• Title/Summary/Keyword: 분자 운동

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An Analysis of Inelastic Neutron Scattering by Liquid Methane

  • Chung, Chang-Hyun;Shin, Won-Kee;Kim, Jin-Soo
    • Nuclear Engineering and Technology
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    • v.5 no.4
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    • pp.265-278
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    • 1973
  • The incoherent neutron scattering cross section of molecular liquids is analyzed using a damping function model for correlation functions of molecular translations and rotations. The present approach is different from recent works in that the scattering function is evaluated directly, not through the intermediate scattering function. The damping fuction is determined from a simple relation between its long-wavelength limit and the generalized frequency distribution function, and translation-rotation couplings are assumed to be neglected. A physical model is used for the translational motions of center-of-mass of a molecule, including properly its short-time and long-time behaviors. A simple model for the rotational motions is suggested which relates the damping function to the Fourier transform of the dipole correlation function, or equivalently, the infrared vibrational absorption spectrum. Theoretical absolute scattering intensities are computed for liquid methane and shown to be in satisfactory agreement with both thermal and cold neutron measurements.

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The Study of Students' Misconception about the Properties of Gas in Secondary School (기체의 성질에 대한 중·고등 학생들의 오개념에 관한 연구)

  • Yoo, Seung A;Koo, In Sun;Kim, Bong Gon;Kang, Dae Ho
    • Journal of the Korean Chemical Society
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    • v.43 no.5
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    • pp.564-577
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    • 1999
  • The purpose of this study is to help an improvement of conceptional learning about the properties of gas based on molecular kinetics for secondary school students and to help an improvement of teaching method for reducing misconceptions regarding the molecular kinetics in gas phase for teachers. The subjects of this study were l00 students of 9th grade and 150 students of 11th grade students. The results showed that students had various misconceptions about the properties of gas. The major misconceptions are as follows. First, the energy is released due to the collision of the molecules, and also the direction of action of pressure is related to the direction of gravity. Second, as molecule is heated, the size of molecule is increased, and the molecule is more active because the number of moIecules is increased. Third, the pressure is reduced because of decreasing the temperature at the higher altitude and the pressure of gas molecuIes is inversely proportional to the collision number of gas molecules. Forth, the numbers of molecules of two different molecules in two same containers differ because the size of molecules differ each other. The results suggest that these problems ought to be addressed in chemistry textbooks and in the classroom teaching of chemistry. If teachers are more aware of students' misconceptions they wilI be better able to remove them.

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The Expression changes of AMPK, ERK-1/2, and p38 protein associated with Exercise in the Mouse hippocampus exposed to Radiofrequency Radiation (전자파(電磁波)에 노출된 생쥐의 해마에서 운동이 AMPK, ERK-1/2, p38 단백 발현 변화에 미치는 생체 영향)

  • Lee, Min-Sun;Park, Oak Jin;Kim, Hyun Taeg;Kim, Myeung Ju
    • Journal of Digital Convergence
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    • v.18 no.3
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    • pp.267-273
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    • 2020
  • To determine the biological effects of exercise on hippocampus in mice brain exposed to radiofrequency radiaton (RF), the expression of AMPKα, p-AMPKα, ERK1/2, p-ERK1/2, p38, and p-p38 protein in the mouse exposed to RF were investigated in the hippocampal tissues, Western blot method was used to compare the protein expression levels for each molecule. Significant increases in protein expression of individual and phosphorylated molecules were observed in the spontaneous exercise group, and the expression of these molecules was notably decreased in the RF exposure and spontaneous exercise group. This study shows that neuroplasticity can be increased by exercise in hippocampus that is responsible for memory, but memory and cognitive function may be affected by exposure to RF. We may expect clinically interesting results on dementia or Alzheimer disease if we proceed further investigation on the effect of RF.

