• Korean Chemical Engineering Research
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• v.43 no.1
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• pp.47-52
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• 2005

The wide use of metal dusts have been found in industrial field and many dust explosion accidents occur by fire spread of dust layer. In this study, we developed a new experimental device to examine fire and explosion characteristics of the dust layer. Aspects of the burning zone over metals(Mg, Zr, Ta, Ti, etc) and PMMA(Polymethyl methacrylate) dust layers have been investigated experimentally to clarify behaviors (Spread rate and quenching distance) and effects of $N_2$ surrounding gas on the fire spread over metal dust layers. From the experimental result, it was found that the spread rate of metal dusts is larger than PMMA, the dependability of spread rate over the thickness of dust layer is small, and the minimum oxygen concentration of spread flame over Mg dust layer is 3.6-3.7 vol%. Since high correlation between the spread rate and the reciprocal of quenching distance was seen, relative risk prediction in those inflammable parameters can be predicted.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.425-429
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• 2011

The development of metal plasma generated by high laser irradiance and its effect on the surrounding air using shadowgraph images after laser pulse termination are studied; hence the formation of laser supported detonation and combustion processes has been investigated. The core of the paper is in detecting chemical reaction using X-Ray Diffraction (XRD) between ablated aluminum plasma and oxygen from air by inducing high power laser pulse (>1000 mJ/pulse) and conduct a quantitative comparison of chemically reactive laser initiated waves with the classical detonation of exploding aluminum (dust) cloud in air. This study may suggest a new approach of initiating detonation from metal sample in its bulk form without the need of mixing nano-particles with oxygen for initiation.

• Tunnel and Underground Space
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• v.25 no.1
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• pp.46-55
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• 2015

A water tube with detonating cord was devised to control the blast dust. Water diffusion experiments with different detonating cord positions were conducted during the series of experiments to optimize the design parameters of the tube. Images from high speed camera were analyzed to evaluate the results. AUTODYN program was adopted to simulate the diffusion process of water and compared with the images. Diffusion of water shows cross flow in case of external charge while the internal case shows radial flow. A bubble ring was formed during the numerical analysis of internal charge case as occurred in underwater blast. An additional bubble ring was formed by the reflection pressure from the ground. And the Weber number was determined as sufficient for spray atomization performance of the water tube.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2013.04a
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• pp.116-116
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• 2013

마그네슘은 스마트폰, 전자기기 케이스, 내화벽돌과 아크용접봉 제조시의 첨가물 등으로 사용되고 있는데, 최근에는 재활용을 위한 마그네슘 용해로를 취급하거나 가공하는 사업장이 증가하고 있어 사고위험성이 높아지고 있다. 금속분을 취급하는 사업장에서의 금속분진은 저장이나 축적 등과 같이 주로 퇴적물로서 존재한다. 퇴적분진의 발화온도는 퇴적물 형상과 두께, 입경, 분위기 가스의 유속, 산소농도, 부유분진의 농도, 퇴적밀도, 수분 등의 많은 영향인자가 관여하기 때문에 이론적 예측이 힘들고 실험적인 측정에 의존할 수 밖에 없는 것이 현실이다. 본 연구에서는 연소성이 높고 화재폭발사고사례가 많은 마그네슘(Mg) 분진을 사용하여 승온속도 변화에 따른 열분해특성을 조사하였다. 퇴적분진의 열적특성을 조사하기 위하여 METTLER TOLEDO의 TGA/DSC1를 사용하였으며, Mg 시료의 평균입경은 38, $142{\mu}m$이다. 입경 $38{\mu}m$의 Mg 시료의 열중량분석 결과, 중량증가는 $400{\sim}500^{\circ}C$의 범위에서 시작되며 $550^{\circ}C$에서 급격하게 중량이 증가하고 있으며, 증량증가개시온도(Temperature of weight gain)는 $460^{\circ}C$에서 시작하여 $900{\sim}950^{\circ}C$ 범위에서 중량 증가 포화값에 도달하였다. 입경 $142{\mu}m$의 Mg에 대하여 공기중 승온속도를 5, 10, $20^{\circ}C/min$으로 변화시키면서 실온에서 $900^{\circ}C$까지 가열 시키는 경우의 시료의 중량 변화에 따른 열분해 특성은 승온속도가 증가할수록 2단계의 S자 곡선은 완만하게 상승을 나타내며 중량증가개시온도가 높아지는 경향을 보이고 있다. 중량증가개시온도가 승온속도에 따라 변화하는 결과를 나타내고는 있지만, 시료량의 증가에 따른 영향을 열중량분석 실험방법의 제약으로 인하여 확인할 수 가 없었다. 그러나 만일 시료량이 크게 증가하는 경우에는 동일한 승온조건에서 중량증가 개시온도는 낮아질 가능성이 있다. 중량증가는 시료의 산화반응에 의한 것이므로 시료량의 증가는 시료 내부에의 열의 축적을 용이하게 하여 보다 낮은 온도에서도 산화반응이 충분히 일어나는 조건이 형성되기 때문이다. 승온속도가 증가할수록 산화 반응한 괴상형태의 연소입자가 크게 증가하고 있는 것을 알 수 있다. 승온속도에 따른 중량개시온도 곡선을 보면 [그림 24]와 같으며 승온속도 5, 10, $20^{\circ}C/min$의 증가에 따라 중량개시온도는 각각 490, 510, $530^{\circ}C$가 얻어졌으며 승온속도의 증가에 따라 중량개시온도가 증가하는 경향을 보이고 있다.

