토(家兎) 외경동맥(外經動脈)의 신장도(伸張度)에 대(對)하여)

  • Lee, Dong-Il;Choo, Young-Eun
    • The Korean Journal of Physiology
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    • v.7 no.2
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    • pp.49-58
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    • 1973
  • The distensibility of the major arteries has been investigated extensively, but the value expressed as Young Modulus varies widely by the different schools of the investigators, the major reason undoubtedly being the difficulties encountered in the measurement. In the present study, an attempt was made to elucidate the distensibility of the external carotid artery of the rabbit, which was placed in saline immediately after removing from the apparently healthy, normal rabbit without anesthesia. The circular section strip and longitudinal section strip were made from the whole artery, and Young Modulus of the whole artery, circular section and longitudinal section strips was calculated from the length-tension curve of each sample. Also, the similar samples of the artery seperately obtained were placed in ATP solution in the concentration of 0.15 mM and 0.30 mM, and Young Modulus was similary calculated. Experiments were performed at 15,45 and 75 min after the artery was removed from the rabbit, and the results thus obtained are summarized as follows. 1) Young Modulus of the whole external carotid artery of the rabbit in saline was $4.74{\times}10^7dyne/cm^2$ at 15 min, but lower values were obtained at 45 and 75 min, Young Modulus being $4.62{\times}10^7dyne/cm^2\;and\;4.13{\times}10^7dyne/cm^2$, respectively. When the arterial samples were placed in ATP solutions, Young Modulus did not change much throughout the experiment, and lower Young Moduli were obtained in 0.30 mM ATP solution than in 0. 15 mM ATP solution. 2) Young Modulus Of the Circular Section Strip in Saline was $4.11{\times}10^7dyne/Cm^2,\;3.75{\times}10^7dyne/cm^2\;and\;3.90{\times}10^7dyne/cm^2,$ respectively, at 15, 45 and 75 min, the value at 15 min being the highest. However, when the strip was placed in ATP solutions, no appreciable change was observed throughout the experiment, and Young Moduli were lower in 0.30 mM ATP solution than in 0.15 mM ATP solution. 3) Young Modulus of the longitudinal section strip in saline was $2.12{\times}10^7dyne/cm^2,\;2.48{\times}10^7dyne/cm^2\;and\;2.46{\times}10^7dyne/cm^2$, respectively, at 15, 45 and 75 min, Young Modulus being slightly elevated in the latter part of the experiment. A similar tendency was observed when the strip was placed in ATP solutions.

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New Method of Volume Measurement for Reference Weights of a Pressure Balance Using a Gas Pycnometer (기체용적계를 이용한 분동식 압력계용 기준분동의 새로운 부피측정 방법)

  • Lee, Yong Jae;Lee, Woo Gab;Mohammed, Mohammed Abdurahman;Park, Yon-Kyu;Oh, Chae Yoon
    • Journal of the Korean Vacuum Society
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    • v.22 no.5
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    • pp.231-237
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    • 2013
  • New method of volume measurement for reference weights of a pressure balance using a gas pycnometer is proposed. The result of volume measurement of proposed method shows the uncertainties of approximately 0.2% at the level of confidence of 95% for reference weights in the ranges of 1 kg, 2 kg, and 5 kg. This measuring system consists of a sample chamber, an expansion chamber, a precision pressure gage, a precison thermometer, a vacuum pump, and helium as a medium gas. The measurement principle of this proposed method is based on Boyle's law. This method will contribute a reliability of the volume measurements of reference weights for a pressure balance to the national measurement standard.