자유분자 Monte Carlo 유동해석에 의한 터보분자펌프 성능 평가

  • Kim, In-Chan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.105.2-105.2
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    • 2013
  • 배기속도 2500 L/s, 최고진공도 10-10 mbar의 구현을 목표로 하는 대용량 복합 분자펌프 설계를 위한 3차원 유동해석을 실시하였다. 진공도가 10-5 mbar 이상이 되는 고진공도에서는 Knudsen 수가 102 이상이 되어러 분자간 충돌을 거의 무시할 수 있게 되며, 이때의 유체해석 방법으로서는 통상 희박기체 해석법으로 많이 쓰이는 Direct simulation Monte Carlo 방법보다, 충돌이 없는 분자의 자유운동을 모사하는 Monte Carlo 방법이 더 적합할 수 있다. 본 연구에서는 다단계 rotor와 stator로 구성되는 복합분자 내 유동장에 Monte Carlo 해석법을 적용하여 유동해석을 실시하였다. 다양한 변수의 조합에 대한 수치적 해석에서, 복합분자펌프의 성능에 영향을 미치는 중요한 설계변수는 rotor-stator의 날개각, 유동방향 회전축의 두께 변화 등, 진행방향 분자의 모멘텀에 직접적인 영향을 미치는 변수들임이 확인되었다.

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Analysis of the Level of Cognitive Demands about Concepts of the Changes of State and Kinetic Theory on 'Science 1' Textbooks in Junior High School (III) ('과학1' 중학교 교과서의 물질의 상태 변화와 분자 운동 내용이 요구하는 인지 수준 분석(제III보))

  • Park, Jieun;Park, Yesul;Kang, Soonhee
    • Journal of the Korean Chemical Society
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    • v.57 no.5
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    • pp.640-655
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    • 2013
  • The purpose of this study is to analyze the cognitive demands level of the description about 'changes of state' and 'kinetic theory' on the 'science 1' textbooks by the 2007 revised curriculum. The three types of curriculum analysis taxonomy have been used to analyze the cognitive demands level of those contents on the 6 kinds of 'science 1' textbooks. The most higher level of cognitive demands about the concepts have been discussed here due to the focus of the concepts. The first, the cognitive demand level about 'three states of substances' depending on the motion of their particles in 6 textbooks is a early formal operational stage because of using by the application of kinetic theory. The second, the cognitive demand level about 'diffusion' and 'evaporation' is a early formal operational stage, because the particles move around faster so they can change their position. The third, the cognitive level of the pressure and volume in a gas is a early formal operational stage because of explaining only phenomena in simple correspondence with formal model of kinetic theory. And simple functional relationships beyond linear on the graph of the volume and pressure of gas, the volume and temperature of gas is also a early formal operational stage. The fourth, the cognitive level of the energy of heat by a change of the state is also a early formal operational stage because kinetic theory picture accepted as providing explanation by the change of the state. And functional relationships beyond linear on the graph of the explanation of boiling point of water in water is also a early formal operational stage.

오로라의 신비

  • 안병호
    • Proceedings of the International Union of Geodesy And Geophysics Korea Journal of Geophysical Research Conference
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    • 2003.05a
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    • pp.13-13
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    • 2003
  • 오로라는 태양풍과 지구자기장의 상호작용에 의해 지구의 상층대기에서 일어나는 대규모의 방전현상이다. 방전을 일으키는 전자들은 상층대기의 원자나 분자들과 충돌하여 이들을 들뜨게 하거나 이온화시킨다. 이렇게 들뜬 분자나 원자는 가시광선, 자외선 및 적외선영역의 빛을 방출한다. 오로라의 운동은 빛을 방출하는 상층대기의 운동에 의해서가 아니라 이를 야기하는 하강전자의 충격지점이 변하기 때문이다. 이것은 마치 극지방 상층대기가 TV의 브라운관과 같은 구실을 하고 오로라는 브라운관 안쪽의 형광막에 전자가 부딪쳐 빛을 내는 것과 유사한 현상이다. 따라서 오로라의 운동으로부터 지구주변의 전기장과 자기장의 변화를 알아낼 수 있다. 오로라는 화려한 빛을 발산할 뿐만 아니라 오로라타원체를 따라 강력한 전류가 발생되므로 상층대기 및 지상에 그 효과가 감지된다. 이로 인하여 지상 및 우주공간에 설치된 인류의 최첨단기기의 성능과 수명에 영향을 미쳐 사회.경제적으로 다양한 손실을 야기한다.