• Korean Chemical Engineering Research
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• v.49 no.1
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• pp.41-46
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• 2011

We investigated experimentally the properties of dust explosion through lycopodium particle clouds in a duct to provide the fundamental knowledge. Propagating dust flames in the vertical duct of 120 cm height and 12 cm square cross-section were observed by digital video camera and flame front is visualized using by PIV(Particle Image Velocimetry) system. As the result, when the same average dust concentration existed in the vertical duct, downward flame propagation was faster than the upward flame propagation, its rate increased with dust concentration in 300g/$m^3$. Post flames were caused by the ignition of unburned particles which flowed into the rear region of flame from passage between flame and duct wall, and they generated regardless of duct condition. Also, it was found that appearance frequency of post flames during dust flame propagations increased with the increase of dust concentration.

• Journal of the Korean Society of Safety
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• v.31 no.4
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• pp.55-63
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• 2016

A dust explosion is a phenomenon of strong blast wave propagation involving destruction which results from dust pyrolysis and rapid oxidation in a confined space. There has been some research done to find individual explosion characteristics and common physical laws for various dust types. However, there has been insufficient number of studies related to the heat of combustion of materials and the oxygen consumption energy about materials in respect of dust explosion characteristics. The present study focuses on the relationship between dust explosion characteristics of wood dust samples and oxygen consumption energy. Since it is difficult to estimate the weight of suspended dust participating in explosions in dust explosion and mixtures are in fuel-rich conditions concentrations with equivalent ratios exceeding 1, methods for estimating explosion overpressure by applying oxygen consumption energy based on unit volume air at standard atmospheric pressure and temperature are proposed. In this study an oxygen consumption energy model for dust explosion is developed, and by applying this model to TNT equivalent model, initial explosion efficiency was calculated by comparing the results of standardized dust explosion experiments.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.67 no.3
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• pp.474-478
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• 2018

The use of metals such as aluminum and titanium and the related industrial facilities have been continuously increasing to meet the requirements of the improvement of high-tech products due to the development of industry, and explosion of metal dust. Semiconductor process Metal dust is essential, but research is insufficient. The purpose of this study is to identify risk by analyzing the quantitative risk such as maximum explosion pressure and minimum explosion concentration applied international test standard in order to select the semiconductor process facilities handling dust and to predict possible risk of accidents.

• Journal of the Korean Society of Safety
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• v.33 no.2
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• pp.39-44
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• 2018

Dust explosions are occurring in a variety of industries. A dust explosion caused by a specific energy generates huge amount of energy in the ignition and releases decomposition gas. Damages can be increased since this released decomposition gas can cause second and subsequent explosions. In this study, the goal was to obtain practical information on what could affect the explosion by comparing the characteristics of two kinds of dusts with completely different chemical properties. Three kinds of dusts were measured and evaluated for explosion pressure, dust explosion index, explosion limit and minimum ignition energy. It is possible to grasp the characteristics of each dust and use it as useful accident prevention data in the production of raw material powder.

• Journal of environmental and Sanitary engineering
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• v.14 no.4
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• pp.93-98
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• 1999

We had investigated combustion properties of rice bran dusts. Decomposition of rice bran dusts with temperature were investigated using DSC and the weight loss according to temperature using TGA in order to find the thermal hazard of rice bran dusts, and the properties of dust explosion in variation of their dust with the same particle size. Using Hartman's dust explosion apparatus which estimate dust explosion by electric ignition after making dust disperse by compressed air, dust explosion experiments have been conducted by varying concentration and size of rice bran dust.According to the results for thermodynamic stability of rice bran dust, there are little change of initiation temperature of heat generation and heating value for used particle size. But initiation temperature of heat generation decreased with high heating rate whereas decomposition heat increased with particle size. Average maximum explosion pressure was $10kgf/cm^2$ for 60/70 mesh and $1.5mg/cm^2$ dust concentration.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1993.04a
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• pp.153-173
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• 1993

폭약은 탄광에서 석탄이나 각종 광물을 캐거나, 건설토목현장에서 암반 제거를 위해서 주로 사용되었다. 전쟁에서 군사용으로 파괴를 위한 목적으로 사용되기도 하였으나, 최근의 동서화해 분위기와 남북통일이 무르익는 시대적 조류로 볼때 더이상 파괴용으로의 사용은 제어될 것이고 이제는 평화를 위하여, 건설을 위하여, 산업발전을 위하여 더 많이 사용되어지고 응용되어질 것이다. 작금의 첨단산업의 발달과 산업의 고도화로 우리 화약 업계에도 첨단발파기술의 개발에 많은 관심과 연구.개발을 진행중이다. 첨단발파기술의 응용사례를 소개하면, 건축토목 분야에서 노후 고층빌딩 및 굴뚝의 철거, 노후 교량 및 공장시설의 철거등에 활용되고 있으며, 위락서비스 분야에서 응용으로는 불꽃놀이를 들 수 있다. 최근에는 첨단 과학 장비를 이용하여 각종 꽃불의 모양이 음악과 미술등 예술적인 기능을 기억시킨 컴퓨터를 활용하여 보다 고차원의 공예술품(공학-예술)을 만들어낸다. 아울러 각종 기공식 발파시에도 예술적 기능과 웅장함을 가미하여 그 화려함을 극치에 다다르게 한다. 그외에도 로켓트 발사추진제등의 우주 개발에의 응용, 석유시추등 해양개발에의 응용, 각종 공학 실험연구에의 응용, 폭발 가공에의 응용, 의학에의 응용, 철강산업에의 응용 등으로 그 숫자를 이제는 일일이 나열하기 힘들 정도로 광범위해졌다.