Region Segmentation from MR Brain Image Using an Ant Colony Optimization Algorithm (개미 군집 최적화 알고리즘을 이용한 뇌 자기공명 영상의 영역분할)

  • Lee, Myung-Eun;Kim, Soo-Hyung;Lim, Jun-Sik
    • The KIPS Transactions:PartB
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    • v.16B no.3
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    • pp.195-202
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    • 2009
  • In this paper, we propose the regions segmentation method of the white matter and the gray matter for brain MR image by using the ant colony optimization algorithm. Ant Colony Optimization (ACO) is a new meta heuristics algorithm to solve hard combinatorial optimization problem. This algorithm finds the expected pixel for image as the real ant finds the food from nest to food source. Then ants deposit pheromone on the pixels, and the pheromone will affect the motion of next ants. At each iteration step, ants will change their positions in the image according to the transition rule. Finally, we can obtain the segmentation results through analyzing the pheromone distribution in the image. We compared the proposed method with other threshold methods, viz. the Otsu' method, the genetic algorithm, the fuzzy method, and the original ant colony optimization algorithm. From comparison results, the proposed method is more exact than other threshold methods for the segmentation of specific region structures in MR brain image.

A Comparative Study on the Methods Estimating Wave Directional Spectrum (파향스펙트럼 추정법의 비교 연구)

  • 오병철;심재설
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.2 no.3
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    • pp.119-127
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    • 1990
  • Wave directional spectrum estimation methods for irregular waves were considered in this study. Until now, the Longuet-Higgins Method (LHM) initiated by Longuet-Higgins et al. (1963) has been widely used, but resolutions of the estimation were found to be low. Kobune's Maximum Entropy Method (MEM) for the estimation of wave directional spectrum, bas-ed on the entropy Principle showed higher resolutions comparing with the LHM . If the wave directional spectrum is of Delta functions, the MEM is exact in its estimation. It was also found that for a unimodal spectrum, if the Mitsuyasu's spreading coefficient is above 5, the estimation resolutions were high. In bimodal spectrum, as the angle difference between the two peaks increased, the resolution improved. The energy seems to transfer to the smoother peak in the smoothing of peak's peakedness. LHM has a tendency to estimate bimodal spectrum as a unimodal spectrum ; thus, except for its computational speed, the resolution of LHM falls far below that of MEM.

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Spectrophotometric Investigation of Oxidation of Cefpodoxime Proxetil by Permanganate in Alkaline Medium: A Kinetic Study (알칼리성 용매에서 과망간에 의한 세프포독심 프록세틸의 산화의 분광광도법적 조사: 속도론적 연구)

  • Khan, Aftab Aslam Parwaz;Mohd, Ayaz;Bano, Shaista;Siddiqi, K. S.
    • Journal of the Korean Chemical Society
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    • v.53 no.6
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    • pp.709-716
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    • 2009
  • A Kinetics pathway of oxidation of Cefpodoxime Proxetil by permanganate in alkaline medium at a constant ionic strength has been studied spectrophotometrically. The reaction showed first order kinetics in permanganate ion concentration and an order less than unity in cefpodoxime acid and alkali concentrations. Increasing ionic strength of the medium increase the rate. The oxidation reaction proceeds via an alkali-permanganate species which forms a complex with cefpodoxime acid. The latter decomposes slowly, followed by a fast reaction between a free radical of cefpodoxime acid and another molecule of permanganate to give the products. Investigations of the reaction at different temperatures allowed the determination of activation parameters with respect to the slow step of proposed mechanism and fallows first order kinetics. The proposed mechanism and the derived rate laws are consistent with the observed kinetics.