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Molecular Vibrational Study of the Allosteric Effect in 2,2'-Bipyridyl Crown Ether (분자진동방법을 사용한 2, 2'-Bipyridyl Crown Ether 의 다른자리 입체성 효과에 관한 연구)

  • Wan Kyu Kim;Soon Ryang Chung
    • Journal of the Korean Chemical Society
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    • v.29 no.3
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    • pp.205-212
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    • 1985
  • By using the Mass-Weighted-Cartesian coordinate method, the allosteric effect of 2,2'-bipyridyl crown(4) ether is studied. The vibrational modes of 235, 234, 188, and 178cm$^{-1}$ belong to the pore opening motion of crown ether and those of 168, 104, and 67cm$^{-1}$ belong to the rotational vibration motion of bipyridyl. Especially the mode appearing at 178cm$^{-1}$ shows a large allosteric effect by activation of the allosteric site.

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초고속 터보 분자펌프의 유동해석

  • Kim, In-Chan;Yun, Jun-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.90-90
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    • 2011
  • 배기속도 2,500 L/s, 최고진공도 10-10 mbar를 구현할 대용량 복합 분자펌프 설계를 위한 2차원과 3차원 형상을 대상으로 실시하였다. 진공도가 10-5 mbar 이상이 되는 고진공도에서는 Knudsen 수가 102~107에 이르러 분자간 충돌을 거의 무시할 수 있게 되며, 이때의 유체해석 방법으로서는 통상 희박기체 해석법으로 많이 쓰이는 Direct Simulation Monte Carlo (DSMC) 방법보다, 충돌이 없는 분자의 자유운동을 모사하는 Monte Carlo 방법이 더 적합하게 된다. 본 연구에서는 다단계 rotor와 stator로 구성되는 복합분자 내 유동장에 Monte Carlo 해석법과 DSMC 방법을 모두 적용하여 유동해석을 실시하였다. 먼저 2차원 모델에 대한 해석을 실시하여 분자펌프의 성능에 중요한 영향을 미치는 설계변수로 날개각과 날개간격이 현저함을 확인하였으며, 이 설계변수들이 펌프의 주요성능 지표인 최대펌핑효율과 최대압축비에 미치는 영향을 다양한 3차원 유동해석을 통해 도출하였다. 유동해석 결과, 기체분자와 rotor 날개사이의 충돌 확률을 높이는 방안이 대체적으로 펌프의 성능을 향상시키는데 도움이 되는 것으로 나타났다.

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Study of Molecular Reorientation in Liquid with Raman Spectroscopy (I). Anisotropic Rotation of CDC$l_3$ in Neat Liquid (용액 중에서의 분자의 재배치 운동에 관한 라만 분광법적 연구 (제1보). 순수 액체상태의 $CDCl_3$에 관한 비등방성 회전)

  • Myung Soo Kim;Kook Joe Shin
    • Journal of the Korean Chemical Society
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    • v.26 no.4
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    • pp.205-209
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    • 1982
  • Anisotropic rotation of $CDCl_3$ in neat liquid is investigated by the analysis of ${\nu}_1$ band of Raman spectrum and the diffusion constant($D_{\perp}$) for the tumbling motion is obtained. The diffusion constant ($D_{II}$) for the spinning motion is obtained from the above $D_{\perp}$ value and the chlorine-35 nuclear quadrupole relaxation time. The diffusion constants thus obtained seem to agree very well with the ones obtained from $^2H$ and $^35C$l in NQR results within experimental errors. The data suggest fairly anisotropic character of reorientational motions in neat $CDCl_3$.

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