비정질 산화물 반도체 IGZO 박막의 특성 연구

  • Jang, Yajuin;Kim, Hong-Bae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.287-287
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    • 2012
  • 최근 투명 산화물 반도체(TOS: Transparent Oxide Semiconductor)중에 비정질 산화물 반도체(amorphous oxide semiconductor)를 이용한 트랜지스터 연구가 활발히 진행되고 있다. 비정질 산화물 반도체는 박막 트렌지스터 소자의 Active Layer으로 사용할 수 있다. 본 연구는 RF magnetron sputtering법으로 유리기판 위에 IGZO박막을 증착하였다. 박막 증착 조건은 초기 압력 $3.0{\times}10^{-6}$ Torr, 증착 압력 20 mTorr, 반응가스 Ar 50 sccm, RF power 30w, 증착 온도는 실온으로 고정하였으며, 공정변수로 증착 시간을 변화시키며 IGZO박막을 증착하였다. IGZO 타겟은 $In_2O_3$, $Ga_2O_3$, ZnO 분말을 각각 1:1:1 mol% 조성비로 혼합하여 소결한 타겟을 사용하였다. XRD 분석결과에 따라서 Bragg's 법칙을 만족하는 피크가 나타나지 않는 비정질 구조임을 확인할 수 있었다. 가시광 영역에서(450~700 nm) 모든 박막은 90% 이상 투과도를 나타내었다. 증착시간이 증가할수록 밴드갭이 감소하는 것을 확인하였다. 증착시간이 5분인 경우 캐리어 농도는 $2.2{\times}10^{19}$ $cm^{-3}$, 이동도는 7.5 $cm^2/V-s$, 비저항은 $3.8{\times}10^{-2}{\Omega}$-cm의 반도체 특성을 나타냈고, 박막 트렌지스터 소자의 Active Layer으로 사용할 수 있다.

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Measurement of Flash Point for Binary Mixtures of Toluene, Methylcyclohexane, n-heptane and Ethylbenzene at 101.3 kPa (Toluene, Methylcyclohexane, n-heptane 그리고 Ethylbenzene 이성분 혼합계에 대한 101.3 kPa에서의 인화점 측정)

  • Hwang, In Chan;In, Se Jin
    • Fire Science and Engineering
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    • v.31 no.3
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    • pp.19-24
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    • 2017
  • Flammable substances are used in laboratories and industrial process. The flash point (FP) is one of the most important physical properties used to determine the potential for characterizing the fire and explosion hazard of liquids. The FP data at 101.3 kPa were measured for the binary systems {toluene+ethylbenzene}, {methlycyclohenxane+ethylbenzene} and {n-heptane+ ethylbenzene}. The experiments were performed according to the standard test method (ASTM D 3278) using a SETA closed cup flash point tester. The measured FPs were compared with the values predicted using the following activity coefficient models: Wilson, Non-Random Two Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC). The average absolute deviation between the predicted and measured lower FP was less than 1.74 K.

A Proposal to Growth Model of $\textrm{NH}_3$/$\textrm{O}_2$ Oxidation with species of $\textrm{O}_2$ and $\textrm{H}_2\textrm{O}$ ($\textrm{O}_2$$\textrm{H}_2\textrm{O}$를 산화제로 하는 $\textrm{NH}_3$/$\textrm{O}_2$산화의 성장모델 제안)

  • Kim, Yeong-Jo
    • Korean Journal of Materials Research
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    • v.9 no.9
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    • pp.932-936
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    • 1999
  • 4NH(sub)3+$3O_2$$\longrightarrow$$2N_2$+$6H_2$O 의 화학반응식을 가지며$ O_2$$H_2$O를 산화제로 하는 $NH_3$/$O_2$산화의 성장모델을 세웠으며, 그 결과 Fick의 제 1 법칙을 기초로 하는 건식 및 습식 산화메카니즘으로 이해되는 Deal-Grove의 산화막 성장모델과 유사한 결과가 도출되었다. 이 성장모델에 의하면 산화제$ O_2$$H_2$O가 상호보완적으로 산화에 영향을 미치므로 산화온도 뿐 아니라 $NH_3$/O$_2$의 유량비도 산화율을 결정한다. rapid thermal processing(RTP)에 의한 산화막 성장실험으로 본 연구에서 제안하는 성장모델을 확인하였으며, NH$_3$분자의 분해에 의해 발생하는 N 원자의 산화막 내부확산을 secondary ion mass spectroscopy(SIMS)로 확인하였으며, Auger electron spectroscopy (AES) 측정결과 N 원자의 존재는 무시할만한 수준이었다.

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